Home Kondensationsreaktionen von Trifluornitrosomethan CF3NO mit Sulfanilamid H2NC6H4SO2NH2-Darstellung von CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(O)N(H)C6H4SO2NNCF3 und CF3C(0)N (H)C6H4SO2NH2 / Condensation Reactions of Trifluoronitrosomethane CF3NO with Sulfanilamide H2NC6H4SO2NH2- Preparation of CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(0)N(H)C6H4SO2NNCF3 and CF3C(0)N (H)C6H4SO2NH2
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Kondensationsreaktionen von Trifluornitrosomethan CF3NO mit Sulfanilamid H2NC6H4SO2NH2-Darstellung von CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(O)N(H)C6H4SO2NNCF3 und CF3C(0)N (H)C6H4SO2NH2 / Condensation Reactions of Trifluoronitrosomethane CF3NO with Sulfanilamide H2NC6H4SO2NH2- Preparation of CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(0)N(H)C6H4SO2NNCF3 and CF3C(0)N (H)C6H4SO2NH2

  • Rolf Minkwitz , Jens Jakob and Andreas Winter
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 5

Abstract

We report the condensations of trifluoronitrosom ethane with sulfanilamide. The new compounds p-trifluorom ethylazophenylsulfonamide CF3NNC6H4SO2NH2, p-trifluorom ethylazosulfonyltrifluorom ethylazobenzole CF3NNC6H4SO2NNCF3 and p-trifluoromethylazosulfonylacetanilide CH3C(O)N(H)C6H4SO2NNCF3 were characterized by elemental analysis, IR, Raman, mass, 1H , 19F and 13C NMR spectroscopy. In addition we present our approach to the preparation of p-trifluorom ethylazosulfonylaniline H2NC6H 4SO2NNCF3 by using protecting groups for the amino group.

