Solvothermal Syntheses, Crystal Structures of Two New Thioantimonates(III) of the Mn2(L)Sb2S5 Family with L = Diethylenetriamine and N-Methyl-1,3-Diaminopropane and a Study of the Magnetic Properties of Four Compounds of the Series
-
L. Engelke
,
R. Pöttgen
Abstract
The two new compounds Mn2(L)Sb2S5 (L = diethylenetriamine = DIEN, N-methyl-1,3- diaminopropane = MDAP) were prepared under solvothermal conditions using the elements as starting materials. Both compounds crystallise in the monoclinic space group P21/c with the lattice parameters a=10.669(7), b=12.805(2), c=12.072(1)Å , β =115.786(7)°,V =1485.1(4) Å3 for L = DIEN and a = 10.1859(7), b = 12.7806(6), c = 12.1256(8)Å , β = 110.173(8)°, V = 1481.7(2) Å3 for L = MDAP and Z = 4. The primary building units are SbS3 pyramids, MnS6 and MnS4N2 distorted octahedra. These primary building blocks are interconnected to form Mn2Sb2S4 hetero-cubane units. The hetero-cubanes share common corners, edges and faces thus forming a second heterocubane. These secondary building units are joined to form layers within the (100) plane. The connection mode yields ellipsoidal pores within the layers. The amines are exclusively bound to one of the two crystallographically independent Mn2+ cations and they point into the pores and between the layers separating the layers from each other. The interlayer separation and the size of the pores depend on the sterical requirements of the amine incorporated into the network. A pronounced distortion of the MnS4N2 octahedron results from a significant elongation of one Mn-S distance from 2.866 Å (L = methylamine, MA) to 3.185 Å for L = MDAP. The magnetic susceptibility curves are typical for low-dimensional antiferromagnetic materials and the large negative values for the Weiss constant Θ indicate strong antiferromagnetic exchange interactions. The magnetic properties are significantly influenced by the change of the Mn-S bonds introduced by the different amines. The compounds decompose at elevated temperatures with a two step reaction for L = MA and ethylenediamine and in a one step reaction for the bidentate acting amine molecules.
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
Articles in the same Issue
- The Structure of the Ligand Tri(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)3, in the Hexafluoroacetylacetonato Copper(I) Complexes, (hfac)Cu[P(C7H7)3]n (n = 1, 2)
- Homoleptic Nickel(0) Phenyl Isocyanide Complexes
- Formation of an Iron(III) Oxo Cubane Core Fe4(μ4-O)4 from FeCl3 and the Unsymmetrical Tripodal Ligand N[(CH2CH2NH2)(CH2CH2OH)(CH2CH2CH2OH)]
- A Second Modification of Mercury(I) Orthoarsenate(V): Preparation and Crystal Structure of β-(Hg2)3(AsO4)2
- Metal Complexes of Biologically Important Ligands, CLV [1]. Some Derivatives of 4-Ethynylphenylalanine
- Solvothermal Syntheses, Crystal Structures of Two New Thioantimonates(III) of the Mn2(L)Sb2S5 Family with L = Diethylenetriamine and N-Methyl-1,3-Diaminopropane and a Study of the Magnetic Properties of Four Compounds of the Series
- Development of A Novel Solid-State pH Sensor Based on Tin Oxide Thin Film
- Oxotellurate(IV) der Lanthanide: I. Die isotype Reihe M2Te4O11 (M = La – Nd, Sm – Yb)
