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Sorption of Uranium(VI) on Rock Material of a Mine Tailing Pile : Solution Speciation by Fluorescence Spectroscopy
-
G. Geipel
Published/Copyright:
December 1, 2013
Published Online: 2013-12-01
Published in Print: 1996-12-01
© 2013 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- Masthead
- Contents
- A Chemistry of Actinides and Fission Products in Natural Aquatic Systems
- A. 1. Solubilities and Dissolution Reactions
- Solubility and Speciation of (UO2)2SiO4 · 2H2O in Aqueous Systems
- Solubility and Oxidation State of Uranium under Anoxic Conditions (N2 Atmosphere)
- Solubility of Neptunium(IV) Hydrous Oxide in Aqueous Solutions
- Solid-Liquid Phase Equilibria of Np(VI) and of U(VI) under Controlled CO2 Partial Pressures
- The Experimental Determination of the Solubility Product for NpO2OH in NaCl Solutions
- Neptunium(Y) and Neptunium(VI) Solubilities in Synthetic Brines of Interest to the Waste Isolation Pilot Plant (WIPP)
- Thermochemistry of Selected Lanthanide and Actinide Hydroxycarbonates and Carbonates
- The Effect of Silica and Phosphate on the Transformation of Schoepite to Becquerelite and Other Uranyl Phases
- Coprecipitation of Mono-, Di-, Tri-, Tetra- and Hexavalent Ions with Na-Polyuranates
- Uranium Dioxide Leaching Mechanism in a Synthetic Granitic Groundwater in Oxic Conditions in Function of S/V Ratio at 96 °C
- The Release of Uranium, Plutonium, Cesium, Strontium, Technetium and Iodine from Spent Fuel under Unsaturated Conditions
- A. 2. Complexation with Inorganic and Organic Ligands
- Complexation in the System UO2+2/PO3-4/OH (aq): Potentiometric and Spectroscopic Investigations at very Low Ionic Strengths
- Direct Spectroscopic Speciation of Uranium(VI) in Carbonate Solutions
- Speciation of Uranium in Seepage Waters of a Mine Tailing Pile Studied by Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLFS)
- Spectrophotometric Study of the Dissociation of the Pu(IV) Carbonate Limiting Complex
- Thermodynamics of Curium(III) in Concentrated Electrolyte Solutions : Formation of Sulfate Complexes in NaCl/Na2SO4 Solutions
- Complexation of Am(III) by Oxalate in NaClO4 Media
- Thermodynamic Modeling of Neptunium(V)-Acetate Complexation in Concentrated NaCl Media
- Complexation Study of NpO+2 and UO2+2 Ions with Several Organic Ligands in Aqueous Solutions of High Ionic Strength
- Variation of Stability Constants of Thorium Citrate Complexes with Ionic Strength
- Stability of Various Plutonium Valence States in the Presence of NTA and EDTA
- A Comparison of Natural Humic Acids with Synthetic Humic Acid Model Substances : Characterization and Interaction with Uranium(VI)
- A Study of Ternary Complexes of Cm(III) with Humic Acid and Hydroxide or Carbonate in Neutral pH Range by Time-Resolved Laser Fluorescence Spectroscopy
- Α. 3. Redox Reactions and Colloid Formation
- Sorption and Reduction of Uranium(VI) on Iron Corrosion Products under Reducing Saline Conditions
- Radiolytic Compounds Formed by Dissolution of Irradiated NaCl and MgCl2 · 6H2O in Water
- Studies on the Immobilization of Technetium under Near Field Geochemical Conditions
- Multiparametric Investigation of the Reactions of Plutonium under Estuarine Conditions
- Α. 4. Experimental Methods
- A Comparison of Sequential Extraction Techniques to Estimate Geochemical Controls on the Mobility of Fission Product, Actinide, and Heavy Metal Contaminants in Soils
- Impedance Measurements on UO2 in Salt Brines
- Applications of Electrophoresis to the Study of the Complexation of Cadmium with Humic Substances Using 109Cd as Radiotracer
- Modified Diffusion Technique for Studying Nonlinear and Kinetic Sorption and Desorption Processes
- B. Geochemical Interactions and Transport Phenomena
- B. 1. Diffusion and Migration in Geologic Media
- The Distribution of Transuranic Elements in Sediment Profiles from an Intertidal Area in West Cumbria, UK
- Radioactive Contamination of Aquatic Ecosystems in the Areas of Nuclear Power Plants and Other Nuclear Facilities in Russia
- A Comparative Study of the Speciation and Behaviour of Plutonium in the Marine Environment of Two Reprocessing Plants
- Characterization of Rock Matrix Structure Using Microscopy and 14C-PMMA Method for the Study of Retardation Mechanisms in Granite
- Β. 2. Sorption/Desorption Phenomena
- Characterization of Hydrous Uranyl Silicate by EXAFS
- Sorption of Iodine and Cesium on Some Mineral Oxide Colloids
- Studies on the Interaction of Radionuclides with Organophilic Clays
- Sorption of Uranium(VI) on Rock Material of a Mine Tailing Pile : Solution Speciation by Fluorescence Spectroscopy
- Uranium Adsorption on Ferrihydrite - Effects of Phosphate and Humic Acid
- Sorption of Europium(III)-Humate Complexes onto a Sandy Soil
- A Kinetic Study of Cation Release from a Mixed Mineral Assemblage : Implications for Determination of Uranium Uptake
- Perspectives for the Study of the Diffusion of Radionuclides into Minerals Using the Nuclear Microprobe Techniques
- On the Incorrect Derivation and Use of In-situ Retardation Factors from Natural Isotope Profiles By I.
