Startseite One-dimensional cyanide- and fumarate-bridged heteronuclear complex, poly[μ-fumaratotetraaminedizinc(II)di-μ-cyanodicyanonickel(II) dihydrate]
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One-dimensional cyanide- and fumarate-bridged heteronuclear complex, poly[μ-fumaratotetraaminedizinc(II)di-μ-cyanodicyanonickel(II) dihydrate]

  • Elvan Sayın , Güneş Süheyla Kürkçüoğlu EMAIL logo , Okan Zafer Yeşilel und Tuncer Hökelek
Veröffentlicht/Copyright: 10. Februar 2015
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 230 Heft 3

Abstract

Cyanide- and fumarate-bridged bimetallic complex, poly[μ-fumaratotetraaminedizinc(II)di-μ-cyanodicyanonickel(II) dihydrate], {[Zn2(μ-fum)(NH3)4Ni(μ-CN)2(CN)2]·2H2O}n (1) (H2fum = Fumaric acid) was synthesized and structurally characterized by vibrational (FT-IR and Raman) spectroscopy, single crystal X-ray diffraction and elemental and thermal analyses techniques. The structure of the complex consists of a one-dimensional polymeric chain, in which the Zn(II) and Ni(II) ions are linked by CN groups. The Ni(II) ion is four coordinated with four cyanide-carbon atoms in a square planar arrangement and the Zn(II) ions are four coordinated with one cyanide nitrogen atom, two amine nitrogen atoms and one fumarate oxygen atom, in a distorted tetrahedral arrangement. In the complex, the adjacent chains are connected by strong O–H···O, O–H···N, N–H···O and N–H···N hydrogen bonding interactions to form a three dimensional network.

Keywords: cyanide complex; fumarate complex; heteronuclear complex; one-dimensional complex; vibrational spectra
Corresponding author: Güneş Süheyla Kürkçüoğlu, Faculty of Arts and Sciences, Department of Physics, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey, Tel.: +90 222 2393750; Fax: +90 222 2393578, E-mail:

Acknowledgments

The authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskişehir, Turkey, for the use of X-ray diffractometer.

Supplementary data

CCDC 982867 contains the supplementary crystallographic data for this paper. This data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif (or from the CCDC, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033; e-mail: ).

References

[1] J. Cernak, G. Helgesen, A. T. Skjeltorp, J. Kovac, J. Voltr, E. Cizmar, Magnetic properties of carbon nanodisk and nanocone powders. Phys. Rev. B 2013, 87, 014434.10.1103/PhysRevB.87.014434Suche in Google Scholar

[2] A. Nangia, Organic nanoporous structures. Curr. Opin. Solid State Mater. Sci. 2001, 5, 115.Suche in Google Scholar

[3] H. Li, M. Eddaoudi, M. O’Keeffe, O. M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature 1999, 402, 276.10.1038/46248Suche in Google Scholar

[4] C. J. Kepert, M. J. Rosseinsky, Zeolite-like crystal structure of an empty microporous molecular framework. Chem. Commun. 1999, 4, 375.Suche in Google Scholar

[5] H. Gudbjartson, K. Biradha, K. M. Poirier, M. J. Zaworotko, Novel nanoporous coordination polymer sustained by self-assembly of shaped moieties. J. Am. Chem. Soc. 1999, 121, 2599.Suche in Google Scholar

[6] J. Hanko, M. Orendac, J. Kuchar, Z. Zak, J. Cernak, A. Orendacova, A. Feher, Hydrogen bonds mediated magnetism in Cu(bmen)2Pd(CN)4. Solid State Commun. 2007, 142, 128.Suche in Google Scholar

[7] G. S. Kürkçüoğlu, O. Z. Yeşilel, İ. Çaylı, O. Büyükgüngör, One-and two-dimensional cadmium(II) tetracyanonickelate(II) coordination polymers with imidazole and 2-methylimidazole ligands. J. Inorg. Organomet. Polym. 2011, 21, 306.Suche in Google Scholar

[8] K. Gör, G. S. Kürkçüoğlu, O. Z. Yeşilel, O. Büyükgüngör, One-dimensional bimetallic cyano complexes with nicotinamide and isonicotinamide ligands. J. Mol. Struct. 2014, 1060, 166.Suche in Google Scholar