Keywords: Trifluoronitrosomethane; Sulfanilamide; p-Trifluoromethylazophenylsulfonamide; p-Trifluoromethylazosulfonyltrifluoromethylazobenzole; p-T rifluoromethylazosulfonylacetanilide
Received: 1997-2-19
Published Online: 2014-6-2
Published in Print: 1997-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Kantenverknüpfte VO6-0ktaeder und PO4-Tetraeder in BaCa(VO)(PO4)2 / Edge-Connected VO6 Octahedra and PO4 Tetrahedra in BaCa(VO)(PO4)2
  2. Geschlossene 1∞[(PtDy4O16)4]-Polyedertunnel in Ba13Dy8Zn4Pt4O37 Closed 1∞ [(PtDy4O16)4] Polyhedra Tunnels in Ba13Dy8Zn4Pt4O37
  3. Preparation and X-Ray Structure of
  4. Quaternary Equiatomic Manganese Pnictide Oxides AMnPO (A = La-Nd, Sm, Gd-Dy), AMnAsO (A = Y, La-Nd, Sm, Gd-Dy, U), and AMnSbO (A = La-Nd, Sm, Gd) with ZrCuSiAs Type Structure
  5. Kristallstrukturen von (n-Bu4N)[B6Cl6], (n-Bu4N)[B6Br6] und (Ph3P=N=PPh3)[B6I6] sowie Schwingungsspektren und Normalkoordinatenanalyse der Hexahalogeno-c/osö-Hexaboratradikalanionen [B6X6]-, X = Cl, Br, I / Crystal Structures of (n-Bu4N)[B6Cl6], (n-Bu4N)[B6Br6], and (Ph3P=N=PPh3)[B6I6], and Vibrational Spectra and Normal Coordinate Analysis of the Hexahalogeno-closo-hexaborate Radical Anions [B6X6]- , X = Cl, Br, I
  6. Synthese und Röntgenstrukturanalyse von [Fe(η6-C6H4{1,3-(CH3)2})(η5 -C5(C6H5)5]+ [FeCl4]- / Synthesis and X-Ray Structure Analysis of [Fe(η6-C6H4{1 ,3 -(CH3)2})(η5-C5(C6H5)5]+ [FeCl4]-
  7. Funktionalisierung und Vernetzung von Poly(silylenmethylenen) Functionalization and Cross-Linking of Poly(silylenemethylenes)
  8. The Crystal Structures of Et2Sn(O2PMe2)2 and Ph2Sn(O2PMe2)2; Synthesis and Spectral Studies of Ph2Sn(O2PMe2)2
  9. Dppa als Komplexligand: Metall-Koordination und P-N-Spaltung in Komplexen des Typs [CpM(L)dppa]X (M = Fe, Mn; L = CO, NO) / Dppa as a Ligand: Metal Coordination and P-N Cleavage in Complexes of the Type [CpM(L)dppa]X (M = Fe, Mn; L = CO, NO)
  10. Synthese und Kristallstruktur von 7-Azaindolato-Silber, einem dimeren Ag(I)-Komplex mit kurzem Ag-Ag-Abstand
  11. Zur Reaktion von Derivaten des 1,3-Dimethyl-2-iminoimidazolins mit CS2 [1] / On the Reaction of 1,3-Dimethyl-2-iminoimidazoline Derivatives with CS2 [1]
  12. Formation and Crystal Structures of the Hydrates of 18-Crown-6 [1]
  13. Substituierte 1,2,4-Thiadiazolium-dichloroaurate(I) und -tetra- chloroaurate(III) als Reaktionsprodukte von N-Thiocarbamoyl- benzamidinen mit TetrachIorogold(III)-Verbindungen / Substituted 1,2,4-Thiadiazolium dichloroaurates(I) and -tetrachloroaurates(III) as Products o f the Reaction o f N -Thiocarbam oyl-benzamidines with Tetrachlorogold(III) Compounds
  14. Neue Synthesen mit Magnesiumhydrid Teil 2: Wege zu neuen komplexen Hydriden und zum Aluminiumwasserstoff / New Syntheses with M agnesium Hydride Part 2: Pathways to New Complex Hydrides and A luminium Hydride
  15. Synthese und Kristallstrukturen der neuen Zinn-Chalkogen-Vierringe [{Cp(Ph3P)Ni}2Cl2Sn2E2] (E = Se, S) / Synthesis and Crystal Structures of the New Four-M em bered Tin-Chalcogen Rings [{Cp(Ph3P)Ni}2Cl2Sn2E2] (E = Se, S)
  16. Die zu BaMg2Cu8V6O26 isotypen Cadmium-Kupferoxovanadate KCd0,67Cu4,33V3O13, RbCd0,5Cu4,5V3O13 sowie TlCd0,5Cu4,5V3O13 /The BaMg2Cu8V6O26 isotypic Cadmium-Cooperoxovanadates KCd0,67Cu4,33V3O13, RbCd0,5Cu4,5V3O13 and TlCd0,5Cu4,5V3O13 /
  17. Dicobaltoarsenat -(CoAsO7) -Baugruppen im Cobaltoxid-Tellurat Co6O2[T eO4(CoAsO5)2] / Dicobaltoarsenate - (CoAsO7) - Groups in the Cobalt Oxide Tellurate Co6O2[TeO4(CoAsO5)2]
  18. Kondensationsreaktionen von Trifluornitrosomethan CF3NO mit Sulfanilamid H2NC6H4SO2NH2-Darstellung von CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(O)N(H)C6H4SO2NNCF3 und CF3C(0)N (H)C6H4SO2NH2 / Condensation Reactions of Trifluoronitrosomethane CF3NO with Sulfanilamide H2NC6H4SO2NH2- Preparation of CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(0)N(H)C6H4SO2NNCF3 and CF3C(0)N (H)C6H4SO2NH2
  19. Übergangsmetall-substituierte Acylphosphane und Phosphaalkene, XXXIY [1] Methylendiyl(thioxo)- und MethyIendiyl(selenoxo)-λ5,σ3-phosphorane als μ-Liganden in [(η5-C5H5)2Fe2(CO)3]-Komplexen. Synthese und Struktur von / Transition Metal Substituted Acylphosphanes and Phosphaalkenes, XXXIV [1] Methylenediyl(thioxo)- and M ethylenediyl(selenoxo)-λ5 ,σ3-phosphoranes as μ-Ligands in [(η5-C5H5)2Fe2(CO)3] Complexes. Synthesis and Structure of
  20. Zum Mineral Johillerit verwandte Oxovanadate RbCd4V3O12 und TlCd4V3O12 / Oxovanadates RbCd4V3O12 and TlCd4V3 O12 Related to the Mineral Johillerite
https://doi.org/10.1515/znb-1997-0518
Keywords for this article
Trifluoronitrosomethane; Sulfanilamide; p-Trifluoromethylazophenylsulfonamide; p-Trifluoromethylazosulfonyltrifluoromethylazobenzole; p-T rifluoromethylazosulfonylacetanilide