- Β. 3. Natural Analogue Studies
- Clays at the Natural Nuclear Reactor at Bangombé, Gabon: Migration of Actinides
- Occurrence of Pu and Fissiogenic REE in Hydrothermal Apatites from the Fossil Nuclear Reactor 16 at Oklo (Gabon)
- Characterization of Near- to Far-Field Ancient Migrations around Oklo Reaction Zones (Gabon) Using Minerals as Geochemical Tracers
- Natural Radionuclide Fluxes and their Contribution to Defining Licensing Criteria for Deep Geological Repositories for Radioactive Wastes
- On the Role of α-Recoil in Uranium Migration - Some Findings from the Palmottu Natural Analogue Site, SW Finland
- Geochemistry of the Cigar Lake Uranium Deposit: XPS Studies
- Naturally-Occurring Zirconolites - Analogues for the Long-Term Encapsulation of Actinides in Synroc
- Β. 4. Effects of Biological Activities and Organic Materials
- Influence of Organic Degradation Products on the Solubilisation of Radionuclides in Intermediate and Low Level Radioactive Wastes
- The Use of Geochemical Speciation Modelling to Predict the Impact of Uranium to Freshwater Biota
- Author Index of Volume 74 (1996)
Articles in the same Issue
- Masthead
- Contents
- A Chemistry of Actinides and Fission Products in Natural Aquatic Systems
- A. 1. Solubilities and Dissolution Reactions
- Solubility and Speciation of (UO2)2SiO4 · 2H2O in Aqueous Systems
- Solubility and Oxidation State of Uranium under Anoxic Conditions (N2 Atmosphere)
- Solubility of Neptunium(IV) Hydrous Oxide in Aqueous Solutions
- Solid-Liquid Phase Equilibria of Np(VI) and of U(VI) under Controlled CO2 Partial Pressures
- The Experimental Determination of the Solubility Product for NpO2OH in NaCl Solutions
- Neptunium(Y) and Neptunium(VI) Solubilities in Synthetic Brines of Interest to the Waste Isolation Pilot Plant (WIPP)
- Thermochemistry of Selected Lanthanide and Actinide Hydroxycarbonates and Carbonates
- The Effect of Silica and Phosphate on the Transformation of Schoepite to Becquerelite and Other Uranyl Phases
- Coprecipitation of Mono-, Di-, Tri-, Tetra- and Hexavalent Ions with Na-Polyuranates
- Uranium Dioxide Leaching Mechanism in a Synthetic Granitic Groundwater in Oxic Conditions in Function of S/V Ratio at 96 °C
- The Release of Uranium, Plutonium, Cesium, Strontium, Technetium and Iodine from Spent Fuel under Unsaturated Conditions
- A. 2. Complexation with Inorganic and Organic Ligands
- Complexation in the System UO2+2/PO3-4/OH (aq): Potentiometric and Spectroscopic Investigations at very Low Ionic Strengths
- Direct Spectroscopic Speciation of Uranium(VI) in Carbonate Solutions
- Speciation of Uranium in Seepage Waters of a Mine Tailing Pile Studied by Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLFS)
- Spectrophotometric Study of the Dissociation of the Pu(IV) Carbonate Limiting Complex
- Thermodynamics of Curium(III) in Concentrated Electrolyte Solutions : Formation of Sulfate Complexes in NaCl/Na2SO4 Solutions
- Complexation of Am(III) by Oxalate in NaClO4 Media
- Thermodynamic Modeling of Neptunium(V)-Acetate Complexation in Concentrated NaCl Media
- Complexation Study of NpO+2 and UO2+2 Ions with Several Organic Ligands in Aqueous Solutions of High Ionic Strength
- Variation of Stability Constants of Thorium Citrate Complexes with Ionic Strength
- Stability of Various Plutonium Valence States in the Presence of NTA and EDTA
- A Comparison of Natural Humic Acids with Synthetic Humic Acid Model Substances : Characterization and Interaction with Uranium(VI)
