Article
Open Access
A Rigid C1-Bridged Ansa-Zirconocene-Derived Catalyst System Suited for Stereoselective Low Molecular Weight Polypropylene Formation
-
Gerhard Erker
Published/Copyright:
June 2, 2014
Received: 1994-9-20
Published Online: 2014-6-2
Published in Print: 1995-4-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
Articles in the same Issue
- Oxidative Abbaureaktionen des homonuklearen Cobalthydridclusters [(η5-Cp*)Co]3H4 / Oxidative Degradation Reactions of the Homonuclear Cobalt Hydride Cluster [(η5-Cp*)Co]3H4
- Problems in Selective Catalysis with Molecular Imprints in Silica - Selective Lactones Formation from Hydroxyesters in Micropores -
- A Rigid C1-Bridged Ansa-Zirconocene-Derived Catalyst System Suited for Stereoselective Low Molecular Weight Polypropylene Formation
- [TiH2 · (MgCl2 · 2 THF)0.2 – 0.3] – der naßchemische Weg zu einem hochreaktiven Titanhydrid / [TiH2 · (MgCl2 · 2 THF)0.2 – 0.3] -the Wet Chemical Route to a Highly Reactive Titanium Hydride
- Bonding in Cyclobutabenzene Chromium Tricarbonyl Complexes Studied by 13C NMR. Evidence of π-Bond Localization from 1J(13C,13C)
- Molecular Modelling: Ein Beitrag zum Verständnis der katalytischen enantioselektiven Hydrovinylierung von Styrol / Molecular Modelling: A Contribution to the Understanding of the Catalytic Enantioselective Hydrovinylation of Styrene
- The Reaction of Dienes with [Fe(Pri2P(CH2)nPPri2)] Species
- The Stability and Structure of Complex Species Formed in Equilibrium Reactions of Diethyltin(IV) with N-D-Gluconylamino Acids in Aqueous Solution
- Charge Transfer Photochemistry of Bis(8-quinolinolato)copper(II) and Bis(8-quinolinethiolato)copper(II) in Aprotic Solvents
- Thermodynamics of Complexation of Sodium Ion with 12-Crown-4 and 18-Crown-6 in Pyridine
- 4- and 5-Coordinate Dinuclear Copper(II) Complexes with the Tetraacetylethanediide and an N-Alkylated Diamine or a Triamine
- Thermochromism of Metal Exchange Reaction between Zinc(II) and Mercury(II) Porphyrins
- Spectroelectrochemical Study of some μ3-Oxo-μ-acetato Trinuclear Rhodium(III) and Iridium(III) Complexes
- Synthesis of [1,2,4,3]Triazaphospholo[1,5-a]pyridines+
- A Novel Triterpene Saponin from Gypsophila capillaris
- The First Liquid-Chromatographic Separation of the (R)- and (S)-Enantiomers of a Chiral Silanol, Silane and Germane
- Synthese und Kristallstruktur von [TeCl2(NPMe3)2]2/ Synthesis and Crystal Structure of [TeCl2(NPMe3)2]2
- Über das Erdalkalimetall-Lanthanoid-Kupfer-Oxomolybdat (Cu0,22Mg0 ,78)BaNd2Mo4O16/The Alkaline Earth Rare Earth Copper-Oxomolybdate (Cu0.22Mg0.78)BaNd2Mo4O16
- Über das gemischte Alkali-Erdalkalimetall-Oxoruthenat NaSr3RuO6 / The Mixed Alkaline Alkaline Earth Oxoruthenate NaSr3RuO6
- Über einen 9L-Perowskit der Zusammensetzung Ba9Ru3,2Mn5,8O27/ On a 9L-Perovskite of the Composition Ba9Ru3.2Mn5.8O27
- Iron(III)Porphinate/H2O2-Mediated Conversion of All-(E)-Retinol
