Effect of Maltodextrin and Temperature on Micellar Behavior of Bile Salts in Aqueous Medium: Conductometric and Spectrofluorimetric Studies
Abstract
Conductivity and fluorescence probe techniques have been employed to study the micellar behavior of bile salts i.e. sodium cholate (1–20 mmol⋅kg−1) and sodium deoxycholate (0.5–10.0 mmol⋅kg−1) in aqueous solutions of maltodextrin (0.0, 0.5, 1.1, and 1.6 mmol⋅kg−1) at different temperatures. The influence of maltodextrin on the micellization behavior of bile salts has been determined in terms of critical micelle concentration (CMC) values obtained from conductivity measurement. The variation in CMC values has been discussed by considering the alteration in the hydrophobic environment of maltodextrin-sodium cholate/sodium deoxycholate complex imparted by the carbohydrate molecules. In order to substantiate the CMC values determined from conductivity method, the fluorescence probe study of aqueous sodium cholate and sodium deoxycholate solutions in presence of fluorescent, pyrene has also been carried. The CMC values obtained from both techniques are in full agreement with each other. Moreover, application of charged pseudo-phase separation model has been made to discuss the thermodynamics of the system.
Acknowledgments
Vivek Sharma and Kuldeep Singh thank Himachal Pradesh University, Shimla for the award of Junior Research Fellowship (F.No. 1-3/2013-HPU (DS) 5111 and No.1-3/2016-HPU(DS), respectively). Financial support from UGC-SAP (DRS-I) (No. F.540/3/DRS/2010 (SAP-1)) to Department of Chemistry, HPU is also acknowledged.
Conflict of interest: The authors declare no competing financial interest.
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Artikel in diesem Heft
- Frontmatter
- Hydrogen Bond Interaction of Ascorbic Acid with Urea: Experimental and Theoretical Study
- The Thermodynamic and Binding Studies of Hg+2 Ions with Egg Protein by Polarographic and pH Metric Techniques
- Effect of Maltodextrin and Temperature on Micellar Behavior of Bile Salts in Aqueous Medium: Conductometric and Spectrofluorimetric Studies
- Probing Inclusion Complexes of Pentoxifylline and Pralidoxim inside Cyclic Oligosaccharides by Physicochemical Methodologies
- Solubility and Solution Thermodynamics of Baricitinib in Six Different Pharmaceutically Used Solvents at Different Temperatures
- One-Pot Synthesis and Rheological Study of Cationic Poly (3-acrylamidopropyltrimethyl ammoniumchloride) P(APTMACl) Polymer Hydrogels
- Synthesis and Characterization of BaAl2O4 Catalyst and its Photocatalytic Activity Towards Degradation of Methylene Blue Dye
- Chemically Synthesized Hierarchical Flower like ZnO Microstructures
- Statistical Modeling, Optimization and Kinetics of Mn2+ Adsorption in Aqueous Solution Using a Biosorbent
Artikel in diesem Heft
- Frontmatter
- Hydrogen Bond Interaction of Ascorbic Acid with Urea: Experimental and Theoretical Study
- The Thermodynamic and Binding Studies of Hg+2 Ions with Egg Protein by Polarographic and pH Metric Techniques
- Effect of Maltodextrin and Temperature on Micellar Behavior of Bile Salts in Aqueous Medium: Conductometric and Spectrofluorimetric Studies
- Probing Inclusion Complexes of Pentoxifylline and Pralidoxim inside Cyclic Oligosaccharides by Physicochemical Methodologies
- Solubility and Solution Thermodynamics of Baricitinib in Six Different Pharmaceutically Used Solvents at Different Temperatures
- One-Pot Synthesis and Rheological Study of Cationic Poly (3-acrylamidopropyltrimethyl ammoniumchloride) P(APTMACl) Polymer Hydrogels
- Synthesis and Characterization of BaAl2O4 Catalyst and its Photocatalytic Activity Towards Degradation of Methylene Blue Dye
- Chemically Synthesized Hierarchical Flower like ZnO Microstructures
- Statistical Modeling, Optimization and Kinetics of Mn2+ Adsorption in Aqueous Solution Using a Biosorbent