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Kristallstruktur von MgSO3·H2O/Crystal Structure of Mg SO3·H2O

  • Willi Buchmeier , Bernward Engelen EMAIL logo and Holger Müller
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 53 Issue 2

Abstract

The crystal structure of MgSO3·H2O , space group P21 /ln, Z = 4, Dx = 2.415 g·cm-3 , a = 4.699(1), b = 12.751(3), c = 5.618(1) Å, β = 90.49(3)°, was determined by single crystal X-ray diffraction. MgSO3·H2O crystallizes in the MnSO3·H2O type. The structure consists of buckled trans layers ∞[MgSO3·H2O], which are built up from strongly distorted MgO5(H2O) octahedra sharing four equatorial vertices, and of trigonal pyramidal SO32- ions. It is close­ly related to the structures of orthorhombic MnSeO3·D2O and monoclinic ZnSeO3·H2O . The Mg-O distances range from 2.051(3) to 2.175(4) Å. The S-O distances (1.543(3), 1.547(3) and 1.493(3) Å) and the O-S-O angles (98.4(2) and 2x 106.0(2)°) correspond to those in MnSO3·H2O . The distortion of the MO5(H2O) octahedra (M = Mg, Mn) and of the SO32- ions is smaller in MgSO3·H2O , but with greater deviations from m symmetry. The distances between the H-connected ∞2[MSO3·H2O] layers are greater in MgSO3·H2O , indicating weaker inter-layer hydrogen bonds. The lateral arrangement of the ∞2[MSO3·H2O] layers is nearly the same in both sulfite monohydrates.

