Home Chemie polyfunktioneller Moleküle, 127 PPh2-Eliminierung aus dem PP-verknüpften Phosphazen Ph2P-N=PPh2-PPh2=N-PPh2 mit [C5H5Fe(CO)(μ-CO)]2; Kristallstrukturanalyse des Phosphazen-Derivats /Chemistry of Polyfunctional Molecules, 127 PPh2 Elimination from the PP Connected Phosphazene Ph2P-N=PPh2-PPh2=N-PPh2, with [C5H5Fe(CO)(μ-CO)]2; Crystal Structure of the Phosphazene Derivative
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Chemie polyfunktioneller Moleküle, 127 PPh2-Eliminierung aus dem PP-verknüpften Phosphazen Ph2P-N=PPh2-PPh2=N-PPh2 mit [C5H5Fe(CO)(μ-CO)]2; Kristallstrukturanalyse des Phosphazen-Derivats /Chemistry of Polyfunctional Molecules, 127 PPh2 Elimination from the PP Connected Phosphazene Ph2P-N=PPh2-PPh2=N-PPh2, with [C5H5Fe(CO)(μ-CO)]2; Crystal Structure of the Phosphazene Derivative

  • Jochen Ellermann , Martin Schütz , Frank W. Heinemann , Matthias Moll and Walter Bauer
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 7

Abstract

The reaction of Ph2P-N=PPh2-PPh2=N-PPh2 (Ph = C6H5, 2) with [CpFe(CO)(μ-CO)]2 (Cp = C5H5, 3) yields under elimination of a PPh2-group from 2 and cleavage of the Fe-Fe bond in 3 the monocyclic ferraphosphazene complex Cp(OC) (4) and Ph2P-PPh2 (5). In a side reaction the P-P bond of 2 is also cleaved in a redox process to give Cp(OC) (7). Compound 4 has been characterized by a crystal structure determination.

Keywords : Phosphazene; Iron Complexes; X-Ray; Elimination of PPh2; Cleavage of PP
Received: 1997-4-7
Published Online: 2014-6-2
Published in Print: 1997-7-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Titelei
  2. Difluorphosphorylcyclosilazane -Synthese und Kristallstruktur/Difluorophosphorylcyclosilazanes -Syntheses and Crystal Structure
  3. Synthese von 2,2-DiphenylethyI-substituierten Silanen -Molekülstruktur von Trichlor-2,2-diphenylethylsilan /Syntheses of 2,2-Diphenylethyl-Substituted Silanes -Molecular Structure of Trichloro-2,2-diphenylethylsilane
  4. Ein [Ba(Ca,Mn)O6]-Gerüst mit eingelagerten V-O-V-Gruppen in der Kristallstruktur von Ba(Ca0.6Mn0.4)V2O7 /A [Ba(Ca,Mn)O6] Framework with Incorporated V-O-V Groups in the Crystal Structure of Ba(Ca0.6Mn0.4)V2O7
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  6. Chemie polyfunktioneller Moleküle, 127 PPh2-Eliminierung aus dem PP-verknüpften Phosphazen Ph2P-N=PPh2-PPh2=N-PPh2 mit [C5H5Fe(CO)(μ-CO)]2; Kristallstrukturanalyse des Phosphazen-Derivats /Chemistry of Polyfunctional Molecules, 127 PPh2 Elimination from the PP Connected Phosphazene Ph2P-N=PPh2-PPh2=N-PPh2, with [C5H5Fe(CO)(μ-CO)]2; Crystal Structure of the Phosphazene Derivative
  7. Synthese und Kristallstruktur von Perhydro-1,4-benzoxazino[2,3-n]phenoxazin/Synthesis and Crystal Structure of Perhydro-1,4-benzoxazino[2,3-n]phenoxazine
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  9. Synthesis and X -Ray Crystal Structure of the Heterobimetallic Complex [FeRh (μ-CO)(CO)3((μ-PBut2)((μ-Ph2PCH2PPh2)]
  10. The Thermal Isomerization of a Tetrahydro-2,3-disilanaphthalene into a 1,2-Disilacyclobutane -The Conversion of a Formal Silene [2+4] Cyclodimer into the [2+2] Cycloadduct
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  16. Synthese neuer Pyridin-C-nukleoside der 2 ,3 -Didesoxyribose durch „inverse“ [4+2]-Cycloaddition Synthesis of Novel Pyridine-C-nucleosides of 2,3-Dideoxyribose by „Inverse“ [4+2]-Cycloaddition
  17. Mechanismus der Cyclotrimerisierung von Phenylvinylketonen und die Kristallstrukturen von 1-((1R*,2S*,3R*,5S*)-und 1-((1R*,2S*,3R*,5R*)- 3.5-Dibenzoyl-2-hydroxy-2-phenylcyclohexylmethyl)-pyrrolidin-2-on/The Mechanism of Cyclotrimerisation of Phenylvinylketones and theCrystal Structures of 1-((1R*,2S*,3R*,5S*)-and1-((1R*,2S*,3R*,5R*)-3.5-Dibenzoyl-2-hydroxy-2-phenylcyclohexylmethyl)-pyrrolidin-2-on
  18. Acyclo C-Nucleosides Analogues of Condensed 1,2,4-Triazines
https://doi.org/10.1515/znb-1997-0705
Keywords for this article
Phosphazene; Iron Complexes; X-Ray; Elimination of PPh2; Cleavage of PP