[9] M. Ohba, H. Ōkawa, Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies. Coordin. Chem. Rev. 2000, 198, 313.Suche in Google Scholar

[10] D. Karaağaç, G. S. Kürkçüoğlu, O. Z. Yeşilel, T. Hökelek, H. Dal, Synthesis and crystal structure of cyano-bridged three dimensional polyheteronuclear complex. Z. Kristallogr. 2012, 227, 639.Suche in Google Scholar

[11] Z. Travnicek, R. Zboril, M. Matikova-Malarova, B. Drahos, J. Cernak, Thermal decomposition of [Co(en)3][Fe(CN)6]·2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation. Chem. Cent. J. 2013, 7, 1.Suche in Google Scholar

[12] S. C. Manna, S. Konar, E. Zangrando, J. Ribas, N. R. Chaudhuri, Hetero-metallic frameworks of [Pd(CN)4]2- and Cu(II) with triamines: A rare example of a tetracyanometallate bridged 2D coordination polymer. Polyhedron 2007, 26, 3189.10.1016/j.poly.2007.02.028Suche in Google Scholar

[13] X. Wang, C. Gong, G. T. Tsao, Bioconversion of fumaric acid to succinic acid by recombinant E. coli. Appl. Biochem. Biotechnol. 1998, 70, 919.Suche in Google Scholar

[14] E. Bozkurt, İ. Uçar, İ. Kartal, A. Bulut, O. Büyükgüngör, Structural, spectroscopic characterization and EPR studies of tetramethylammonium-hydrogen fumarate–fumaric acid complex. J. Phys. Chem. Solids 2008, 69, 2109.10.1016/j.jpcs.2008.03.011Suche in Google Scholar

[15] J. Do, Y. Lee, J. Kang, A. J. Jacobson, A twofold interpenetrating network constructed from silver ions coordinated to fumaric acid and pyrazine: Ag2(fum)(H2fum)(pyz)2(fum = fumarate, pyz = pyrazine). Inorg. Chim. Acta 2012, 382, 191.10.1016/j.ica.2011.11.061Suche in Google Scholar

[16] G. Dong, G. Cuia, J. Lin, Catena-poly[[aqua(4,4′-dimethyl-2,2′-bipyridine)-copper(II)]-μ-fumarato-kappa O-2,O′:kappa O-2″O′″-[aqua-(4,4′-dimethyl-2,2′-bipyridine)copper(II)]-μ-fumarato-kappaO:kappaO′]. Acta Crystallogr. 2006, E62, m628.Suche in Google Scholar

[17] A. Bruker, SAINT and SADABS, Bruker AXS Inc., Madison, Wisconsin, USA, 2005.Suche in Google Scholar

[18] G. M. Sheldrick, A short history of SHELX. Acta Cryst. A 2008, 64, 112.10.1107/S0108767307043930Suche in Google Scholar

[19] L. J. Farrugia, ORTEP-3 for Windows-a version of ORTEP-III with a graphical user interface (GUI). J. Appl. Crystallogr. 1997, 30, 565.Suche in Google Scholar

[20] C. F. Macrae, I. J. Bruno, J. A. Chisholm, P. R. Edgington, P. McCabe, E. Pidcock, L. Rodriguez-Monge, R. Taylor, J. van de Streek, P. A. Wood, Mercury CSD 2.0-new features for the visualization and investigation of crystal structures. J. Appl. Cryst. 2008, 41, 466.Suche in Google Scholar

[21] E. M. Macôas, R. Fausto, J. Lundell, M. Pettersson, L. Khriachtchev, M. Räsänen, A matrix isolation spectroscopic and quantum chemical study of fumaric and maleic acid. J. Phys. Chem. A 2001, 105, 3922.10.1021/jp003802pSuche in Google Scholar

[22] K. Nakamoto, Infrared and Raman spectra of inorganic and coordination compounds, 4th ed., John Wiley and Sons, New York, 1986.Suche in Google Scholar

[23] R. McCullough, L. Jones, G. Crosby, An analysis of the vibrational spectrum of the tetracyanonickelate (II) ion in a crystal lattice. Spectrochimica Acta 1960, 16, 929.10.1016/0371-1951(60)80057-4Suche in Google Scholar

