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Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers

  • Dirk Steinborn , Olaf Gravenhorst , Henrik Junicke and Frank W. Heinemann
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 53 Issue 5-6

Abstract

Crown ether complexed pentachloro(aqua)platinic acid, (H3O)[PtCl5(H2O)]·2(18-cr-6)·6H2O (1) reacts with glycine, L-alanine, and DL-2-aminobutyric acid to give cis-[PtCl4(O-glyH)(H2O)]·(18-cr-6)·H2O (4a)1 and cis-[PtCl4(O-amacH)(H2O)]·(18-cr-6) (amacH = alaH 4b, abuH 4c), respectively, as well as (amacH2)2[PtCl6]·2(18-cr-6) (amacH = glyH 5a, alaH 5b, abuH 5c). The crown ether complexed hexachloroplatinic acid, (H3O) 2[PtCl6]·2(18-cr-6) (2), reacts with glycine to afford (glyH2)[PtCl4(N,O-gly)]·2(18-cr-6)·1.25H2O (6).

The structures of 4b and 6 were determined by X-ray diffraction. The alanine ligand in 4b is a zwitterion that is coordinated to platinum by one oxygen atom of the carboxylate group only. The other oxygen atom is engaged in a strong hydrogen bond to the ds-coordinated aqua ligand. The glycinato ligand in 6 is N, O-coordinated at platinum forming an anion [PtCl4(N,O-gly)]- . The other oxygen atom of the carboxylate group is involved in a strong hydrogen bridge to the cation (glyH2)+. In both complexes hydrogen bridges are formed between the -N+H3 and -NH2 groups of the amino acid ligands and the oxygen atoms of the crown ether molecules.