Articles in the same Issue

  1. Titelei
  2. Difluorphosphorylcyclosilazane -Synthese und Kristallstruktur/Difluorophosphorylcyclosilazanes -Syntheses and Crystal Structure
  3. Synthese von 2,2-DiphenylethyI-substituierten Silanen -Molekülstruktur von Trichlor-2,2-diphenylethylsilan /Syntheses of 2,2-Diphenylethyl-Substituted Silanes -Molecular Structure of Trichloro-2,2-diphenylethylsilane
  4. Ein [Ba(Ca,Mn)O6]-Gerüst mit eingelagerten V-O-V-Gruppen in der Kristallstruktur von Ba(Ca0.6Mn0.4)V2O7 /A [Ba(Ca,Mn)O6] Framework with Incorporated V-O-V Groups in the Crystal Structure of Ba(Ca0.6Mn0.4)V2O7
  5. Darstellung und Kristallstrukturbestimmung von 1,2-Di-t-butyl-1,2-diiodo- diarsan (t-C4H9AsI)2 und Synthese von 1,2,3,4-Tetrakis(t-butyl)tetraarsetan (t-C4H9As)4 über selektive Reduktion von t-Butylarsendiiodid t-C4H9AsI2 Synthesis and Crystal Structure of 1,2-Di-t-butyl-1,2-diiododiarsane (t-C4H9AsI)2 and Synthesis of 1,2,3,4-Tetrakis(t-butyl)tetraarsetane (t-C4H9As)4 via Selective Reduction of t-Butylarsenic Diiodide t-C4H9AsI2
  6. Chemie polyfunktioneller Moleküle, 127 PPh2-Eliminierung aus dem PP-verknüpften Phosphazen Ph2P-N=PPh2-PPh2=N-PPh2 mit [C5H5Fe(CO)(μ-CO)]2; Kristallstrukturanalyse des Phosphazen-Derivats /Chemistry of Polyfunctional Molecules, 127 PPh2 Elimination from the PP Connected Phosphazene Ph2P-N=PPh2-PPh2=N-PPh2, with [C5H5Fe(CO)(μ-CO)]2; Crystal Structure of the Phosphazene Derivative
  7. Synthese und Kristallstruktur von Perhydro-1,4-benzoxazino[2,3-n]phenoxazin/Synthesis and Crystal Structure of Perhydro-1,4-benzoxazino[2,3-n]phenoxazine
  8. Strukturen zweier isomerer Gadolinium(III)-Polyaminopolycarboxylate -Argumente für signifikante Unterschiede ihrer 1H-NMR-Relaxation/Structures of Two Isomeric Gadolinium(III) Polyamino Polycarboxylates -Relation to their Significant Differences in 1H NMR Relaxation
  9. Synthesis and X -Ray Crystal Structure of the Heterobimetallic Complex [FeRh (μ-CO)(CO)3((μ-PBut2)((μ-Ph2PCH2PPh2)]
  10. The Thermal Isomerization of a Tetrahydro-2,3-disilanaphthalene into a 1,2-Disilacyclobutane -The Conversion of a Formal Silene [2+4] Cyclodimer into the [2+2] Cycloadduct
  11. Synthese und Kristallstruktur von [(Cl3Si)2N]2TiCl2 -ein perchloriertes N-Silyl-titanamid /Synthesis and Crystal Structure of [(Cl3Si)2N]2TiCl2 -a Fully Chlorinated N-Silyl Titanium Amide
  12. Synthesis of C2B3 X-Heterocycles (X = C, N, P, O, S) from 1,3,5-Triborapentanes
  13. Synthese und Struktur eines zweikernigen Uranylkomplexes mit acyclischem, mehrzähnigem Aminoalkohol als Chelatligand: Lösungsmittelinduzierte supramolekulare Struktur/Synthesis und Structure of a Binuclear Uranyl Complex with an Acyclic, Multidentate Amino Alcohol as Chelate Ligand: Solvent Induced Supramoleculare Structure
  14. Enantioselektive Katalyse, 109 Neue erweiterte chirale Bipyridine/Enantioselective Catalysis, 109 New Expanded Chiral Bipyridines
  15. Reaktionen von Azacoronanden mit Quecksilber(II)iodid: Kristallstrukturen zweier Komplexe von Hgl2 mit Diaza-15-krone-5 und Diaza-18-krone-6 /Reactions of Azacoronands with Mercury(II) Iodide: Crystal Structures of Two Complexes of Hgl2 with Diaza-15-crown-5, and Diaza-18-crown-6
  16. Synthese neuer Pyridin-C-nukleoside der 2 ,3 -Didesoxyribose durch „inverse“ [4+2]-Cycloaddition Synthesis of Novel Pyridine-C-nucleosides of 2,3-Dideoxyribose by „Inverse“ [4+2]-Cycloaddition
  17. Mechanismus der Cyclotrimerisierung von Phenylvinylketonen und die Kristallstrukturen von 1-((1R*,2S*,3R*,5S*)-und 1-((1R*,2S*,3R*,5R*)- 3.5-Dibenzoyl-2-hydroxy-2-phenylcyclohexylmethyl)-pyrrolidin-2-on/The Mechanism of Cyclotrimerisation of Phenylvinylketones and theCrystal Structures of 1-((1R*,2S*,3R*,5S*)-and1-((1R*,2S*,3R*,5R*)-3.5-Dibenzoyl-2-hydroxy-2-phenylcyclohexylmethyl)-pyrrolidin-2-on
  18. Acyclo C-Nucleosides Analogues of Condensed 1,2,4-Triazines
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