[24] K. Nakamoto, Infrared and RamanSpectra of Inorganic and Coordination Compounds, PartB: Applications in Coordination,Organometallic,and Bioinorganic Chemistry, 6th ed., Wiley and Sons, NewYork, 1997.Suche in Google Scholar

[25] J. Kuchar, J. Cernak, K. A. Abboud, The one-dimensional structure of Cu(dmen)2Pd(CN)4 (dmen is N,N-dimethylethylenediamine). Acta Crystallogr. C 2004, 60, m492.10.1107/S0108270104019146Suche in Google Scholar

[26] S. Z. Zhan, X. Y. Chen, Q. J. Meng, Synthesis and properties of cyano-bridged nickel(II)-iron(III) complexes. Transition Met. Chem. 1996, 21, 181.Suche in Google Scholar

[27] S. Z. Zhan, Q. J. Meng, Spectrophotometric studies of cyano-bridged complexes of the type [(dien)M(II)-μ-NC-Fe(III)(CN)5]-. Spectrosc. Lett. 1996, 29, 127.Suche in Google Scholar

[28] S. Z. Zhan, X. Y. Chen, Q. J. Meng, W. Xei, Synthesis, characterization and electrochemical properties of cyanide-bridged cobalt(III) iron(II) complexes. Synth. React. Inorg. Met. Org. Chem. 1996, 26, 277.Suche in Google Scholar

[29] S. Z. Zhan, X. Y. Chen, A. Vij, D. Guo, Q. J. Meng, Synthesis, studies and molecular structure of trinuclear cyanide-bridged copper-iron complexes. Inorg. Chim. Acta 1999, 292, 157.10.1016/S0020-1693(99)00183-8Suche in Google Scholar

Supplemental Material

The online version of this article (DOI: 10.1515/zkri-2014-1818) offers supplementary material, available to authorized users.

Received: 2014-11-10
Accepted: 2014-12-16
Published Online: 2015-2-10
Published in Print: 2015-3-1

©2015 by De Gruyter

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Inorganic Crystal Structures
  4. The crystal structure of the compound Pb6Cu+(AsO3)2Cl7 discovered in the ancient slags of Lavrion, Greece
  5. The magnesium intermetallics RE2RuMg (RE = Sc, Y, Er, Tm, Lu) – i2 superstructures of the CuAu type
  6. Organic and Metalorganic Crystal Structures
  7. Formation of R44(8) ring in chloride salts of 8-hydroxyquinolinium derivatives: synthesis, structural, and theoretical studies
  8. Solvent manipulation of N-methylacetamide inclusion compounds with a xanthenol host
  9. Attempted covalent imitation of a supramolecular synthon moiety embedded in a crystalline hydrogen-bonded aggregate structure
  10. Synthesis, supramolecular structure and thermal study of a new dinuclear zinc(II) complex derived from benzene-1,2,4,5-tetracarboxylic acid
  11. One-dimensional cyanide- and fumarate-bridged heteronuclear complex, poly[μ-fumaratotetraaminedizinc(II)di-μ-cyanodicyanonickel(II) dihydrate]
https://doi.org/10.1515/zkri-2014-1818
Schlagwörter für diesen Artikel
cyanide complex; fumarate complex; heteronuclear complex; one-dimensional complex; vibrational spectra

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Inorganic Crystal Structures
  4. The crystal structure of the compound Pb6Cu+(AsO3)2Cl7 discovered in the ancient slags of Lavrion, Greece
  5. The magnesium intermetallics RE2RuMg (RE = Sc, Y, Er, Tm, Lu) – i2 superstructures of the CuAu type
  6. Organic and Metalorganic Crystal Structures
  7. Formation of R44(8) ring in chloride salts of 8-hydroxyquinolinium derivatives: synthesis, structural, and theoretical studies
  8. Solvent manipulation of N-methylacetamide inclusion compounds with a xanthenol host
  9. Attempted covalent imitation of a supramolecular synthon moiety embedded in a crystalline hydrogen-bonded aggregate structure
  10. Synthesis, supramolecular structure and thermal study of a new dinuclear zinc(II) complex derived from benzene-1,2,4,5-tetracarboxylic acid
  11. One-dimensional cyanide- and fumarate-bridged heteronuclear complex, poly[μ-fumaratotetraaminedizinc(II)di-μ-cyanodicyanonickel(II) dihydrate]
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