- Optically Active Transition Metal Compounds, 136 [1]. An Octahedral Molybdenum Complex (P-P’)Mo(CO)4 with a Chiral Secondary Phosphorus Atom
- The Solid Solution TmNi1–x–yIn1+x
- The Synthesis, Crystal Structure and Spectroscopic Properties of a Dinuclear μ–Pyrazolato–N,N’–Bridged Dinickel(II) Complex of 1,3–Bis(salicylideneamino)propan–2–ol
- Über die Dialkaliacetylendicarboxylate Na2(C2(COO)2)(H2O)4 und K2(C2(COO)2)(H2O) / On Dialkali Acetylenedicarboxylates Na2(C2(COO)2)(H2O)4 and K2(C2(COO)2)(H2O)
- Ethenetetracarbonitrile and Heterocyclization of Symmetrical Dithiobiurea as well as Thioureidoethylthiourea Derivatives
- An Internally Coordinated Metalla[14]-crown-5 System with a Pentagonal-dipyramidal Coordination Geometry of the Central Titanium Atom
- Isolation, Characterization and Crystal Structure of Natural Eremophilenolide from Ligularia sagitta
- Protoilludane-Type Sesquiterpenes, Echinocidins A and B, from a Mycelial Culture of Echinodontium tsugicola
- Ring Size Influence on the Cyclocondensation Mode of GABA – Nitrile Imine Adducts
- Synthesis and Biological Evaluation of a “Natural” Insect Repellent
- The Hexagonal Laves Phase MgIr2
Articles in the same Issue
- The Structure of the Ligand Tri(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)3, in the Hexafluoroacetylacetonato Copper(I) Complexes, (hfac)Cu[P(C7H7)3]n (n = 1, 2)
- Homoleptic Nickel(0) Phenyl Isocyanide Complexes
- Formation of an Iron(III) Oxo Cubane Core Fe4(μ4-O)4 from FeCl3 and the Unsymmetrical Tripodal Ligand N[(CH2CH2NH2)(CH2CH2OH)(CH2CH2CH2OH)]
- A Second Modification of Mercury(I) Orthoarsenate(V): Preparation and Crystal Structure of β-(Hg2)3(AsO4)2
- Metal Complexes of Biologically Important Ligands, CLV [1]. Some Derivatives of 4-Ethynylphenylalanine
- Solvothermal Syntheses, Crystal Structures of Two New Thioantimonates(III) of the Mn2(L)Sb2S5 Family with L = Diethylenetriamine and N-Methyl-1,3-Diaminopropane and a Study of the Magnetic Properties of Four Compounds of the Series
- Development of A Novel Solid-State pH Sensor Based on Tin Oxide Thin Film
- Oxotellurate(IV) der Lanthanide: I. Die isotype Reihe M2Te4O11 (M = La – Nd, Sm – Yb)
- Optically Active Transition Metal Compounds, 136 [1]. An Octahedral Molybdenum Complex (P-P’)Mo(CO)4 with a Chiral Secondary Phosphorus Atom
- The Solid Solution TmNi1–x–yIn1+x
- The Synthesis, Crystal Structure and Spectroscopic Properties of a Dinuclear μ–Pyrazolato–N,N’–Bridged Dinickel(II) Complex of 1,3–Bis(salicylideneamino)propan–2–ol
- Über die Dialkaliacetylendicarboxylate Na2(C2(COO)2)(H2O)4 und K2(C2(COO)2)(H2O) / On Dialkali Acetylenedicarboxylates Na2(C2(COO)2)(H2O)4 and K2(C2(COO)2)(H2O)
- Ethenetetracarbonitrile and Heterocyclization of Symmetrical Dithiobiurea as well as Thioureidoethylthiourea Derivatives
- An Internally Coordinated Metalla[14]-crown-5 System with a Pentagonal-dipyramidal Coordination Geometry of the Central Titanium Atom
- Isolation, Characterization and Crystal Structure of Natural Eremophilenolide from Ligularia sagitta
- Protoilludane-Type Sesquiterpenes, Echinocidins A and B, from a Mycelial Culture of Echinodontium tsugicola
- Ring Size Influence on the Cyclocondensation Mode of GABA – Nitrile Imine Adducts
- Synthesis and Biological Evaluation of a “Natural” Insect Repellent
- The Hexagonal Laves Phase MgIr2
