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Kristallzucht und Strukturaufklärung von K2[Pt(CN)4Cl2], K2[Pt(CN)4Br2], K2[Pt(CN)4I2] und K2[Pt(CN)4Cl2] · 2H2O/ Crystal Growth and Crystal Structure Determination of K2[Pt(CN)4Cl2], K2[Pt(CN)4Br2], K2[Pt(CN)4I2] and K2[Pt(CN)4]Cl2] · 2H2O
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Claus Mühle
Veröffentlicht/Copyright:
2. Juni 2014
Abstract
Crystals of K2Pt(CN)4Br2, K2Pt(CN)4I2 and K2Pt(CN)4Cl2 ·2H2O were grown, and their crystal structures have been determined from single crystal data. The structure of K2Pt(CN)4Cl2 has been determined and refined from X-ray powder data. All compounds crystallize monoclinicly (P21/c; Z = 2), and K2Pt(CN)4X2 with X = Cl, Br, I are isostructural. K2Pt(CN)4Cl2: a = 708.48(2); b = 903.28(3); c = 853.13(3) pm; β = 106.370(2)°; Rp = 0.064 (N(hkl) = 423). K2Pt(CN)4Br2: a = 716.0(1); b = 899.1(1); c = 867.9(1) pm; β = 106.85(1)°; R(F)N′ = 0.026 (N’(hkl) = 3757). K2Pt(CN)4I2: a = 724.8(1); b = 914.5(1); c = 892.1(1) pm; β = 107.56(1)°; R(F)N′ = 0.025 (N’(hkl) = 2197). K2Pt(CN)4Cl2 ·2H2O: a = 763.76(4); b = 1143.05(6); c = 789.06(4) pm; β = 105.18(1)°; R(F)N′ = 0.021 (N’(hkl) = 2281). Raman and infrared spectroscopy data are reported.
Keywords: Dipotassium Tetracyanoplatinate(IV) Dihalides; Platinum Cyanides; Crystal Structures; X-Ray Scattering; Vibrational Spectroscopy
Received: 2004-2-6
Published Online: 2014-6-2
Published in Print: 2004-5-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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Schlagwörter für diesen Artikel
Dipotassium Tetracyanoplatinate(IV) Dihalides;
Platinum Cyanides;
Crystal Structures;
X-Ray Scattering;
Vibrational Spectroscopy
Artikel in diesem Heft
- ERRATUM
- Tris-N-(N′,N′,N″,N″-tetramethylguanidyl)phosphine Oxide – Synthesis and Reaction with Acids
- Neue Barium-Oxoantimonate(III): Darstellung und Kristallstruktur von Ba3[SbO3]2 und Ba2[Sb2O5]/New Barium Oxoantimonates(III): Synthesis and Crystal Structures of Ba3[SbO3]2 and Ba2[Sb2O5]
- Ternary Indides REMgIn (RE = Y, La–Nd, Sm, Gd–Tm, Lu). Synthesis, Structure and Magnetic Properties
- Magnetic Films of Cobalt/Aluminum Electrodeposited from the Room Temperature Molten Salts AlCl3-BPC-CoCl2
- Synthese und Struktur von Meldrums Olefin/Synthesis and Structure of Meldrum’s Olefin
- Crystal Structure and Magnetic Properties of a Novel CuIINdIII Heterodinuclear Schiff Base Complex
- Magnetic Properties and Crystal Structure of a CuIIGdIII Heterodinuclear Schiff Base Complex
- The Pd(II) Complex of a Bidentate Di(benzimidazol-2-ylidene) Ligand
- Cleavage of a Dibenzotetraazafulvalene to Yield a Rh(I) Carbene Complex
- Chemistry of C6F5SeLi and C6F5SeCl: Precursors to New Pentafluorophenylselenium(II) Compounds
- Synthesis and Characterization of Diarylthiourea Derivatives of Tungsten Carbonyl
- Eine neue Modifikation von Lanthanmonogermanid – lT-LaGe /A New Modification of Lanthanummonogermanide – lT-LaGe
- Divalent Europium in 1∞[Eu(Pz)2(Pz-H)2]: The First Unsubstituted Pyrazolate and Cp Analogous Pyrazole Complex of a Rare Earth Element in One
- Kristallzucht und Strukturaufklärung von K2[Pt(CN)4Cl2], K2[Pt(CN)4Br2], K2[Pt(CN)4I2] und K2[Pt(CN)4Cl2] · 2H2O/ Crystal Growth and Crystal Structure Determination of K2[Pt(CN)4Cl2], K2[Pt(CN)4Br2], K2[Pt(CN)4I2] and K2[Pt(CN)4]Cl2] · 2H2O
- Dinuclear Ruthenium(I)Triazenide Complexes as Catalysts for Carbenoid Cyclopropanation Reactions
- Enzyme Inhibiting Terpenoids from Amberboa ramosa
- A New Clerodane Diterpene and Other Constituents from Ajuga chamaepitys ssp. laevigata
- Convenient Route to Efavirenz Analogues as Potential non-Nucleoside HIV-1 Reverse Transcriptase Inhibitors
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- Solvent-Free Synthesis of 2,4,6-Triaryl Pyridines
- Iridoid and Phenylethanoid Glycosides from Phlomis nissolii and P. capitata
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