Home Diphenyl(2-hydroxy-phenyl)phosphine and its Trimethylsilyl Ether as Ligands for Gold(I) Complexes
Article
Licensed
Unlicensed Requires Authentication

Diphenyl(2-hydroxy-phenyl)phosphine and its Trimethylsilyl Ether as Ligands for Gold(I) Complexes

  • Christian Hollatz , Annette Schier and Hubert Schmidbaur
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 1

Diphenyl(2-hydroxy-phenyl)phosphine was introduced as a ligand for gold(I) halides and pentafluorophenyl gold(I) in order to probe the interplay of intra- and intermolecular interactions based on aurophilic (Au· · ·Au) and hydrogen bonding. 1:1 complexes of the type Ph2(2-HO-C6H4)P-Au-X with X = Cl, Br, C6F5 have been prepared and characterized by analytical and spectroscopic data. The crystal structure of the chloro complex (1) has been determined. In the lattice the molecules form dimers through O-H· · ·Cl hydrogen bonds. Au· · ·Au contacts are ruled out by steric congestion. Reaction of 1 with triethylamine yields a 1:1 adduct with O-H· · ·NEt3 hydrogen bonding. The trimethylsilyl ether of the title ligand also forms 1:1 complexes with AuCl, AuBr, Aul, and AuC6F5. The crystal structures of the chloro (5) and iodo (7) compound have been determined. In both cases the lattices are built from monomers which show only minor differences in their conformations. The silylether groups are not acting as intra- or intermolecular donor functions to the gold atoms.