- Wechselwirkungen in Kristallen 62 [1, 2] Kristallisation und Strukturbestimmung von 2,5-Bis(trimethylsilyl)-p-benzochinon und von 2,5-Bis(trimethylsilyl)hydrochinon-natrium-bis(dimethoxyethan), einem Polymer-Strang mit Chelat-überkappten Wasserstoffbrücken (⊖O···HO)Na⊕(DME)2/ Interactions in Crystals, 62 [1, 2] Crystallization and Structure Determination of 2,5-Bis(trimethylsilyl)-p-benzoquinone and of 2,5-Bis(trimethylsilyl)hydroquinone Sodium Bis(dimethoxyethane), a Polymer String with Chelate-Capped Hydrogen Bridges (⊖O···HO)Na⊕(DME)2
- Wechselwirkungen in Kristallen, 63 [1, 2] Kristallisation und Strukturbestimmung von 1,2-Dimesitoylbenzol und von Bis(hydrogen-1,2-dimesitoylbenzol)-dinatrium-bis(ethylendiamin)/Interactions in Crystals, 63 [1, 2] Crystallization and Structure Determination of 1,2-Dimesitoylbenzene and of Bis(hydrogen-1,2-dimesitoylbenzene)-disodium-bis(ethylendiamine)
- A Synthetic Pathway to Arylsilyl(silyl)arenes; Selective Si-C Cleavage in Bis(arylsilyl)arenes with Triflic Acid
- CaMg2N2 – ein gemischtes Erdalkalimetallnitrid mit anti-La2O3-Struktur / CaMg2N2 – a Mixed Alkaline-Earth Metal Nitride with anti-La2O3 Structure
- Darstellung, Schwingungsspektren und Normalkoordinationsanalyse der D- und 13C-Isotopomeren des Methylpentahydro-closo-hexaborats [B6H5(CH3)]2- sowie Kristallstruktur von [P(C6H5)4][B6H6(CH3)] / Preparation, Vibrational Spectra and Normal Coordinate Analysis of the D and 13C Isotopomeres of the Methylpentahydro-closo-hexaborate [B6H5(CH3)]2- and the Crystal Structure of [P(C6H5)4][B6H6(CH3)]
- CuTm2[B2O5]2: Das erste „Metaborat“ mit einem 2∞[B2O5]4- -Anion / CuTm2[B2O5]2: The First “ Metaborate” with a 2∞[B2O5]4- -Anion
- Trimethylaminoxidaddukte an Tetrakis[bis(trimethylsilyl)methyl]dialuminoxan: R2Al – O – AlR2 · ONMe3 und R2Al – O – AlR2 · 2ONMe3 mit gewinkelten Al – O – Al-Gruppen / Adducts of Trimethylaminoxide with Tetrakis[bis(trimethylsilyl)methyl]dialuminoxane: R2Al – O – AlR2 · ONMe3 and R2Al – O – AlR2 · 2ONMe3 with Bent Al – O – A l Groups
- Synthese und Koordinationschemie eines neuartigen Bistetrazols: Ein 1D-Metallopolymer durch Selbstorganisation koordinativ ungesättigter Zink(II)-M4onomere [1] / Synthesis and Coordination Chemistry of a New Bistetrazole: A 1D-Metallopolymer via Self-Assembly of Monomeric Zinc(II)-Buildingblocks
- Photoreaktionen von Dekacarbonyldirhenium mit Allen und unverzweigten Allenderivaten / Photoreactions of Decacarbonyldirhenium with Allene and Unbranched Derivatives of Allene
- Block Synthesis of Oligosaccharides under Mild Conditions
- New Synthesis and Structure Determination of 13-Aza-4,4,8,8,12,12-hexamethyl-2,6,10-trioxatricyclo[7,3,1,05,13]tridecane
- Synthesis of 3′-PEG -Modified Oligonucleotides on PS -PEG Tentacle Polymers
- Einstufige Synthese von Oxazolo[3′,2′ : 1,2]pyrido[3,4-b]indolen durch direkte Kondensationsreaktion von 3,4-Dihydro-β-carbolin mit α-Hydroxy-γ-butyrolactonen / One-Step Synthesis of Oxazolo[3′,2′ : 1,2]pyrido[3,4-b]indoles by Condensation of 3,4-Dihydro-β-carboline with α-Hydroxy-γ-butyrolactones
- Notiz zur Kristallchemie von LiBa2Cu3O6 / Note on the Crystal Chemistry of LiBa2Cu3O6
- Notizen: Preparation of Dimeric [(η5-tBu3Cp)CoBr]2 and Convenient Synthesis of the Homodinuclear Cobalt Complex [(η5-tBu3Cp)Co]2H3 therefrom.
