Die Kristallstruktur von Zinkformiat-Dihydrat
Abstract
Zinc formate cristallizes isomorphous to the formates of Mg, Sr, Cd, Mn and Ni in the monoclinic space group P21/c. The lattice constants are a = 8.685 Å, b = 7.160 Å, c = 9.323 Å and β = 97.58°.
The structure has been refined including an isotropic extinction correction to RF = 0.043.
The octahedra of the two nonequivalent zinc atoms are slightly distorted. Zn(l) in (000) is surrounded by six oxygen atoms of the formate groups [distances Zn(l)–O = 2.071 Å–2.145 Å]; the octahedron of Zn(2) in (½½0) consists of the oxygen atoms of the two formate groups and two water molecules [distances Zn(2)–O = 2.053 Å–2.165 Å].
The three-dimensional structure is stabilized by hydrogen bonding between formate groups and water molecules.
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
Articles in the same Issue
- Synthese und Kristallstruktur von Te8O10(PO4)4
- Refinement of the crystal structure of α domeykite, a structure related to the A15 type*
- Die Kristallstruktur von Zinkformiat-Dihydrat
- Zur Sytematik tetraedrischer Verbindungen vom Typ Cu2MeIIMeIVMe4VI(Stannite und Wurtzstannite)
- Exploration of cyclotomic point sets for tautoeikonic complementary pairs*
- Verfeinerung der Struktur von Malachit, Cu2(OH)2CO3, durch Neutronenbeugung
- Die Kristallstruktur des Thallium(I)thiogermanats Tl4GeS4
Articles in the same Issue
- Synthese und Kristallstruktur von Te8O10(PO4)4
- Refinement of the crystal structure of α domeykite, a structure related to the A15 type*
- Die Kristallstruktur von Zinkformiat-Dihydrat
- Zur Sytematik tetraedrischer Verbindungen vom Typ Cu2MeIIMeIVMe4VI(Stannite und Wurtzstannite)
- Exploration of cyclotomic point sets for tautoeikonic complementary pairs*
- Verfeinerung der Struktur von Malachit, Cu2(OH)2CO3, durch Neutronenbeugung
- Die Kristallstruktur des Thallium(I)thiogermanats Tl4GeS4
