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Molecular interaction studies on the binding ability of hydrated zinc sulphate with aqueous solution of ascorbic acid at different temperatures

  • Vikas Bharti , Deepika Kaushal , Sunil Kumar , Abhishek Thakur , Dilbag Singh Rana , Manish Kumar EMAIL logo and Shashi Kant
Published/Copyright: June 24, 2022
Zeitschrift für Physikalische Chemie
From the journal Zeitschrift für Physikalische Chemie Volume 236 Issue 10

Abstract

The ternary systems containing Water, Ascorbic acid (AA) and ZnSO4·7H2O were investigated using three approaches namely volumetric studies, viscosity studies and conductance studies. The solvent systems used were 2, 4 and 6% (by weight) of AA in water. The studies were conducted at four temperatures (303.15–318.15 K with an interval of 5 K) and pressure 0.1 MPa with concentration of ZnSO4·7H2O in the solution ranging from 0.01 to 0.12 m. Various parameters like partial molar volume (ϕv), apparent molar volume ( ϕ v o ) , Hepler’s constant ( ( d 2 ϕ v o / d T 2 ) p ) , partial molar expansibility ( ϕ E o ) and transfer volume ( Δ t r ϕ v o ) have been evaluated from volumetric studies. The viscosity studies have yielded Jones-Dole parameters (A and B) and free energy of activation per mole for solvent ( Δ μ 1 0 ‡ ) and solute ( Δ μ 2 0 ‡ ) . The conductance data has been used to calculate molar conductance (Λm), limiting molar conductance ( Λ m o ) and Walden product ( Λ m o η o ) . The results of these studies agree with each other and have concluded the structure breaker behavior of ZnSO4·7H2O in the solvent system containing AA and water.

Keywords: apparent molar volume; partial molar expansibility; structure breaker behavior; transfer parameters; Walden product
Corresponding author: Manish Kumar, Department of Chemistry & Chemical Sciences, Central University of Himachal Pradesh, Dharamshala, Kangra (HP), India, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: Vikas Bharti is grateful to UGC, New Delhi for financial support.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-04-22
Accepted: 2022-06-08
Published Online: 2022-06-24
Published in Print: 2022-10-26

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/zpch-2021-3054
Keywords for this article
apparent molar volume; partial molar expansibility; structure breaker behavior; transfer parameters; Walden product

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Combine merits of both sacrificial and impressed current cathodic protection in one system to mitigate chloride-induced corrosion in reinforcement concrete
  4. Differences in perchlorate adsorption to azobenzene monolayers on gold formed from thioacetate and thiol precursors
  5. Adsorption kinetics for the removal of toxic Congo red dye by polyaniline and citrus leaves as effective adsorbents
  6. Ionizing radiation based advanced oxidation process for reactive orange 122 dye degradation and kinetics studies
  7. Molecular interaction studies on the binding ability of hydrated zinc sulphate with aqueous solution of ascorbic acid at different temperatures
  8. Theoretical investigation of some 1,2,4-triazole-based molecules synthetized
  9. Review Article
  10. Heterogeneous nanocatalyst for biodiesel fuel production: bench scale from waste oil sources
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