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Das Ytterbium(III)-Oxidbromid-Oxidotellurat(IV) Yb3O2Br[TeO3]2

  • Steffen F. Meier , Philip L. Russ and Thomas Schleid EMAIL logo
Published/Copyright: August 21, 2020
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 75 Issue 8

Abstract

The ytterbium(III) oxide bromide oxidotellu-rate(IV) Yb3O2Br[TeO3]2 was obtained from a mixture of Yb2O3, YbBr3 and TeO2 in a molar ratio of 2:1:2 along with an excess of KBr as fluxing agent in evacuated fused silica ampoules after 10 days at T = 800 °C and subsequent slow cooling to room temperatures as colorless, plate-shaped single crystals. Its triclinic crystal structure (a = 663.97(5), b = 697.46(5), c = 1080.15(8) pm, α = 105.102(3), β = 90.931(3), γ = 100.034(3)°; Z = 2, space group: P1‾) displays three crystallographically different Yb3+ cations with coordination numbers of six, seven and eight. Six out of eight distinct oxygen atoms belong to two independent ψ1-tetrahedral [TeO3]2−anions, whereas the other two represent O2− anions in tetrahedral coordination of four Yb3+ cations each, not having any contact to tellurium. Condensed via common vertices and edges, these [OYb4]10+ tetrahedra form cationic layers ∞2{[O2Yb3]5+}, which spread out parallel to the (001) plane. Two discrete [TeO3]2− groups and one Br− anion per formula unit take care of their three-dimensional interconnection along [001] and the overall charge balance of Yb3O2Br[TeO3]2. Remarkable interactions between the lone pair of electrons at the Te4+ cations of the ψ1-tetrahedral [TeO3]2− anions and those at the Br− anions are discussed.

Keywords: crystal structure; oxide bromides; oxidotellurates; rare earth metals; X-ray diffraction

Gewidmet Professor Christian Robl zum 65. Geburtstag.

Corresponding author: Thomas Schleid, Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-06-30
Accepted: 2020-07-05
Published Online: 2020-08-21
Published in Print: 2020-09-25

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/znb-2020-0106
Keywords for this article
crystal structure; oxide bromides; oxidotellurates; rare earth metals; X-ray diffraction

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Research Articles
  4. Na2MgSnS4 – a new member of the A2IBIICIVX4 family of compounds
  5. Synthesis, crystal structure, luminescence, and photocatalytic properties of a 2D Cu(II) metal-organic frameworks based on 3,5-di(1H-benzimidazol-1-yl)pyridine and 4,4′-oxybis(benzoate) ligands
  6. Synthesis and structural characterization of a three-dimensional two-fold interpenetrated coordination polymer constructed from bis(4-(1H-imidazol-1-yl)phenyl)methanone and 1,1ʹ-biphenyl-2,2ʹ-dicarboxylate ligands for cadmium(II)
  7. Impact of aging on the hydration of tricalcium aluminate (C3A)/gypsum blends and the effectiveness of retarding admixtures
  8. Influence of meso-linker attachment on the formation of core···π interactions in urea-functionalized porphyrins
  9. Single-crystal investigation of Ce5AgxGe4−x (x = 0.1−1.08) with Sm5Ge4 type
  10. Wirt-Gast-Komplexe von [bfu.bfu.bfu]: Vorhersage von Ionenselektivitäten mittels quantenchemischer Rechnungen XIII
  11. Untersuchungen zur Polymorphie der Cäsium-Dodekahalogeno-closo-Dodekaborate Cs2[B12X12] (X = Cl–I)
  12. Das Ytterbium(III)-Oxidbromid-Oxidotellurat(IV) Yb3O2Br[TeO3]2
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  14. Sc14Co3.10In2.59 – the representative of the Lu14Co3In3 type with the smallest rare earth element
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