Keywords: X-Ray; Sulfites; Hydrates; Magnesium; Pseudosymmetry
Received: 1997-11-10
Published Online: 2014-6-2
Published in Print: 1998-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Kristallstruktur von MgSO3·H2O/Crystal Structure of Mg SO3·H2O
  2. Synthesis of Spirocyclic Aminosilanes with Electron Withdrawing Substituents at Nitrogen
  3. Synthese und Kristallstruktur des Lanthan-Titanat-Tellurats LaTi(Ti0,25Te0,75)O6 und seine Verwandtschaft mit PbSb2O6 und Sr(MnTe)O6/Synthesis and Crystal Structure of the Lanthanum Titanate Tellurate LaTi(Ti0.25Te0.75)O6 and its Relationship to PbSb2O6 and Sr(MnTe)O6
  4. Oxochlorierung von Übergangsmetall-Komplexen mit Thionylchlorid/Oxochlorination of Transition Metal Complexes with Thionyl Chloride
  5. Ag2Cs[B15O24]: Ein wasserfreies quaternäres Silber(I)-Borat mit einem neuartigen Boratanion mit helixartigem Aufbau / Ag2Cs[B15O24]: An Anhydrous Quaternary Silver(I)-Borate with a New Helical Borate Anion
  6. Synthese und Charakterisierung des Fulleren-Kokristallisats C60*SiH(C6H5)3/Synthesis and Characterisation of the Fullerene Co-Crystal C60*SiH(C6H5)3
  7. Oligomere Tetraeder-Anionen in Borophosphaten: Darstellung und Kristall­strukturen von NaFe[BP2O7(OH)3] und K2Fe2[B2P4O16(OH)2 ]/Oligomeric Tetrahedral Anions in Borophosphates: Synthesis and Crystal Structures of NaFe[BP2O7(OH)3] and K2Fe2[B2P4O16(OH)2]
  8. (Triphenylarsine)gold(I) Complexes: Synthesis of an Oxonium Salt and Redistribution of the Arsine Ligands
  9. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumneodymchloriden/Thermal Decomposition and Solution Calorimetry of Ammonium Neodymium Chlorides
  10. Zum Chemischen Transport von Rhenium und Rheniumoxiden/On the Chemical Transport of Rhenium and Rhenium Oxides
  11. Metallkomplexe mit biologisch wichtigen Liganden, XCVIII Cyclopalladierte Schiff-Basen von α-Aminosäure- und Peptidestern/Metal Complexes of Biologically Important Ligands, XCVIII Cyclopalladated Schiff Bases of α-Amino Acid and Peptide Esters
  12. Kristallstrukturen der iodierten closo-Hexaborate trans-(Ph4P)2[B6H4I2], mer-(Ph4P)2[B6H3I3] · 2 CH2Cl2, trans-(Ph4P)2[B6H2I4] · 2 CH3CN und (CH2Py2)[B6HI5]/Crystal Structures of the Iodized closo-Hexaborates trans-(Ph4P)2[B6H4I2], mer-(Ph4P)2[B6H3I3] · 2 CH2Cl2, trans-(Ph4P )2[B6H2I4] · 2 CH3CN and (CH2Py2)[B6HI5]
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  14. Photoreactivity of Titanocene Pentasulfide
  15. Darstellung und Schwingungsspektren von cis- und trans-[OsXY(acac)2], X ≠ Y = Cl, Br, I sowie Normalkoordinatenanalyse von trans-[OsClBr(acac)2]/Synthesis and Vibrational Spectra of cis- and trans-[OsXY(acac)2], X ≠ Y = Cl, Br, I, and Normal Coordinate Analysis of trans-[OsClBr(acac)2]
  16. Darstellung, Kristallstruktur, Schwingungsspektren und Normalkoordinatenanalyse von [Os(acac)3]/ Synthesis, Crystal Structure, Vibrational Spectra, and Normal Coordinate Analysis of [Os(acac)3]
  17. Synthese und Kristallstruktur von [H2NMe2]+[(Me2NH)2 TiCl4]-/Synthesis and Crystal Structure of [H2NMe2]+[(Me2NH)2TiCl4]-
  18. 18-Krone-6 und kleine Carbonsäuren. Bildung und Struktur binärer Addukte mit Ameisen-und Essigsäure sowie ternärer mit Essigsäure und Wasser/18-Crown-6 and Small Carboxylic Acids. Formation and Structure of Binary Adducts with Formic and Acetic Acid, as well as Ternary Ones with Acetic Acid and Water
  19. The Promotive Properties of Alkali Metal Nitrate Melts for the Partial Oxidation of Methane to Methanol
  20. Interaction of the Vanadyl(IV) Cation with L-Ascorbic Acid and Related Systems
  21. Untersuchungen an Polyhalogeniden, XXXIV Cäsium(18-Krone-6)dichloroiodat, [Cs(C12H24O6)]ICl2/Studies on Polyhalides, XXXIV Cesium (18 -crown -6 )dichloroiodate, [Cs(C12H24O6)]ICl2
https://doi.org/10.1515/znb-1998-0201
Keywords for this article
X-Ray; Sulfites; Hydrates; Magnesium; Pseudosymmetry

