Home NMR Studies of Lithium Diffusion in Li3(NH2)2I Over Wide Range of Li+ Jump Rates
Article
Licensed
Unlicensed Requires Authentication

NMR Studies of Lithium Diffusion in Li3(NH2)2I Over Wide Range of Li+ Jump Rates

  • Alexander V. Skripov EMAIL logo , Kai Volgmann , C. Vinod Chandran , Roman V. Skoryunov , Olga A. Babanova , Alexei V. Soloninin , Shin-ichi Orimo and Paul Heitjans
Published/Copyright: May 8, 2017
Zeitschrift für Physikalische Chemie
From the journal Zeitschrift für Physikalische Chemie Volume 231 Issue 7-8

Abstract

We have studied the Li diffusion in the complex hydride Li3(NH2)2I which appears to exhibit fast Li ion conduction. To get a detailed insight into the Li motion, we have applied 7Li nuclear magnetic resonance spectroscopy methods, such as spin-lattice relaxation in the laboratory and rotating frames of reference, as well as spin-alignment echo. This combined approach allows us to probe Li jump rates over the wide dynamic range (~102–109 s−1). The spin-lattice relaxation data in the range 210–410 K can be interpreted in terms of a thermally-activated Li jump process with a certain distribution of activation energies. However, the low-temperature spin-alignment echo decays at T≤200 K suggest the presence of another Li jump process with the very low effective activation energy.

Keywords: complex hydride; ion diffusion; nuclear magnetic resonance; spin-alignment echo; spin-lattice relaxation

Acknowledgements

This work was supported in part by the Russian Federal Agency of Scientific Organizations under Program “Spin” No. 01201463330, the Russian Foundation for Basic Research (Grant. No. 15-03-01114), and the JSPS KAKENHI Grant No. 25220911 from MEXT, Japan. A.V. Skripov is grateful to Alexander von Humboldt Foundation for the support of his research visit to Leibniz Universität Hannover. Research in Hannover has generally been supported by the German Research Foundation (DFG) in the frame of the Research Unit FOR 1277 (molife). The authors are also grateful to V.I. Voronin and V.A. Blatov for useful discussions.

References

1. M. Matsuo, S. Orimo, Adv. Energy Mater. 1 (2011) 161.10.1002/aenm.201000012Search in Google Scholar

2. M. Matsuo, S. Kuromoto, S. Sato, H. Oguchi, H. Takamura, S. Orimo, Appl. Phys. Lett. 100 (2012) 203904.10.1063/1.4716021Search in Google Scholar

3. P. E. de Jongh, D. Blanchard, M. Matsuo, T. J. Udovic, S. Orimo, Appl. Phys. A Mater. Sci. Process. 122 (2016) 1.10.1007/s00339-015-9525-1Search in Google Scholar

4. M. Matsuo, Y. Nakamori, S. Orimo, H. Maekawa, H. Takamura, Appl. Phys. Lett. 91 (2007) 224103.10.1063/1.2817934Search in Google Scholar

5. H. Maekawa, M. Matsuo, H. Takamura, M. Ando, Y. Noda, T. Karahashi, S. Orimo, J. Am. Chem. Soc. 131 (2009) 894.10.1021/ja807392kSearch in Google Scholar PubMed

6. M. Matsuo, A. Remhof, P. Martelli, R. Caputo, M. Ernst, Y. Miura, T. Sato, H. Oguchi, H. Maekawa, H. Takamura, A. Borgschulte, A. Züttel, S. Orimo, J. Am. Chem. Soc. 131 (2009) 16389.10.1021/ja907249pSearch in Google Scholar PubMed

7. B. A. Boukamp, R. A. Huggins, Phys. Lett. A 72 (1979) 464.10.1016/0375-9601(79)90846-6Search in Google Scholar

8. M. B. Ley, D. B. Ravnsbæk, Y. Filinchuk, Y. S. Lee, R. Janot, Y. W. Cho, J. Skibsted, T. R. Jensen, Chem. Mater. 24 (2012) 1654.10.1021/cm300792tSearch in Google Scholar

