Spectroscopic, Electrochemical and Quantum Chemical Studies for Adsorption Action of Polyethylene Oxide on Copper Surface in NaCl Solution
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Mahmoud N. El-Haddad
Abstract
The adsorption action of polyethylene oxide (PEO) on copper surface in 3.5 wt.% NaCl solution was tested using electrochemical frequency modulation (EFM), atomic absorption spectrometry (AAS), UV- visible spectrometry and the morphology of copper surface was investigated by attenuated total reflectance spectroscopy (ATR-FTIR), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) techniques. Results obtained show that PEO is effective in preventing the corrosion of copper in NaCl solution. The adsorption of PEO onto copper surface was found to follow Langmuir isotherm model. ATR-FTIR, SEM and EDX spectroscopy techniques confirmed the adsorption of protective film of PEO on copper surface. Further, quantum chemical calculations were in agreement with inhibition efficiency (%I) of PEO that were obtained experimentally.
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Articles in the same Issue
- Frontmatter
- Original Papers
- Exploring Differences in Excited-State Properties of Styryl-BODIPY Chromophores upon Change from α- to β-Substitution
- Synthesis of Carboxymethyl Starch-Bio-Based Epoxy Resin and their Impact on Mechanical Properties
- Temperature Dependent Solubility of Benzoic Acid in Aqueous Phase and Aqueous Mixtures of Aliphatic Alcohols
- A Simple but Efficient Catalytic Approach for the Degradation of Pollutants in Aqueous Media through Cicer arietinum Supported Ni Nanoparticles
- Kinetic Study of Degradation of Basic Turquise Blue X-GB and Basic Blue X-GRRL using Advanced Oxidation Process
- Characterization and Gas Sensing Properties of Spin Coated WO3 Thin Films
- Spectroscopic, Electrochemical and Quantum Chemical Studies for Adsorption Action of Polyethylene Oxide on Copper Surface in NaCl Solution
- Interactions of Drug Doxycycline Hyclate with Galactitol in Aqueous Solutions at Different Temperatures by Volumetric and Acoustic Methods
Articles in the same Issue
- Frontmatter
- Original Papers
- Exploring Differences in Excited-State Properties of Styryl-BODIPY Chromophores upon Change from α- to β-Substitution
- Synthesis of Carboxymethyl Starch-Bio-Based Epoxy Resin and their Impact on Mechanical Properties
- Temperature Dependent Solubility of Benzoic Acid in Aqueous Phase and Aqueous Mixtures of Aliphatic Alcohols
- A Simple but Efficient Catalytic Approach for the Degradation of Pollutants in Aqueous Media through Cicer arietinum Supported Ni Nanoparticles
- Kinetic Study of Degradation of Basic Turquise Blue X-GB and Basic Blue X-GRRL using Advanced Oxidation Process
- Characterization and Gas Sensing Properties of Spin Coated WO3 Thin Films
- Spectroscopic, Electrochemical and Quantum Chemical Studies for Adsorption Action of Polyethylene Oxide on Copper Surface in NaCl Solution
- Interactions of Drug Doxycycline Hyclate with Galactitol in Aqueous Solutions at Different Temperatures by Volumetric and Acoustic Methods