Articles in the same Issue

  1. Kristallstruktur von MgSO3·H2O/Crystal Structure of Mg SO3·H2O
  2. Synthesis of Spirocyclic Aminosilanes with Electron Withdrawing Substituents at Nitrogen
  3. Synthese und Kristallstruktur des Lanthan-Titanat-Tellurats LaTi(Ti0,25Te0,75)O6 und seine Verwandtschaft mit PbSb2O6 und Sr(MnTe)O6/Synthesis and Crystal Structure of the Lanthanum Titanate Tellurate LaTi(Ti0.25Te0.75)O6 and its Relationship to PbSb2O6 and Sr(MnTe)O6
  4. Oxochlorierung von Übergangsmetall-Komplexen mit Thionylchlorid/Oxochlorination of Transition Metal Complexes with Thionyl Chloride
  5. Ag2Cs[B15O24]: Ein wasserfreies quaternäres Silber(I)-Borat mit einem neuartigen Boratanion mit helixartigem Aufbau / Ag2Cs[B15O24]: An Anhydrous Quaternary Silver(I)-Borate with a New Helical Borate Anion
  6. Synthese und Charakterisierung des Fulleren-Kokristallisats C60*SiH(C6H5)3/Synthesis and Characterisation of the Fullerene Co-Crystal C60*SiH(C6H5)3
  7. Oligomere Tetraeder-Anionen in Borophosphaten: Darstellung und Kristall­strukturen von NaFe[BP2O7(OH)3] und K2Fe2[B2P4O16(OH)2 ]/Oligomeric Tetrahedral Anions in Borophosphates: Synthesis and Crystal Structures of NaFe[BP2O7(OH)3] and K2Fe2[B2P4O16(OH)2]
  8. (Triphenylarsine)gold(I) Complexes: Synthesis of an Oxonium Salt and Redistribution of the Arsine Ligands
  9. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumneodymchloriden/Thermal Decomposition and Solution Calorimetry of Ammonium Neodymium Chlorides
  10. Zum Chemischen Transport von Rhenium und Rheniumoxiden/On the Chemical Transport of Rhenium and Rhenium Oxides
  11. Metallkomplexe mit biologisch wichtigen Liganden, XCVIII Cyclopalladierte Schiff-Basen von α-Aminosäure- und Peptidestern/Metal Complexes of Biologically Important Ligands, XCVIII Cyclopalladated Schiff Bases of α-Amino Acid and Peptide Esters
  12. Kristallstrukturen der iodierten closo-Hexaborate trans-(Ph4P)2[B6H4I2], mer-(Ph4P)2[B6H3I3] · 2 CH2Cl2, trans-(Ph4P)2[B6H2I4] · 2 CH3CN und (CH2Py2)[B6HI5]/Crystal Structures of the Iodized closo-Hexaborates trans-(Ph4P)2[B6H4I2], mer-(Ph4P)2[B6H3I3] · 2 CH2Cl2, trans-(Ph4P )2[B6H2I4] · 2 CH3CN and (CH2Py2)[B6HI5]
  13. Enantioselektive Katalyse, XVIII Der Einfluß nicht koordinierter Stereozentren auf die enantioselektive Hydrierung/Enantioselective Catalysis, XVIII The Influence of Non-Coordinated Stereocenters on the Enantioselective Hydrogenation
  14. Photoreactivity of Titanocene Pentasulfide
  15. Darstellung und Schwingungsspektren von cis- und trans-[OsXY(acac)2], X ≠ Y = Cl, Br, I sowie Normalkoordinatenanalyse von trans-[OsClBr(acac)2]/Synthesis and Vibrational Spectra of cis- and trans-[OsXY(acac)2], X ≠ Y = Cl, Br, I, and Normal Coordinate Analysis of trans-[OsClBr(acac)2]
  16. Darstellung, Kristallstruktur, Schwingungsspektren und Normalkoordinatenanalyse von [Os(acac)3]/ Synthesis, Crystal Structure, Vibrational Spectra, and Normal Coordinate Analysis of [Os(acac)3]
  17. Synthese und Kristallstruktur von [H2NMe2]+[(Me2NH)2 TiCl4]-/Synthesis and Crystal Structure of [H2NMe2]+[(Me2NH)2TiCl4]-
  18. 18-Krone-6 und kleine Carbonsäuren. Bildung und Struktur binärer Addukte mit Ameisen-und Essigsäure sowie ternärer mit Essigsäure und Wasser/18-Crown-6 and Small Carboxylic Acids. Formation and Structure of Binary Adducts with Formic and Acetic Acid, as well as Ternary Ones with Acetic Acid and Water
  19. The Promotive Properties of Alkali Metal Nitrate Melts for the Partial Oxidation of Methane to Methanol
  20. Interaction of the Vanadyl(IV) Cation with L-Ascorbic Acid and Related Systems
  21. Untersuchungen an Polyhalogeniden, XXXIV Cäsium(18-Krone-6)dichloroiodat, [Cs(C12H24O6)]ICl2/Studies on Polyhalides, XXXIV Cesium (18 -crown -6 )dichloroiodate, [Cs(C12H24O6)]ICl2
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