Articles in the same Issue

  1. Kantenverknüpfte VO6-0ktaeder und PO4-Tetraeder in BaCa(VO)(PO4)2 / Edge-Connected VO6 Octahedra and PO4 Tetrahedra in BaCa(VO)(PO4)2
  2. Geschlossene 1∞[(PtDy4O16)4]-Polyedertunnel in Ba13Dy8Zn4Pt4O37 Closed 1∞ [(PtDy4O16)4] Polyhedra Tunnels in Ba13Dy8Zn4Pt4O37
  3. Preparation and X-Ray Structure of
  4. Quaternary Equiatomic Manganese Pnictide Oxides AMnPO (A = La-Nd, Sm, Gd-Dy), AMnAsO (A = Y, La-Nd, Sm, Gd-Dy, U), and AMnSbO (A = La-Nd, Sm, Gd) with ZrCuSiAs Type Structure
  5. Kristallstrukturen von (n-Bu4N)[B6Cl6], (n-Bu4N)[B6Br6] und (Ph3P=N=PPh3)[B6I6] sowie Schwingungsspektren und Normalkoordinatenanalyse der Hexahalogeno-c/osö-Hexaboratradikalanionen [B6X6]-, X = Cl, Br, I / Crystal Structures of (n-Bu4N)[B6Cl6], (n-Bu4N)[B6Br6], and (Ph3P=N=PPh3)[B6I6], and Vibrational Spectra and Normal Coordinate Analysis of the Hexahalogeno-closo-hexaborate Radical Anions [B6X6]- , X = Cl, Br, I
  6. Synthese und Röntgenstrukturanalyse von [Fe(η6-C6H4{1,3-(CH3)2})(η5 -C5(C6H5)5]+ [FeCl4]- / Synthesis and X-Ray Structure Analysis of [Fe(η6-C6H4{1 ,3 -(CH3)2})(η5-C5(C6H5)5]+ [FeCl4]-
  7. Funktionalisierung und Vernetzung von Poly(silylenmethylenen) Functionalization and Cross-Linking of Poly(silylenemethylenes)
  8. The Crystal Structures of Et2Sn(O2PMe2)2 and Ph2Sn(O2PMe2)2; Synthesis and Spectral Studies of Ph2Sn(O2PMe2)2
  9. Dppa als Komplexligand: Metall-Koordination und P-N-Spaltung in Komplexen des Typs [CpM(L)dppa]X (M = Fe, Mn; L = CO, NO) / Dppa as a Ligand: Metal Coordination and P-N Cleavage in Complexes of the Type [CpM(L)dppa]X (M = Fe, Mn; L = CO, NO)
  10. Synthese und Kristallstruktur von 7-Azaindolato-Silber, einem dimeren Ag(I)-Komplex mit kurzem Ag-Ag-Abstand
  11. Zur Reaktion von Derivaten des 1,3-Dimethyl-2-iminoimidazolins mit CS2 [1] / On the Reaction of 1,3-Dimethyl-2-iminoimidazoline Derivatives with CS2 [1]
  12. Formation and Crystal Structures of the Hydrates of 18-Crown-6 [1]
  13. Substituierte 1,2,4-Thiadiazolium-dichloroaurate(I) und -tetra- chloroaurate(III) als Reaktionsprodukte von N-Thiocarbamoyl- benzamidinen mit TetrachIorogold(III)-Verbindungen / Substituted 1,2,4-Thiadiazolium dichloroaurates(I) and -tetrachloroaurates(III) as Products o f the Reaction o f N -Thiocarbam oyl-benzamidines with Tetrachlorogold(III) Compounds
  14. Neue Synthesen mit Magnesiumhydrid Teil 2: Wege zu neuen komplexen Hydriden und zum Aluminiumwasserstoff / New Syntheses with M agnesium Hydride Part 2: Pathways to New Complex Hydrides and A luminium Hydride
  15. Synthese und Kristallstrukturen der neuen Zinn-Chalkogen-Vierringe [{Cp(Ph3P)Ni}2Cl2Sn2E2] (E = Se, S) / Synthesis and Crystal Structures of the New Four-M em bered Tin-Chalcogen Rings [{Cp(Ph3P)Ni}2Cl2Sn2E2] (E = Se, S)
  16. Die zu BaMg2Cu8V6O26 isotypen Cadmium-Kupferoxovanadate KCd0,67Cu4,33V3O13, RbCd0,5Cu4,5V3O13 sowie TlCd0,5Cu4,5V3O13 /The BaMg2Cu8V6O26 isotypic Cadmium-Cooperoxovanadates KCd0,67Cu4,33V3O13, RbCd0,5Cu4,5V3O13 and TlCd0,5Cu4,5V3O13 /
  17. Dicobaltoarsenat -(CoAsO7) -Baugruppen im Cobaltoxid-Tellurat Co6O2[T eO4(CoAsO5)2] / Dicobaltoarsenate - (CoAsO7) - Groups in the Cobalt Oxide Tellurate Co6O2[TeO4(CoAsO5)2]
  18. Kondensationsreaktionen von Trifluornitrosomethan CF3NO mit Sulfanilamid H2NC6H4SO2NH2-Darstellung von CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(O)N(H)C6H4SO2NNCF3 und CF3C(0)N (H)C6H4SO2NH2 / Condensation Reactions of Trifluoronitrosomethane CF3NO with Sulfanilamide H2NC6H4SO2NH2- Preparation of CF3NNC6H4SO2NH2, CF3NNC6H4SO2NNCF3, CH3C(0)N(H)C6H4SO2NNCF3 and CF3C(0)N (H)C6H4SO2NH2
  19. Übergangsmetall-substituierte Acylphosphane und Phosphaalkene, XXXIY [1] Methylendiyl(thioxo)- und MethyIendiyl(selenoxo)-λ5,σ3-phosphorane als μ-Liganden in [(η5-C5H5)2Fe2(CO)3]-Komplexen. Synthese und Struktur von / Transition Metal Substituted Acylphosphanes and Phosphaalkenes, XXXIV [1] Methylenediyl(thioxo)- and M ethylenediyl(selenoxo)-λ5 ,σ3-phosphoranes as μ-Ligands in [(η5-C5H5)2Fe2(CO)3] Complexes. Synthesis and Structure of
  20. Zum Mineral Johillerit verwandte Oxovanadate RbCd4V3O12 und TlCd4V3O12 / Oxovanadates RbCd4V3O12 and TlCd4V3 O12 Related to the Mineral Johillerite
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