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Ionizing radiation based advanced oxidation process for reactive orange 122 dye degradation and kinetics studies

  • Saddaqat Ali , Majid Muneer EMAIL logo , Muhammad Kaleem Khan Khosa , Nada Alfryyan and Munawar Iqbal EMAIL logo
Published/Copyright: September 14, 2022
Zeitschrift für Physikalische Chemie
From the journal Zeitschrift für Physikalische Chemie Volume 236 Issue 10

Abstract

In the current study, the degradation of reactive orange 122 (RO 122) dye was carried out under UV and gamma irradiation in presence of H2O2. The effect of variables such as UV exposure time, gamma-ray absorbed dose, initial concentration of dye and oxidant dose were investigated. The removal of 64.10, 58.84 and 55.46 (%) was observed for 50, 100 and 150 (mg/L) dye concentrations, respectively using UV radiation time of 150 (min). The degradation was enhanced to 80.39, 69.95 and 67.01 (%) when UV radiation was employed in the presence of H2O2 (0.5 mL/L) for above concentrations respectively. The degradation was further improved to 97, 92.54 and 81.32 (%) using 5 kGy absorbed dose along with H2O2 (0.5 mL/L). The reduction in chemical oxygen demand (COD) was 77, 64 and 57 (%) using UV/H2O2 (0.5 mL/L), while 63, 56 and 53 (%) in case of gamma/H2O2 for aforementioned concentrations. The removal efficiency (G-value), dose constants (k), dose indispensable for 50, 90 and 99 (%) degradation (D 0.5, D 0.90, and D 0.99) after the treatment with gamma radiation were determined. The G-value was noted as 0.46–0.0711 for 50–150 mg/L dye concentration for gamma irradiated samples which improved to 0.57–0.1204 for above mentioned concentrations in presence of H2O2. The FTIR analysis showed that all the peaks were disappeared using gamma/H2O2 at 5 kGy absorbed dose except a minor peak of −CO stretching. The degradation mechanism of dye followed pseudo-first-order kinetics. A significant decrease in peak area was observed by the HPLC analysis after treating the dye samples with gamma/H2O2 (0.5 mL/L) at absorbed dose of 5 kGy which has proven the process efficiency for dye degradation.

Keywords: ionizing radiation; reactive orange 122 dye; removal efficiency; UV radiation
Corresponding authors: Majid Muneer, Department of Chemistry, Government College University Faisalabad, Faisalabad, 38000, Pakistan, E-mail: ; and Munawar Iqbal, Department of Chemistry, Division of Science and Technology, University of Education, Lahore, Pakistan, E-mail:

Acknowledgments

The authors express their gratitude to Princess Nourah bint Abdulrahman University Researchers Supporting Project (Grant No. PNURSP2022R291), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia. The authors are thankful to the authorities of the National Institute for Agriculture and Biology (NIAB), Faisalabad, Pakistan for providing the facility of the gamma radiation source for the treatment of dye samples. We are also thankful to Dr. Muhammad Saeed for helping in data analysis.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This research was funded by Princess Nourah bint Abdulrahman University Researchers Supporting Project (Grant No. PNURSP2022R291), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.

  3. Conflict of interest statement: The authors declare no conflicts of interest.

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Received: 2021-04-28
Accepted: 2022-06-08
Published Online: 2022-09-14
Published in Print: 2022-10-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/zpch-2021-3056
Keywords for this article
ionizing radiation; reactive orange 122 dye; removal efficiency; UV radiation

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Combine merits of both sacrificial and impressed current cathodic protection in one system to mitigate chloride-induced corrosion in reinforcement concrete
  4. Differences in perchlorate adsorption to azobenzene monolayers on gold formed from thioacetate and thiol precursors
  5. Adsorption kinetics for the removal of toxic Congo red dye by polyaniline and citrus leaves as effective adsorbents
  6. Ionizing radiation based advanced oxidation process for reactive orange 122 dye degradation and kinetics studies
  7. Molecular interaction studies on the binding ability of hydrated zinc sulphate with aqueous solution of ascorbic acid at different temperatures
  8. Theoretical investigation of some 1,2,4-triazole-based molecules synthetized
  9. Review Article
  10. Heterogeneous nanocatalyst for biodiesel fuel production: bench scale from waste oil sources
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