- Notizen: Neue N,Si,O,C-Heteraphane - Synthese eines 16-gliedrigen Makrocyclus / New N,Si,O,C-Heteraphanes - Synthesis of a 16-Membered Macrocycle
- Notizen: Neue fluorhaltige Phosphorylide aus 6-Phenyl-3-pentafluorphenoxy-tetrafluorcyclohexa- 2,4-dien-1-on und Triphenylphosphan / Novel Fluorine-Containing Phosphorus Ylids from 6-Phenyl-3-pentafluorophenoxy-tetrafluorocyclohexa- 2,4-dien-1-one and Triphenylphosphane
- Notizen: The Crystal Structure of [Et4N]22+[TeI6]2-, a Tetraalkyl Ammonium Salt Containing a Discrete Octahedral [TeI6]2- Anion
- Notizen: Synthesis of 3-Amino-3-deoxy Sugars through Intramolecular Carbamate Cyclizations on a Neighbouring Oxirane Ring
- Notizen: Solid State Structure of N,N-Dibenzylhydroxylamine
Keywords for this article
Homogeneous Ziegler Catalyst;
Isotactic Polypropylene;
Ansa-Metallocene;
Fulvene
Creative Commons
BY-NC-ND 3.0
Articles in the same Issue
- Oxidative Abbaureaktionen des homonuklearen Cobalthydridclusters [(η5-Cp*)Co]3H4 / Oxidative Degradation Reactions of the Homonuclear Cobalt Hydride Cluster [(η5-Cp*)Co]3H4
- Problems in Selective Catalysis with Molecular Imprints in Silica - Selective Lactones Formation from Hydroxyesters in Micropores -
- A Rigid C1-Bridged Ansa-Zirconocene-Derived Catalyst System Suited for Stereoselective Low Molecular Weight Polypropylene Formation
- [TiH2 · (MgCl2 · 2 THF)0.2 – 0.3] – der naßchemische Weg zu einem hochreaktiven Titanhydrid / [TiH2 · (MgCl2 · 2 THF)0.2 – 0.3] -the Wet Chemical Route to a Highly Reactive Titanium Hydride
- Bonding in Cyclobutabenzene Chromium Tricarbonyl Complexes Studied by 13C NMR. Evidence of π-Bond Localization from 1J(13C,13C)
- Molecular Modelling: Ein Beitrag zum Verständnis der katalytischen enantioselektiven Hydrovinylierung von Styrol / Molecular Modelling: A Contribution to the Understanding of the Catalytic Enantioselective Hydrovinylation of Styrene
- The Reaction of Dienes with [Fe(Pri2P(CH2)nPPri2)] Species
- The Stability and Structure of Complex Species Formed in Equilibrium Reactions of Diethyltin(IV) with N-D-Gluconylamino Acids in Aqueous Solution
- Charge Transfer Photochemistry of Bis(8-quinolinolato)copper(II) and Bis(8-quinolinethiolato)copper(II) in Aprotic Solvents
- Thermodynamics of Complexation of Sodium Ion with 12-Crown-4 and 18-Crown-6 in Pyridine
- 4- and 5-Coordinate Dinuclear Copper(II) Complexes with the Tetraacetylethanediide and an N-Alkylated Diamine or a Triamine
- Thermochromism of Metal Exchange Reaction between Zinc(II) and Mercury(II) Porphyrins
- Spectroelectrochemical Study of some μ3-Oxo-μ-acetato Trinuclear Rhodium(III) and Iridium(III) Complexes
- Synthesis of [1,2,4,3]Triazaphospholo[1,5-a]pyridines+
- A Novel Triterpene Saponin from Gypsophila capillaris
- The First Liquid-Chromatographic Separation of the (R)- and (S)-Enantiomers of a Chiral Silanol, Silane and Germane
- Synthese und Kristallstruktur von [TeCl2(NPMe3)2]2/ Synthesis and Crystal Structure of [TeCl2(NPMe3)2]2
- Über das Erdalkalimetall-Lanthanoid-Kupfer-Oxomolybdat (Cu0,22Mg0 ,78)BaNd2Mo4O16/The Alkaline Earth Rare Earth Copper-Oxomolybdate (Cu0.22Mg0.78)BaNd2Mo4O16
- Über das gemischte Alkali-Erdalkalimetall-Oxoruthenat NaSr3RuO6 / The Mixed Alkaline Alkaline Earth Oxoruthenate NaSr3RuO6
- Über einen 9L-Perowskit der Zusammensetzung Ba9Ru3,2Mn5,8O27/ On a 9L-Perovskite of the Composition Ba9Ru3.2Mn5.8O27
- Iron(III)Porphinate/H2O2-Mediated Conversion of All-(E)-Retinol
- Wechselwirkungen in Kristallen 62 [1, 2] Kristallisation und Strukturbestimmung von 2,5-Bis(trimethylsilyl)-p-benzochinon und von 2,5-Bis(trimethylsilyl)hydrochinon-natrium-bis(dimethoxyethan), einem Polymer-Strang mit Chelat-überkappten Wasserstoffbrücken (⊖O···HO)Na⊕(DME)2/ Interactions in Crystals, 62 [1, 2] Crystallization and Structure Determination of 2,5-Bis(trimethylsilyl)-p-benzoquinone and of 2,5-Bis(trimethylsilyl)hydroquinone Sodium Bis(dimethoxyethane), a Polymer String with Chelate-Capped Hydrogen Bridges (⊖O···HO)Na⊕(DME)2