Keywords: Platinum(IV) Complexes; Crown Ethers; Amino Acids; Crystal Structure
Received: 1998-1-16
Published Online: 2014-6-2
Published in Print: 1998-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Darstellung und Strukturbeschreibung von NaCa3 Mn(V2O7)(V3O10) / Preparation and Structure of NaCa3Mn(V2O7)(V3O10)
  2. Ba4Mn2Ag2O(As04)4 , ein Barium-Mangan-Oxid-Arsenat mit nichtlinearen O-Ag-O-Hanteln / Ba4Mn2Ag2O(AsO4)4, a Barium Manganese Oxide-Arsenate Showing Nonlinear O-Ag-O Dumbbells
  3. Indium partiell in tetraedrischer Sauerstoffkoordination in BaIn2Zn3O7. Eine Betrachtung zum Ba2Ln2Zn8O13/BaLnAlZn3O7 -Typ / Partial Tetrahedral Oxygen Coordination of Indium in BaIn2Zn3O7. A Consideration of the Ba2Ln2Zn8O13/BaLnAlZn3O7 Type
  4. Zur Kenntnis eines Vanadyl-Oxocuprat-Phosphats CaCu(VO)(PO4)2 mit Cu2+ auf Positionen der VO2+-Ionen und einer kupferreicheren Phase CaCu1,13(VO)0,87(PO4)2 / On an Vanadyl Oxocuprate Phosphate CaCu(VO)(PO4)2 Containing Cu2+ at Positions of VO2+ Ions and a Copper Rich Phase CaCu1.13(VO)0.87(PO4)2
  5. Verknüpfung von (TeO6)6- und (TeO6)3(NiO6)3-Sechsringen durch TeNiO9-Oktaederdoppel in Pb3Ni4,5Te2,5O15 / Connection of (TeO6)6 and (TeO6)3(NiO6)3 Hexagons by TeNiO9 Octahedra Double in Pb3Ni4,5Te2,5O15
  6. Preparation and X-Ray Structure of 3,5-Dimethyl-1,4-dichloro-1,2,6- thiadiazine-1-oxide
  7. Pentafluoro[(4-methyl-1,4-bisazoniacy clohex-1 -yl)methy 1] germanate Hydrate: Synthesis and Crystal Structure of a Zwitterionic λ6Ge-Germanate with a GeF5C Framework
  8. Mesitylene Osmium(II) Complexes Containing the Functional Phosphane tBuP(CH2CO2Me)2 and Anionic Species Derived Thereof as Bi- and Tridentate Ligands
  9. Benzylgallium-Verbindungen. Die Kristallstrukturen von [Mg3Br2,4Cl1,6(OEt2)6][Ga(CH2Ph)4]2 · 0,5 Toluol und [(3,5-Me2C6H3CH2)2GaBr]2 / Benzylgallium Compounds. The Crystal Structures of [Mg3Br2,4Cl1,6(OEt2)6][Ga(CH2Ph)4]2 · 0.5 Toluene and [(3,5-Me2C6H3CH2)2GaBr]2
  10. Die Kristallstruktur von [Me3PN(H)PMe3]4l28, einem Polyiodid mit I3--, l82-- und I144--Ionen Crystal / Structure of [Me3PN(H)PMe3]4I28, a Polyiodide with I3-, I82- , and I 144- Ions
  11. In situ Neutron Diffraction on DxNb2O5
  12. The First Hydrogen Containing (Polyfluorocycloalken-l-yl)xenon(II) Salts
  13. Kristallstruktur von 1,1'-Dimethyl-4,4'-bipyridinium-octachlorodiantimonat(III) / Crystal Structure of 1,1'-Dimethyl-4,4'-bipyridinium-octachlorodiantimonate(III)
  14. Kristallstruktur des Doppelkomplexsalzes trans-(py2CH2)[Pt(OH)2(ox)2]transs-(py2CH2)[Pt(OH)(ox)2(H2O)]2·4H2O / Crystal Structure of the Double Complex Salt trans-(py2CH2)[Pt(OH)2(ox)2](H2O)]2·4H2O
  15. Tetrakis(sulfurdiimido)silane, -germane and -stannane
  16. Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
  17. Hydrido(acylphenolato)cobaIt(III)-Verbindungen mit Trimethylphosphan-Liganden / Hydrido(acylphenolato)cobalt(III) Compounds Containing Trimethylphosphane Ligands
  18. Onio-assistierte SN2-Reaktionen: Allgemeiner Zugang zu symmetrischen und unsymmetrischen geminal bisoniosubstituierten Methanderivaten / Onio-Assisted SN2-Reactions: General Access to Symmetrical and Unsymmetrical Geminally Bisonio Substituted Methane Derivatives
  19. Anodic Methoxylation of Isatin
  20. Neuartige Synthese und Molekülstruktur von Benzylkalium (thf) [KCH2C6H5]2 / Novel Synthesis and Molecular Structure of Benzyl Potassium (thf)[KCH2C6H5]2
  21. Weitere Verbindungen zum Ba6Nd2Al4O15-Typ: Ba4Nd4Zn3PtO15 und Ba4Eu4Zn3PtO15 / Further Compounds of the Ba6Nd2Al4O15 Type: Ba4Nd4Zn3PtO15 and Ba4Eu4Zn3PtO15
  22. Fe[B2P2O7(OH)5]: Ein neues Boro-phosphat mit unverzweigten Vierer-Einfach Tetraederketten / Fe[B2P2O7(OH)5]: A New Borophosphate Containing Non-Branched Tetrahedral Vierer-Einfach Chains
  23. Polysulfonylamine, CIII [1] Ein Hydroxylamin mit bemerkenswert kurzer O-N-B Bindung: Kristall- und Molekülstruktur von MeO-N(SO2Me)2 / Polysulfonylamines, C III [1] A Hydroxylamine with a Remarkably Short O-N Bond: Crystal and Molecular Structure of MeO-N(SO2Me)2
  24. 3,10,17,24-Tetra(1-methylethyl)-[29H,31H-tetrapyrido[2,3-b:2′,3′-g:2″-3″-I:2‴,3‴ -q]porphyrazinato-(2-)N29,N30,N31,N32]-nickel- [Eu(fod)3]4- Ein lösliches Pyridoporphyrazin / 3,10,17,24-Tetra(1-methylethyl)- [29H,31H-tetrapyrido[2,3-b:2′,3′-g:2″-3″-I:2‴,3‴-q]porphyrazinato-(2-)N29,N30,N31,N32]-nickel-[Eu(fod)3]4 - A Soluble Pyridoporphyrazine
https://doi.org/10.1515/znb-1998-5-616
Keywords for this article
Platinum(IV) Complexes; Crown Ethers; Amino Acids; Crystal Structure