9. M. B. Ley, S. Boulineau, R. Janot, Y. Filinchuk, T. R. Jensen, J. Phys. Chem. C 116 (2012) 21267.10.1021/jp307762gSearch in Google Scholar

10. T. J. Udovic, M. Matsuo, A. Unemoto, N. Verdal, V. Stavila, A. V. Skripov, J. J. Rush, H. Takamura, S. Orimo, Chem. Commun. 50 (2014) 3750.10.1039/C3CC49805KSearch in Google Scholar

11. T. J. Udovic, M. Matsuo, W. S. Tang, H. Wu, V. Stavila, A. V. Soloninin, R. V. Skoryunov, O. A. Babanova, A. V. Skripov, J. J. Rush, A. Unemoto, H. Takamura, S. Orimo, Adv. Mater. 26 (2014) 7622.10.1002/adma.201403157Search in Google Scholar PubMed

12. W. S. Tang, M. Matsuo, H. Wu, V. Stavila, W. Zhou, A. Talin, A. V. Soloninin, R. V. Skoryunov, O. A. Babanova, A. V. Skripov, A. Unemoto, S. Orimo, T. J. Udovic, Adv. Energy Mater. 6 (2016) 1502237.10.1002/aenm.201502237Search in Google Scholar

13. W. S. Tang, K. Yoshida, A. V. Soloninin, R. V. Skoryunov, O. A. Babanova, A. V. Skripov, M. Dimitrievska, V. Stavila, S. Orimo, T. J. Udovic, ACS Energy Lett. 1 (2016) 659.10.1021/acsenergylett.6b00310Search in Google Scholar

14. A. V. Skripov, A. V. Soloninin, M. B. Ley, T. R. Jensen, Y. Filinchuk, J. Phys. Chem. C 117 (2013) 14965.10.1021/jp403746mSearch in Google Scholar

15. Y. S. Lee, M. B. Ley, T. R. Jensen, Y. W. Cho, J. Phys. Chem. C 120 (2016) 19035.10.1021/acs.jpcc.6b06564Search in Google Scholar

16. M. Matsuo, T. Sato, Y. Miura, H. Oguchi, Y. Zhou, H. Maekawa, H. Takamura, S. Orimo, Chem. Mater. 22 (2010) 2702.10.1021/cm1006857Search in Google Scholar

17. A. V. Skripov, A. V. Soloninin, O. A. Babanova, R. V. Skoryunov, J. Alloys Compd. 645 (2015) S428.10.1016/j.jallcom.2014.12.089Search in Google Scholar

18. C. Vinod Chandran, P. Heitjans, Ann. Rep. NMR Spectrosc. 89 (2016) 1.10.1016/bs.arnmr.2016.03.001Search in Google Scholar

19. A. V. Skripov, R. V. Skoryunov, A. V. Soloninin, O. A. Babanova, M. Matsuo, S. Orimo, J. Phys. Chem. C 119 (2015) 13459.10.1021/acs.jpcc.5b03183Search in Google Scholar

20. D. C. Look, I. J. Lowe, J. Chem. Phys. 44 (1966) 2995.10.1063/1.1727169Search in Google Scholar

21. D. C. Ailion, C. P. Slichter, Phys. Rev. 137 (1965) A235.10.1103/PhysRev.137.A235Search in Google Scholar

22. H. W. Spiess, J. Chem. Phys. 72 (1980) 6755.10.1063/1.439165Search in Google Scholar

23. R. Böhmer, T. Jörg, F. Qi, A. Titze, Chem. Phys. Lett. 316 (2000) 419.10.1016/S0009-2614(99)01297-XSearch in Google Scholar

24. F. Qi, C. Rier, R. Böhmer, W. Franke, P. Heitjans, Phys. Rev. B 72 (2005) 104301.10.1103/PhysRevB.72.104301Search in Google Scholar

25. M. Wilkening, P. Heitjans, Solid State Ionics 177 (2006) 3031.10.1016/j.ssi.2006.07.037Search in Google Scholar

26. M. Wilkening, P. Heitjans, ChemPhysChem 13 (2012) 53.10.1002/cphc.201100580Search in Google Scholar PubMed

27. M. Wilkening, P. Heitjans, Phys. Rev. B 77 (2008) 024311.10.1103/PhysRevB.77.024311Search in Google Scholar

28. J. Jeener, P. Broekaert, Phys. Rev. 157 (1967) 232.10.1103/PhysRev.157.232Search in Google Scholar

29. A. Abragam, The Principles of Nuclear Magnetism, Clarendon Press, Oxford (1961).10.1063/1.3057238Search in Google Scholar