- A Study of Ternary Complexes of Cm(III) with Humic Acid and Hydroxide or Carbonate in Neutral pH Range by Time-Resolved Laser Fluorescence Spectroscopy
- Α. 3. Redox Reactions and Colloid Formation
- Sorption and Reduction of Uranium(VI) on Iron Corrosion Products under Reducing Saline Conditions
- Radiolytic Compounds Formed by Dissolution of Irradiated NaCl and MgCl2 · 6H2O in Water
- Studies on the Immobilization of Technetium under Near Field Geochemical Conditions
- Multiparametric Investigation of the Reactions of Plutonium under Estuarine Conditions
- Α. 4. Experimental Methods
- A Comparison of Sequential Extraction Techniques to Estimate Geochemical Controls on the Mobility of Fission Product, Actinide, and Heavy Metal Contaminants in Soils
- Impedance Measurements on UO2 in Salt Brines
- Applications of Electrophoresis to the Study of the Complexation of Cadmium with Humic Substances Using 109Cd as Radiotracer
- Modified Diffusion Technique for Studying Nonlinear and Kinetic Sorption and Desorption Processes
- B. Geochemical Interactions and Transport Phenomena
- B. 1. Diffusion and Migration in Geologic Media
- The Distribution of Transuranic Elements in Sediment Profiles from an Intertidal Area in West Cumbria, UK
- Radioactive Contamination of Aquatic Ecosystems in the Areas of Nuclear Power Plants and Other Nuclear Facilities in Russia
- A Comparative Study of the Speciation and Behaviour of Plutonium in the Marine Environment of Two Reprocessing Plants
- Characterization of Rock Matrix Structure Using Microscopy and 14C-PMMA Method for the Study of Retardation Mechanisms in Granite
- Β. 2. Sorption/Desorption Phenomena
- Characterization of Hydrous Uranyl Silicate by EXAFS
- Sorption of Iodine and Cesium on Some Mineral Oxide Colloids
- Studies on the Interaction of Radionuclides with Organophilic Clays
- Sorption of Uranium(VI) on Rock Material of a Mine Tailing Pile : Solution Speciation by Fluorescence Spectroscopy
- Uranium Adsorption on Ferrihydrite - Effects of Phosphate and Humic Acid
- Sorption of Europium(III)-Humate Complexes onto a Sandy Soil
- A Kinetic Study of Cation Release from a Mixed Mineral Assemblage : Implications for Determination of Uranium Uptake
- Perspectives for the Study of the Diffusion of Radionuclides into Minerals Using the Nuclear Microprobe Techniques
- On the Incorrect Derivation and Use of In-situ Retardation Factors from Natural Isotope Profiles By I.
- Β. 3. Natural Analogue Studies
- Clays at the Natural Nuclear Reactor at Bangombé, Gabon: Migration of Actinides
- Occurrence of Pu and Fissiogenic REE in Hydrothermal Apatites from the Fossil Nuclear Reactor 16 at Oklo (Gabon)
- Characterization of Near- to Far-Field Ancient Migrations around Oklo Reaction Zones (Gabon) Using Minerals as Geochemical Tracers
- Natural Radionuclide Fluxes and their Contribution to Defining Licensing Criteria for Deep Geological Repositories for Radioactive Wastes
- On the Role of α-Recoil in Uranium Migration - Some Findings from the Palmottu Natural Analogue Site, SW Finland
- Geochemistry of the Cigar Lake Uranium Deposit: XPS Studies
- Naturally-Occurring Zirconolites - Analogues for the Long-Term Encapsulation of Actinides in Synroc
- Β. 4. Effects of Biological Activities and Organic Materials
- Influence of Organic Degradation Products on the Solubilisation of Radionuclides in Intermediate and Low Level Radioactive Wastes
- The Use of Geochemical Speciation Modelling to Predict the Impact of Uranium to Freshwater Biota
- Author Index of Volume 74 (1996)