Articles in the same Issue

  1. Darstellung und Strukturbeschreibung von NaCa3 Mn(V2O7)(V3O10) / Preparation and Structure of NaCa3Mn(V2O7)(V3O10)
  2. Ba4Mn2Ag2O(As04)4 , ein Barium-Mangan-Oxid-Arsenat mit nichtlinearen O-Ag-O-Hanteln / Ba4Mn2Ag2O(AsO4)4, a Barium Manganese Oxide-Arsenate Showing Nonlinear O-Ag-O Dumbbells
  3. Indium partiell in tetraedrischer Sauerstoffkoordination in BaIn2Zn3O7. Eine Betrachtung zum Ba2Ln2Zn8O13/BaLnAlZn3O7 -Typ / Partial Tetrahedral Oxygen Coordination of Indium in BaIn2Zn3O7. A Consideration of the Ba2Ln2Zn8O13/BaLnAlZn3O7 Type
  4. Zur Kenntnis eines Vanadyl-Oxocuprat-Phosphats CaCu(VO)(PO4)2 mit Cu2+ auf Positionen der VO2+-Ionen und einer kupferreicheren Phase CaCu1,13(VO)0,87(PO4)2 / On an Vanadyl Oxocuprate Phosphate CaCu(VO)(PO4)2 Containing Cu2+ at Positions of VO2+ Ions and a Copper Rich Phase CaCu1.13(VO)0.87(PO4)2
  5. Verknüpfung von (TeO6)6- und (TeO6)3(NiO6)3-Sechsringen durch TeNiO9-Oktaederdoppel in Pb3Ni4,5Te2,5O15 / Connection of (TeO6)6 and (TeO6)3(NiO6)3 Hexagons by TeNiO9 Octahedra Double in Pb3Ni4,5Te2,5O15
  6. Preparation and X-Ray Structure of 3,5-Dimethyl-1,4-dichloro-1,2,6- thiadiazine-1-oxide
  7. Pentafluoro[(4-methyl-1,4-bisazoniacy clohex-1 -yl)methy 1] germanate Hydrate: Synthesis and Crystal Structure of a Zwitterionic λ6Ge-Germanate with a GeF5C Framework
  8. Mesitylene Osmium(II) Complexes Containing the Functional Phosphane tBuP(CH2CO2Me)2 and Anionic Species Derived Thereof as Bi- and Tridentate Ligands
  9. Benzylgallium-Verbindungen. Die Kristallstrukturen von [Mg3Br2,4Cl1,6(OEt2)6][Ga(CH2Ph)4]2 · 0,5 Toluol und [(3,5-Me2C6H3CH2)2GaBr]2 / Benzylgallium Compounds. The Crystal Structures of [Mg3Br2,4Cl1,6(OEt2)6][Ga(CH2Ph)4]2 · 0.5 Toluene and [(3,5-Me2C6H3CH2)2GaBr]2
  10. Die Kristallstruktur von [Me3PN(H)PMe3]4l28, einem Polyiodid mit I3--, l82-- und I144--Ionen Crystal / Structure of [Me3PN(H)PMe3]4I28, a Polyiodide with I3-, I82- , and I 144- Ions
  11. In situ Neutron Diffraction on DxNb2O5
  12. The First Hydrogen Containing (Polyfluorocycloalken-l-yl)xenon(II) Salts
  13. Kristallstruktur von 1,1'-Dimethyl-4,4'-bipyridinium-octachlorodiantimonat(III) / Crystal Structure of 1,1'-Dimethyl-4,4'-bipyridinium-octachlorodiantimonate(III)
  14. Kristallstruktur des Doppelkomplexsalzes trans-(py2CH2)[Pt(OH)2(ox)2]transs-(py2CH2)[Pt(OH)(ox)2(H2O)]2·4H2O / Crystal Structure of the Double Complex Salt trans-(py2CH2)[Pt(OH)2(ox)2](H2O)]2·4H2O
  15. Tetrakis(sulfurdiimido)silane, -germane and -stannane
  16. Synthese und Charakterisierung von kronenetherstabilisierten Platin(IV)- Komplexen mit Aminosäureliganden / Synthesis and Characterization of Amino Acid Complexes of Platinum(IV) Stabilized by Crown Ethers
  17. Hydrido(acylphenolato)cobaIt(III)-Verbindungen mit Trimethylphosphan-Liganden / Hydrido(acylphenolato)cobalt(III) Compounds Containing Trimethylphosphane Ligands
  18. Onio-assistierte SN2-Reaktionen: Allgemeiner Zugang zu symmetrischen und unsymmetrischen geminal bisoniosubstituierten Methanderivaten / Onio-Assisted SN2-Reactions: General Access to Symmetrical and Unsymmetrical Geminally Bisonio Substituted Methane Derivatives
  19. Anodic Methoxylation of Isatin
  20. Neuartige Synthese und Molekülstruktur von Benzylkalium (thf) [KCH2C6H5]2 / Novel Synthesis and Molecular Structure of Benzyl Potassium (thf)[KCH2C6H5]2
  21. Weitere Verbindungen zum Ba6Nd2Al4O15-Typ: Ba4Nd4Zn3PtO15 und Ba4Eu4Zn3PtO15 / Further Compounds of the Ba6Nd2Al4O15 Type: Ba4Nd4Zn3PtO15 and Ba4Eu4Zn3PtO15
  22. Fe[B2P2O7(OH)5]: Ein neues Boro-phosphat mit unverzweigten Vierer-Einfach Tetraederketten / Fe[B2P2O7(OH)5]: A New Borophosphate Containing Non-Branched Tetrahedral Vierer-Einfach Chains
  23. Polysulfonylamine, CIII [1] Ein Hydroxylamin mit bemerkenswert kurzer O-N-B Bindung: Kristall- und Molekülstruktur von MeO-N(SO2Me)2 / Polysulfonylamines, C III [1] A Hydroxylamine with a Remarkably Short O-N Bond: Crystal and Molecular Structure of MeO-N(SO2Me)2
  24. 3,10,17,24-Tetra(1-methylethyl)-[29H,31H-tetrapyrido[2,3-b:2′,3′-g:2″-3″-I:2‴,3‴ -q]porphyrazinato-(2-)N29,N30,N31,N32]-nickel- [Eu(fod)3]4- Ein lösliches Pyridoporphyrazin / 3,10,17,24-Tetra(1-methylethyl)- [29H,31H-tetrapyrido[2,3-b:2′,3′-g:2″-3″-I:2‴,3‴-q]porphyrazinato-(2-)N29,N30,N31,N32]-nickel-[Eu(fod)3]4 - A Soluble Pyridoporphyrazine
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