- Wechselwirkungen in Kristallen, 63 [1, 2] Kristallisation und Strukturbestimmung von 1,2-Dimesitoylbenzol und von Bis(hydrogen-1,2-dimesitoylbenzol)-dinatrium-bis(ethylendiamin)/Interactions in Crystals, 63 [1, 2] Crystallization and Structure Determination of 1,2-Dimesitoylbenzene and of Bis(hydrogen-1,2-dimesitoylbenzene)-disodium-bis(ethylendiamine)
- A Synthetic Pathway to Arylsilyl(silyl)arenes; Selective Si-C Cleavage in Bis(arylsilyl)arenes with Triflic Acid
- CaMg2N2 – ein gemischtes Erdalkalimetallnitrid mit anti-La2O3-Struktur / CaMg2N2 – a Mixed Alkaline-Earth Metal Nitride with anti-La2O3 Structure
- Darstellung, Schwingungsspektren und Normalkoordinationsanalyse der D- und 13C-Isotopomeren des Methylpentahydro-closo-hexaborats [B6H5(CH3)]2- sowie Kristallstruktur von [P(C6H5)4][B6H6(CH3)] / Preparation, Vibrational Spectra and Normal Coordinate Analysis of the D and 13C Isotopomeres of the Methylpentahydro-closo-hexaborate [B6H5(CH3)]2- and the Crystal Structure of [P(C6H5)4][B6H6(CH3)]
- CuTm2[B2O5]2: Das erste „Metaborat“ mit einem 2∞[B2O5]4- -Anion / CuTm2[B2O5]2: The First “ Metaborate” with a 2∞[B2O5]4- -Anion
- Trimethylaminoxidaddukte an Tetrakis[bis(trimethylsilyl)methyl]dialuminoxan: R2Al – O – AlR2 · ONMe3 und R2Al – O – AlR2 · 2ONMe3 mit gewinkelten Al – O – Al-Gruppen / Adducts of Trimethylaminoxide with Tetrakis[bis(trimethylsilyl)methyl]dialuminoxane: R2Al – O – AlR2 · ONMe3 and R2Al – O – AlR2 · 2ONMe3 with Bent Al – O – A l Groups
- Synthese und Koordinationschemie eines neuartigen Bistetrazols: Ein 1D-Metallopolymer durch Selbstorganisation koordinativ ungesättigter Zink(II)-M4onomere [1] / Synthesis and Coordination Chemistry of a New Bistetrazole: A 1D-Metallopolymer via Self-Assembly of Monomeric Zinc(II)-Buildingblocks
- Photoreaktionen von Dekacarbonyldirhenium mit Allen und unverzweigten Allenderivaten / Photoreactions of Decacarbonyldirhenium with Allene and Unbranched Derivatives of Allene
- Block Synthesis of Oligosaccharides under Mild Conditions
- New Synthesis and Structure Determination of 13-Aza-4,4,8,8,12,12-hexamethyl-2,6,10-trioxatricyclo[7,3,1,05,13]tridecane
- Synthesis of 3′-PEG -Modified Oligonucleotides on PS -PEG Tentacle Polymers
- Einstufige Synthese von Oxazolo[3′,2′ : 1,2]pyrido[3,4-b]indolen durch direkte Kondensationsreaktion von 3,4-Dihydro-β-carbolin mit α-Hydroxy-γ-butyrolactonen / One-Step Synthesis of Oxazolo[3′,2′ : 1,2]pyrido[3,4-b]indoles by Condensation of 3,4-Dihydro-β-carboline with α-Hydroxy-γ-butyrolactones
- Notiz zur Kristallchemie von LiBa2Cu3O6 / Note on the Crystal Chemistry of LiBa2Cu3O6
- Notizen: Preparation of Dimeric [(η5-tBu3Cp)CoBr]2 and Convenient Synthesis of the Homodinuclear Cobalt Complex [(η5-tBu3Cp)Co]2H3 therefrom.
- Notizen: Neue N,Si,O,C-Heteraphane - Synthese eines 16-gliedrigen Makrocyclus / New N,Si,O,C-Heteraphanes - Synthesis of a 16-Membered Macrocycle
- Notizen: Neue fluorhaltige Phosphorylide aus 6-Phenyl-3-pentafluorphenoxy-tetrafluorcyclohexa- 2,4-dien-1-on und Triphenylphosphan / Novel Fluorine-Containing Phosphorus Ylids from 6-Phenyl-3-pentafluorophenoxy-tetrafluorocyclohexa- 2,4-dien-1-one and Triphenylphosphane
- Notizen: The Crystal Structure of [Et4N]22+[TeI6]2-, a Tetraalkyl Ammonium Salt Containing a Discrete Octahedral [TeI6]2- Anion
- Notizen: Synthesis of 3-Amino-3-deoxy Sugars through Intramolecular Carbamate Cyclizations on a Neighbouring Oxirane Ring
- Notizen: Solid State Structure of N,N-Dibenzylhydroxylamine