Keywords: Gold(I) Complexes; Phosphine Ligands; Diphenyl(2-hydroxy-phenyl)phosphine; Hydrogen Bonding; Trimethylsilyl Ether
Received: 1988-11-19
Published Online: 2014-6-2
Published in Print: 1999-1-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Titelei
  2. Contents
  3. Reduktion eines Bis(chlorphenylphosphanyl)methylids zum entsprechenden Diphosphan und Tetraphosphinan Reduction of a Bis(chlorophenylphosphanyl)methylide to the Corresponding Diphosphane and Tetraphosphinane
  4. Pentacoordinated Nitrogen Atoms in the Structure of Hexalithium Bis[methylsilyl-tris(methylimide)] Hexakis(tetrahydrofuran)
  5. Synthesis and Molecular Structures of 2-Trimethylsilyl-, 2-Trimethylgermyl-, and 2-Trimethylstannyl-pyridines
  6. The Stereochemistry of Chloro-bis(N-morpholino)phenylsilane
  7. Indium Triiodide Complexes of Bis(diphenyIphosphino)ethane (dppe) and its Disulfide (dppeS2)
  8. (Tnmethylphosphine)(triphenylsilyl)gold(I) and Related Compounds
  9. Diphenyl(2-hydroxy-phenyl)phosphine and its Trimethylsilyl Ether as Ligands for Gold(I) Complexes
  10. SrRhIn2, SrPdIn2, SrIrIn2, and SrPtIn2 – New Intermetallic Compounds with a Filled Variant of the CaIn2 Structure
  11. The Intermetallic Zirconium Compounds ZrNiAl, ZrRhSn, and ZrPtGa - Structural Distortions and Metal-Metal Bonding in Fe2P Related Compounds
  12. Darstellung und Kristallstruktur von [OsFPy5][BF4] · H2O · CH2Cl2/Synthesis and Crystal Structure of [OsFPy5][BF4] · H2O · CH2Cl2
  13. 1,3-Distanna-2-phospha-[3]ferrocenophanes - Synthesis, Reactivity and NMR Spectroscopic Properties
  14. Oligonuclear Tricarbonylchromium- and Tricarbonyltungsten Derivatives of Tris(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)3, and Related Ligands
  15. Oxidative S-S-Kopplung von 1,2-Dithiooxalat durch intramolekulare Redoxreaktion der Selen(II)- und Tellur(II)-Komplexe/Oxidative S-S Coupling of 1,2-Dithiooxalate by Intramolecular Redox Reaction of the Selenium (II) and Tellurium(II) Complexes
  16. Donor-Akzeptor-Komplexe von Halogenidionen mit 1.4-Diiodtetrafluorbenzol/Donor-Acceptor Complexes of Halide Ions with 1,4-Diiodotetrafluorobenzene
  17. Darstellung enantiomerenreiner 3-Oxa-2,7-diazabicyclo[3.3.0]octane und ihre Umwandlung in andere bicyclische Ringsysteme/Preparation of Pure Enantiomeric 3-Oxa-2,7-diazabicyclo[3.3.0]octanes and their Conversion to Other Bicyclic Ring-Systems
  18. Metallkomplexe mit biologisch wichtigen Liganden, CXI. Phosphan-Gold(I), -Nickel(II) und -Platin(II) Komplexe mit dem Anion von Hydantoin und 3,4-Pyridindicarbonsäureimid/Metal Complexes of Biologically Important Ligands, CXI. Phosphine Gold(I), Nickel(II) and Platinum(II) Complexes with the Anion of Hydantoin and of 3,4 Pyridine Dicarboxylic Imide
  19. Di- bis Pentahydrate von fünf Alkylendiaminen. Eine Fallstudie zu ein- und zweidimensionalen Wasserpolymeren in Festkörpern/Di- to Pentahydrates of Five Alkylenediamines. A Case Study of One- and Two-Dimensional Water Polymers in Solids
  20. Excitonic Bands in the Optical Absorption Spectra of (Bu4N)CuBr2, (Et4N)2Cu2Br4, (Pr4N)2Cu4Br6, (Bu4N)2Cu2I4, (Me4N)Cu2I3, (Pr4N)4Ag4I8, (Me4N)Ag2I3, (Et4N)Ag2Br3, and Similar Compounds
  21. Synthesen und Kristallstrukturen von Tris(di-n-propylamino)-p-brombenzylphosphonium-bromiden: [(C3H7)2N]3PCH2C6H4Br+Br- und [(C3H7)2N]3PCH2C6H4Br+Br3-/Syntheses and Crystal Structures of Tris(di-n-propylamino)-p-bromobenzyl-phosphonium Bromides: [(C3H7)2N]3PCH2C6H4Br+Br- and [(C3H7)2N]3PCH2C6H4Br+Br3-
  22. Kristallstrukturen von Octacyanomolybdaten(IV). V. Quadratisch-antiprismatische [Mo(CN)8]-Koordination in den cyanoverbrückten Kupfer- und Cadmium-Amminkomplexen Cu2(NH3)8[Mo(CN)8] und Cd2(NH3)6[Mo(CN)8]·H2O/Crystal Structures of Octacyanomolybdates(IV). V. Square Antiprismatic [Mo(CN)8]-Coordination of the Cyano-Bridged Copper and Cadmium Ammine Complexes Cu2(NH3)8[Mo(CN)8] and Cd2(NH3)6[Mo(CN)8]·H2O
  23. Zu den Phasenbeziehungen im System V/Nb/O, IV. Die Festelektrolyt-Coulometrie (FEC) als Methode zur Aufklärung ternärer Zustandsgebiete am Beispiel des Systems V/Nb/O/The Phase Relations in the System V/Nb/O, IV. Solid Electrolytic Coulometry (SEC) as a Method to Investigate Ternary Systems: V/Nb/O
  24. Synthesis of 2-Acetoxy-3,4,5-trihydro-azepino[2,3-b]indoles and 2-Acetoxy-1-acetylamino-3,4-dihydrocarbazoles
  25. Notizen: Untersuchungen an Polyhalogeniden, XXXIX. [(H3O)(18-Krone-6)]I7, eine Struktur-Neubestimmung/Studies on Polyhalides, XXXIX. Structure Refinement of [(H3O)(18-crow n-6)]I7
  26. Synthese und Kristallstruktur von PPh4[PhICl3]/Synthesis and Crystal Structure of PPh4[PhICl3]
https://doi.org/10.1515/znb-1999-0109
Keywords for this article
Gold(I) Complexes; Phosphine Ligands; Diphenyl(2-hydroxy-phenyl)phosphine; Hydrogen Bonding; Trimethylsilyl Ether