30. J. T. Markert, E. J. Cotts, R. M. Cotts, Phys. Rev. B 37 (1988) 6446.10.1103/PhysRevB.37.6446Search in Google Scholar

31. A. Kuhn, M. Kunze, P. Sreeraj, H.-D. Wiemhöfer, V. Thangadurai, M. Wilkening, P. Heitjans, Solid State Nucl. Magn. Reson. 42 (2012) 2.10.1016/j.ssnmr.2012.02.001Search in Google Scholar PubMed

32. V. A. Blatov, A. P. Shevchenko, D. M. Proserpio, Cryst. Growth Des. 14 (2014) 3576.10.1021/cg500498kSearch in Google Scholar

Received: 2016-11-2
Accepted: 2017-1-18
Published Online: 2017-5-8
Published in Print: 2017-7-26

©2017 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Preface
  3. Mobility of Ions in Solids
  4. Solid-State NMR to Study Translational Li Ion Dynamics in Solids with Low-Dimensional Diffusion Pathways
  5. Solid-State NMR Spectroscopy Study of Cation Dynamics in Layered Na2Ti3O7 and Li2Ti3O7
  6. Density Functional Theory Evaluated for Structural and Electronic Properties of 1T-LixTiS2 and Lithium Ion Migration in 1T-Li0.94TiS2
  7. Diffusion Pathways and Activation Energies in Crystalline Lithium-Ion Conductors
  8. Lithium Mobility in Borate and Phosphate Glass Networks
  9. Effect of Particle Size and Pretreatment on the Conductivity of Glass Powder during Compaction
  10. On the Mechanisms of Chemical Intercalation of Lithium in Electrode Materials
  11. Nanostructured Ceramics: Ionic Transport and Electrochemical Activity
  12. Lithium Insertion into Mixed Phase Titania Nanotubes
  13. Slow Lithium Transport in Metal Oxides on the Nanoscale
  14. Local Ion Dynamics in Polycrystalline β-LiGaO2: A Solid-State NMR Study
  15. NMR Studies of Lithium Diffusion in Li3(NH2)2I Over Wide Range of Li+ Jump Rates
https://doi.org/10.1515/zpch-2016-0925
Keywords for this article
complex hydride; ion diffusion; nuclear magnetic resonance; spin-alignment echo; spin-lattice relaxation

Articles in the same Issue

  1. Frontmatter
  2. Preface
  3. Mobility of Ions in Solids
  4. Solid-State NMR to Study Translational Li Ion Dynamics in Solids with Low-Dimensional Diffusion Pathways
  5. Solid-State NMR Spectroscopy Study of Cation Dynamics in Layered Na2Ti3O7 and Li2Ti3O7
  6. Density Functional Theory Evaluated for Structural and Electronic Properties of 1T-LixTiS2 and Lithium Ion Migration in 1T-Li0.94TiS2
  7. Diffusion Pathways and Activation Energies in Crystalline Lithium-Ion Conductors
  8. Lithium Mobility in Borate and Phosphate Glass Networks
  9. Effect of Particle Size and Pretreatment on the Conductivity of Glass Powder during Compaction
  10. On the Mechanisms of Chemical Intercalation of Lithium in Electrode Materials
  11. Nanostructured Ceramics: Ionic Transport and Electrochemical Activity
  12. Lithium Insertion into Mixed Phase Titania Nanotubes
  13. Slow Lithium Transport in Metal Oxides on the Nanoscale
  14. Local Ion Dynamics in Polycrystalline β-LiGaO2: A Solid-State NMR Study
  15. NMR Studies of Lithium Diffusion in Li3(NH2)2I Over Wide Range of Li+ Jump Rates
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 3.10.2025 from https://www.degruyterbrill.com/document/doi/10.1515/zpch-2016-0925/html?lang=en
Scroll to top button