Home Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von (n-Bu4N)2[Pt(SCN)n(ox)], n = 2, 4, sowie Kristallstruktur von [(C5H5N)2CH2][Pt(SCN)4(ox)] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of (n-Bu4N)2[Pt(SCN)n(ox)], n = 2, 4, and Crystal Structure of [(C5H5N)2CH2][Pt(SCN)4(ox)]
Article
Licensed
Unlicensed Requires Authentication

Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von (n-Bu4N)2[Pt(SCN)n(ox)], n = 2, 4, sowie Kristallstruktur von [(C5H5N)2CH2][Pt(SCN)4(ox)] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of (n-Bu4N)2[Pt(SCN)n(ox)], n = 2, 4, and Crystal Structure of [(C5H5N)2CH2][Pt(SCN)4(ox)]

  • J.-G. Uttecht , C. Nöther and W. Preetz EMAIL logo
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 57 Issue 9

On exposure of trans-(n-Bu4N)2[Pt(SCN)2(ox)2] to photochemical reduction (n-Bu4N)2- [Pt(SCN)2(ox)] (1) is formed. Further treatment with (SCN)2 yields (n-Bu4N)2- [Pt(SCN)4(ox)] (2). The X-ray structure determination on a single crystal was performed of [(C5H5N)2CH2][Pt(SCN)4 (ox)] (triclinic, space group P1̅, a = 9.823(1), b = 14.850(1), c = 15.799(1) Å , α= 74.304(9), β= 86.268(9), γ= 87.455(9)°, Z = 4). Based on the molecular parameters of the X-ray determination the IR and Raman spectra have been assigned by normal coordinate analysis. The valence force constants of the symmetric axis S-Pt-S and of the asymmetrically coordinated S'-Pt-O* axes are fd(PtS) = 1.71, fd(PtS') = 1.92 (1), fd(PtS') = 2.02 (2) and fd(PtO•) = 2.45 (1) and 2.24 (2) mdyn/Å. Taking into account increments of the trans influence a good agreement between observed and calculated frequencies is achieved. The NMR shifts are δ(195Pt) = 1967.7 (1) and 2930.8 ppm (2)

Keywords: Di(thiocyanato)oxalatoplatinate(II); Tetra(thiocyanato)oxalatoplatinate(IV); Vibrational Spectra
Received: 2002-5-10
Published Online: 2014-6-2
Published in Print: 2002-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Alkalimetall-Arsenide A3As7 Und Aas (A = K, Rb, Cs). Synthesen, Kristallstrukturen, Schwingungsspektren / Alkaline Metal Arsenides A3As7 and AAs (A = K, Rb, Cs). Preparation, Crystal Structure, Vibrational Spectroscopy
  2. Synthesen und Kristallstrukturen von Bis(N-lithiumtrimethylsilylamino)- bis(dimethylamino)silan und 1,1-Dichloro-2,4-bis(trimethylsilylamino)- 3,3-bis(dimethylamino)siladiazatitanacyclobutan / Syntheses and Crystal Structures of Bis(N-lithio-trimethylsilylamino)bis(dimethylamino)- silane and 1,1-Dichloro-2,4-bis(trimethylsilylamino)-3,3-bis(dimethylamino)siladiazatitanacyclobutane
  3. Valence Bond Studies of N5+
  4. Synthesis and Characterization of Chromium Tricarbonyl Complexes of 1-Phenylgermatrane and 1-Phenylazagermatrane. Crystal Structure of [N(CH2CH2O)3GeC6H5]Cr(CO)3
  5. Synthesis and Structural Characterization of [Cu(NH2CH2C6H4N=CHC5H5N)Cl2]
  6. Die Kristallstruktur von Bis-[methylammonium]-hexafluorosilikat, (MeNH3)2SiF6 / The Crystal Structure of Bis-[methylammonium]-hexafluorosilicate, (MeNH3)2SiF6
  7. New Phosphorus-Containing Polycylic Large-Ring Systems Involving Heteroatoms
  8. Bis[dicarbonyl(cyclopentadienyl)ruthenium(I)] Komplexe / Bis[dicarbonyl(cyclopentadienyl)ruthenium(I)] Complexes
  9. Zur Reaktion von PCl3 mit NaR*, KR* und ZnR*2 (R* = SitBu3) [1]: Bildung des Diphosphens R*P=PR*, Tetraphosphans P4R*2 , Tetraphosphanids NaP4R*3 sowie von Halogenphosphanen R*mPmClp / On the Reaction of PCl3 with NaR*, KR* and ZnR*2 (R*= SitBu3) [1]: Formation of the Diphosphene R*P=PR*, Tetraphosphane P4R*2, Tetraphosphanide NaP4R*3 as well as Halogenophosphanes R*mPnClp
  10. Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von (n-Bu4N)2[Pt(SCN)n(ox)], n = 2, 4, sowie Kristallstruktur von [(C5H5N)2CH2][Pt(SCN)4(ox)] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of (n-Bu4N)2[Pt(SCN)n(ox)], n = 2, 4, and Crystal Structure of [(C5H5N)2CH2][Pt(SCN)4(ox)]
  11. Hydrothermal Single Crystal Growth and Crystal Structures of the Mercury(II) Selenates(VI) HgSeO4, HgSeO4·HgO and HgSeO4·2HgO
  12. Polysulfonylamine, CLVII [1]. Molekulare Cokristalle aus Di(4-halogenbenzolsulfonyl)aminen und Sauerstoffbasen: Lamellare Schichten mit engen Zwischenschichtkontakten der Art C-H···Hal, Cl ··· Cl oder Br ··· Br / Molecular Co-crystals of Di(4-halobenzenesulfonyl)amines and Oxygen Bases: Lamellar Layers with Close C-H···Hal, Cl · · · Cl or Br · · · Br
  13. New Bioactive Diterpenoid from Euphorbia decipiens
  14. Magnesium Isotope Effects by Ion Exchange Using Monoazacrown Bonded Merrifield Peptide Resin
https://doi.org/10.1515/znb-2002-0910
Keywords for this article
Di(thiocyanato)oxalatoplatinate(II); Tetra(thiocyanato)oxalatoplatinate(IV); Vibrational Spectra

