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Die Kristallstruktur von bis-Cyclooctadien-(1,5)-Nickel(0)
Published/Copyright:
July 28, 2010
Abstract
The crystal structure of bis-cyclo-octadien-nickel, Ni(C8H12)2, has been determined from x-ray diffraction data. The space group is P[unk]–Ci1 and the unit cell, with a = 10.84, b = 9.12, c = 7.38 Å, α = 109.95°, β = 84.72°, γ = 108.13°, contains two molecules, each of which has the symmetry 222. The four C–C double bonds of each molecule are elongated by 0.05 Å compared to normal double bonds and form a quasi-tetrahedral arrangement around the nickel atom with the distances Ni–C all equal to 2.12 Å.
Published Online: 2010-07-28
Published in Print: 1965-10
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Articles in the same Issue
- Die Kristallstruktur von bis-Cyclooctadien-(1,5)-Nickel(0)
- Corrections for x-ray absorption by a crystal of arbitrary shape1
- Kristall- und Molekülstruktur von bis-Methallylnickel Ni[(CH2)2C · CH3]2
- A preliminary orienting procedure for single crystals, using the Weissenberg camera
- Mg2+ – Fe2+ order in an orthopyroxene, Mg0.93Fe1.07Si2O6
- On the x-ray determination of the iron-magnesium ratio in biotites
- Phases and twinning in C2Al3B48 (beta AlB12)
- Packing of B12 groups in boron and boride structures
- A crystallographic study of ammonium and rubidium imidodisulphates
- Interstitial derivatives of β boron
- Die Intensität der an gebogenen Glimmerspaltflächen in höheren Ordnungen reflektierten Röntgenstrahlung
- Morphology and space group of hexaantipyrine perchlorate complexes of Mg++, Ca++ and Zn++, and pentaantipyrine perchlorate of Cu++
- Kristallographische Daten von Quecksilber(I)-acetat
- Preliminary x-ray crystallographic data for 3,7-dideoxy-7-iodo-heptulosonate methyl ester
