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‘Schmidbaur gold chemistry’ and beyond

  • Daniela I. Bezuidenhout ORCID logo , Catharine Esterhuysen ORCID logo , Liliana Dobrzańska ORCID logo , Stephanie Cronje ORCID logo and Helgard G. Raubenheimer ORCID logo EMAIL logo
Published/Copyright: January 13, 2025
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 79 Issue 12

Abstract

Hubert Schmidbaur has significantly influenced the field of gold chemistry. His work on preparing various aurocyclic digold compounds and studying their structures and reactivities has laid the foundation for unique applications in photophysics and homogeneous catalysis. The naming and characterization, both experimental and theoretical, of the aurophilicity phenomenon have led to numerous interdisciplinary applications. The emergence and development of dynamic gold chemistry in the excited state, exemplify this impact. Preparative methodologies, characterization techniques, and qualitative bonding theories have been tested through the rational preparation of ligated, element-centred gold clusters. The potential of this fascinating class of compounds remains largely untapped.

Keywords: aurocyclic complexes; aurophilicity; photophysics; excimers; gold-element clusters; homogeneous catalysis
Corresponding author: Helgard G. Raubenheimer, Department of Chemistry and Polymer Science, Stellenbosch University, Private Bag X1, Matieland, 7602, Stellenbosch, South Africa, E-mail:
Dedicated to gold chemistry maestro and crusader, Prof. Dr. Dr. h.c. Hubert Schmidbaur on the occasion of his 90th birthday.

Acknowledgments

We thank Beatrice Elisabeth Cronje for drawing the Havana cigar and the hiking poles in the graphical abstract.

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: All authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: None declared.

  7. Data availability: Not applicable.

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Received: 2024-10-08
Accepted: 2024-10-15
Published Online: 2025-01-13
Published in Print: 2024-12-17

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Hubert Schmidbaur 90 years – an appreciation
  5. Reviews
  6. ‘Schmidbaur gold chemistry’ and beyond
  7. The ligand polyhedral model and its application to the structures and fluxional behaviour of the metal carbonyls
  8. Research Articles
  9. Equiatomic transition metal (T) silicides TT′Si: systematics of 29Si NMR Knight shifts
  10. New alkaline earth and rare earth representatives adopting the Ce2Al16Pt9-type structure
  11. Bis(2-chloroethyl)sulfane revisited: (ClH4C2)2S⋯S(C2H4Cl) dimers by S⋯S interaction in the solid state
  12. Structural studies of (2R,3R)-(+)-bis(diphenylphosphino)butane and (R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl
  13. High-pressure synthesis and crystal structure of Al3BO6
  14. LiEu[BO3]: a lithium europium(II) ortho-oxoborate with a familiar crystal structure
  15. Fluorescence analysis of wood chips and their constituents
  16. C–S–H–PCE nanocomposites as hydration accelerator in calcined clay-limestone-blended low carbon cement
  17. An intermolecular Lewis pair based on tin acid and phosphonium ylide base functions
  18. Cyanopyridine adducts of SiF4 and SiCl4
  19. A [Zn4O(fcCO2)6] oxocarboxylate cluster: synthesis, chemical and physical properties
  20. Homo- and heteronuclear complexes derived from N-picoline-functionalized benzimidazolin-2-ylidene ligands
  21. “Coordination caps” of graded electron-donor capacity
  22. The hare and the hedgehog – Similar thermal expansion of argento- and aurophilic contacts for different reasons
  23. Atomic migration and phase transformation processes in dental amalgams over 27 years, monitored by X-ray spectroscopy and X-ray powder diffraction
  24. Book Review
  25. Hubert Schmidbaur: From Chemical Craftsmanship to the Art of Gilding Atoms. (Lives in Chemistry.)
https://doi.org/10.1515/znb-2024-0086
Keywords for this article
aurocyclic complexes; aurophilicity; photophysics; excimers; gold-element clusters; homogeneous catalysis

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Hubert Schmidbaur 90 years – an appreciation
  5. Reviews
  6. ‘Schmidbaur gold chemistry’ and beyond
  7. The ligand polyhedral model and its application to the structures and fluxional behaviour of the metal carbonyls
  8. Research Articles
  9. Equiatomic transition metal (T) silicides TT′Si: systematics of 29Si NMR Knight shifts
  10. New alkaline earth and rare earth representatives adopting the Ce2Al16Pt9-type structure
  11. Bis(2-chloroethyl)sulfane revisited: (ClH4C2)2S⋯S(C2H4Cl) dimers by S⋯S interaction in the solid state
  12. Structural studies of (2R,3R)-(+)-bis(diphenylphosphino)butane and (R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl
  13. High-pressure synthesis and crystal structure of Al3BO6
  14. LiEu[BO3]: a lithium europium(II) ortho-oxoborate with a familiar crystal structure
  15. Fluorescence analysis of wood chips and their constituents
  16. C–S–H–PCE nanocomposites as hydration accelerator in calcined clay-limestone-blended low carbon cement
  17. An intermolecular Lewis pair based on tin acid and phosphonium ylide base functions
  18. Cyanopyridine adducts of SiF4 and SiCl4
  19. A [Zn4O(fcCO2)6] oxocarboxylate cluster: synthesis, chemical and physical properties
  20. Homo- and heteronuclear complexes derived from N-picoline-functionalized benzimidazolin-2-ylidene ligands
  21. “Coordination caps” of graded electron-donor capacity
  22. The hare and the hedgehog – Similar thermal expansion of argento- and aurophilic contacts for different reasons
  23. Atomic migration and phase transformation processes in dental amalgams over 27 years, monitored by X-ray spectroscopy and X-ray powder diffraction
  24. Book Review
  25. Hubert Schmidbaur: From Chemical Craftsmanship to the Art of Gilding Atoms. (Lives in Chemistry.)
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