Articles in the same Issue

  1. Titelei
  2. Contents
  3. Reduktion eines Bis(chlorphenylphosphanyl)methylids zum entsprechenden Diphosphan und Tetraphosphinan Reduction of a Bis(chlorophenylphosphanyl)methylide to the Corresponding Diphosphane and Tetraphosphinane
  4. Pentacoordinated Nitrogen Atoms in the Structure of Hexalithium Bis[methylsilyl-tris(methylimide)] Hexakis(tetrahydrofuran)
  5. Synthesis and Molecular Structures of 2-Trimethylsilyl-, 2-Trimethylgermyl-, and 2-Trimethylstannyl-pyridines
  6. The Stereochemistry of Chloro-bis(N-morpholino)phenylsilane
  7. Indium Triiodide Complexes of Bis(diphenyIphosphino)ethane (dppe) and its Disulfide (dppeS2)
  8. (Tnmethylphosphine)(triphenylsilyl)gold(I) and Related Compounds
  9. Diphenyl(2-hydroxy-phenyl)phosphine and its Trimethylsilyl Ether as Ligands for Gold(I) Complexes
  10. SrRhIn2, SrPdIn2, SrIrIn2, and SrPtIn2 – New Intermetallic Compounds with a Filled Variant of the CaIn2 Structure
  11. The Intermetallic Zirconium Compounds ZrNiAl, ZrRhSn, and ZrPtGa - Structural Distortions and Metal-Metal Bonding in Fe2P Related Compounds
  12. Darstellung und Kristallstruktur von [OsFPy5][BF4] · H2O · CH2Cl2/Synthesis and Crystal Structure of [OsFPy5][BF4] · H2O · CH2Cl2
  13. 1,3-Distanna-2-phospha-[3]ferrocenophanes - Synthesis, Reactivity and NMR Spectroscopic Properties
  14. Oligonuclear Tricarbonylchromium- and Tricarbonyltungsten Derivatives of Tris(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)3, and Related Ligands
  15. Oxidative S-S-Kopplung von 1,2-Dithiooxalat durch intramolekulare Redoxreaktion der Selen(II)- und Tellur(II)-Komplexe/Oxidative S-S Coupling of 1,2-Dithiooxalate by Intramolecular Redox Reaction of the Selenium (II) and Tellurium(II) Complexes
  16. Donor-Akzeptor-Komplexe von Halogenidionen mit 1.4-Diiodtetrafluorbenzol/Donor-Acceptor Complexes of Halide Ions with 1,4-Diiodotetrafluorobenzene
  17. Darstellung enantiomerenreiner 3-Oxa-2,7-diazabicyclo[3.3.0]octane und ihre Umwandlung in andere bicyclische Ringsysteme/Preparation of Pure Enantiomeric 3-Oxa-2,7-diazabicyclo[3.3.0]octanes and their Conversion to Other Bicyclic Ring-Systems
  18. Metallkomplexe mit biologisch wichtigen Liganden, CXI. Phosphan-Gold(I), -Nickel(II) und -Platin(II) Komplexe mit dem Anion von Hydantoin und 3,4-Pyridindicarbonsäureimid/Metal Complexes of Biologically Important Ligands, CXI. Phosphine Gold(I), Nickel(II) and Platinum(II) Complexes with the Anion of Hydantoin and of 3,4 Pyridine Dicarboxylic Imide
  19. Di- bis Pentahydrate von fünf Alkylendiaminen. Eine Fallstudie zu ein- und zweidimensionalen Wasserpolymeren in Festkörpern/Di- to Pentahydrates of Five Alkylenediamines. A Case Study of One- and Two-Dimensional Water Polymers in Solids
  20. Excitonic Bands in the Optical Absorption Spectra of (Bu4N)CuBr2, (Et4N)2Cu2Br4, (Pr4N)2Cu4Br6, (Bu4N)2Cu2I4, (Me4N)Cu2I3, (Pr4N)4Ag4I8, (Me4N)Ag2I3, (Et4N)Ag2Br3, and Similar Compounds
  21. Synthesen und Kristallstrukturen von Tris(di-n-propylamino)-p-brombenzylphosphonium-bromiden: [(C3H7)2N]3PCH2C6H4Br+Br- und [(C3H7)2N]3PCH2C6H4Br+Br3-/Syntheses and Crystal Structures of Tris(di-n-propylamino)-p-bromobenzyl-phosphonium Bromides: [(C3H7)2N]3PCH2C6H4Br+Br- and [(C3H7)2N]3PCH2C6H4Br+Br3-
  22. Kristallstrukturen von Octacyanomolybdaten(IV). V. Quadratisch-antiprismatische [Mo(CN)8]-Koordination in den cyanoverbrückten Kupfer- und Cadmium-Amminkomplexen Cu2(NH3)8[Mo(CN)8] und Cd2(NH3)6[Mo(CN)8]·H2O/Crystal Structures of Octacyanomolybdates(IV). V. Square Antiprismatic [Mo(CN)8]-Coordination of the Cyano-Bridged Copper and Cadmium Ammine Complexes Cu2(NH3)8[Mo(CN)8] and Cd2(NH3)6[Mo(CN)8]·H2O
  23. Zu den Phasenbeziehungen im System V/Nb/O, IV. Die Festelektrolyt-Coulometrie (FEC) als Methode zur Aufklärung ternärer Zustandsgebiete am Beispiel des Systems V/Nb/O/The Phase Relations in the System V/Nb/O, IV. Solid Electrolytic Coulometry (SEC) as a Method to Investigate Ternary Systems: V/Nb/O
  24. Synthesis of 2-Acetoxy-3,4,5-trihydro-azepino[2,3-b]indoles and 2-Acetoxy-1-acetylamino-3,4-dihydrocarbazoles
  25. Notizen: Untersuchungen an Polyhalogeniden, XXXIX. [(H3O)(18-Krone-6)]I7, eine Struktur-Neubestimmung/Studies on Polyhalides, XXXIX. Structure Refinement of [(H3O)(18-crow n-6)]I7
  26. Synthese und Kristallstruktur von PPh4[PhICl3]/Synthesis and Crystal Structure of PPh4[PhICl3]
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 29.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/znb-1999-0109/html
Scroll to top button