Covalent linkage of [Mn2(μ-O2PPh2)2] units by trans-1,4-bis(4-pyridyl)ethene ligands into one-dimensional and two-dimensional polymers
-
Ying Zhang
,
Jing-Jing Zhang
Abstract
Two coordination polymers, [Mn2(μ-O2PPh2)2(η1-O2PPh2)2(η1-HOCH3)2(μ-bpe)2·CH3OH]n (1) and [Mn2(μ-O2PPh2)4(μ-bpe)2]n (2), were assembled in single-pot reactions from [Mn(CH3COO)2·4H2O], Ph2P(O)OK and trans-1,4-bis(4-pyridyl)ethene (bpe). The products were characterized by single-crystal X-ray diffraction, which revealed a one-dimensional metal-organic ladder type in 1 and a two-dimensional rectangular grid type in 2. Both 1 and 2 are constructed from six-coordinate Mn(II) nodes that adopt distorted octahedral (MnN4O2) environments; the adjacent nodes are connected by the μ-bpe linkers in 1 or μ-bpe and μ-O2PPh2 linkers in 2 to form different metal-organic networks. The catalytic property of complex 1 for selective thioether oxidation was also investigated in this work.
Acknowledgement
This project was supported by the Natural Science Foundation of China (21471003).
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Articles in the same Issue
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Articles in the same Issue
- Frontmatter
- In this Issue
- An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand
- Bis-heterocycles. Part I: tetrahydro-5,5′- bi(1,2,4-triazin-6-ones)
- Aminkomplexe des Goldes, Teil 11a: Strukturen zweier (Methylamin)gold(I)-Komplexe
- Single-crystal structure of pyrite-type HP-Pd0.84(1)Se2 prepared by high-pressure/ high-temperature synthesis
- Rare earth-copper-magnesium intermetallics: crystal structure of CeCuMg, magnetocaloric effect of GdCuMg and physical properties of the Laves phases RECu4Mg (RE=Sm, Gd, Tb, Tm)
- Microwave-assisted solvent-free synthesis and spectral and structural characterization of cyclotriphosphazene hexakis(o-tolylamide)
- Selenium analogs of phenoxypropionic and phenoxyacetic herbicides
- Rare earth-rhodium-plumbides RE2Rh2Pb with RE = La–Nd, Sm, Gd and Tb
- Covalent linkage of [Mn2(μ-O2PPh2)2] units by trans-1,4-bis(4-pyridyl)ethene ligands into one-dimensional and two-dimensional polymers
- Note
- Crystal and molecular structure of trans-[RhCl(CO)(PtBu2Ph)2]