Articles in the same Issue

  1. Alkalimetall-Arsenide A3As7 Und Aas (A = K, Rb, Cs). Synthesen, Kristallstrukturen, Schwingungsspektren / Alkaline Metal Arsenides A3As7 and AAs (A = K, Rb, Cs). Preparation, Crystal Structure, Vibrational Spectroscopy
  2. Synthesen und Kristallstrukturen von Bis(N-lithiumtrimethylsilylamino)- bis(dimethylamino)silan und 1,1-Dichloro-2,4-bis(trimethylsilylamino)- 3,3-bis(dimethylamino)siladiazatitanacyclobutan / Syntheses and Crystal Structures of Bis(N-lithio-trimethylsilylamino)bis(dimethylamino)- silane and 1,1-Dichloro-2,4-bis(trimethylsilylamino)-3,3-bis(dimethylamino)siladiazatitanacyclobutane
  3. Valence Bond Studies of N5+
  4. Synthesis and Characterization of Chromium Tricarbonyl Complexes of 1-Phenylgermatrane and 1-Phenylazagermatrane. Crystal Structure of [N(CH2CH2O)3GeC6H5]Cr(CO)3
  5. Synthesis and Structural Characterization of [Cu(NH2CH2C6H4N=CHC5H5N)Cl2]
  6. Die Kristallstruktur von Bis-[methylammonium]-hexafluorosilikat, (MeNH3)2SiF6 / The Crystal Structure of Bis-[methylammonium]-hexafluorosilicate, (MeNH3)2SiF6
  7. New Phosphorus-Containing Polycylic Large-Ring Systems Involving Heteroatoms
  8. Bis[dicarbonyl(cyclopentadienyl)ruthenium(I)] Komplexe / Bis[dicarbonyl(cyclopentadienyl)ruthenium(I)] Complexes
  9. Zur Reaktion von PCl3 mit NaR*, KR* und ZnR*2 (R* = SitBu3) [1]: Bildung des Diphosphens R*P=PR*, Tetraphosphans P4R*2 , Tetraphosphanids NaP4R*3 sowie von Halogenphosphanen R*mPmClp / On the Reaction of PCl3 with NaR*, KR* and ZnR*2 (R*= SitBu3) [1]: Formation of the Diphosphene R*P=PR*, Tetraphosphane P4R*2, Tetraphosphanide NaP4R*3 as well as Halogenophosphanes R*mPnClp
  10. Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von (n-Bu4N)2[Pt(SCN)n(ox)], n = 2, 4, sowie Kristallstruktur von [(C5H5N)2CH2][Pt(SCN)4(ox)] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of (n-Bu4N)2[Pt(SCN)n(ox)], n = 2, 4, and Crystal Structure of [(C5H5N)2CH2][Pt(SCN)4(ox)]
  11. Hydrothermal Single Crystal Growth and Crystal Structures of the Mercury(II) Selenates(VI) HgSeO4, HgSeO4·HgO and HgSeO4·2HgO
  12. Polysulfonylamine, CLVII [1]. Molekulare Cokristalle aus Di(4-halogenbenzolsulfonyl)aminen und Sauerstoffbasen: Lamellare Schichten mit engen Zwischenschichtkontakten der Art C-H···Hal, Cl ··· Cl oder Br ··· Br / Molecular Co-crystals of Di(4-halobenzenesulfonyl)amines and Oxygen Bases: Lamellar Layers with Close C-H···Hal, Cl · · · Cl or Br · · · Br
  13. New Bioactive Diterpenoid from Euphorbia decipiens
  14. Magnesium Isotope Effects by Ion Exchange Using Monoazacrown Bonded Merrifield Peptide Resin
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 14.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/znb-2002-0910/html?lang=en
Scroll to top button