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1:1 Co-crystals of sulfadimidine with three bipyridine-type molecules: Persistence of N–H…N hydrogen bonded supramolecular chains
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Edward R. T. Tiekink
,
Hadi D. Arman
Published/Copyright:
April 25, 2014
Abstract
The crystal and molecular structures of 1:1 cocrystals formed between sulfadimidine and each of three bipyridine-type molecules, namely 4,4′-bipyridine (1), 4- [(E)-2-(pyridin-4-yl)ethenyl]pyridine (2) and 4-[2-(pyridin- 4-yl)ethyl]pyridine (3), are described; 1 and 2 were characterised as acetone hemi-solvates. A common feature of the sulfadimidine molecules is the adoption of a shape approximating the letter L. Conformational variability of sulfadimidine as well as in the bipyridine-type molecules is highlighted. The common feature of the crystal packing is the formation of non-linear supramolecular chains sustained by amino- and amide-H…N(pyridyl) hydrogen bonds
Keywords: co-crystal; sulfadimidine; supramolecular synthon; crystal structure analysis; X-ray diffraction
Online erschienen: 2014-4-25
Erschienen im Druck: 2014-5-1
© 2014 De Gruyter Oldenbourg GmbH, Rosenheimer Str. 145, 81671 München
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Keywords for this article
co-crystal;
sulfadimidine;
supramolecular synthon;
crystal structure analysis;
X-ray diffraction
Articles in the same Issue
- Front matter
- Crystallographic Computing System JANA2006: General features
- The incommensurate crystal structure of the Pd5B1-z phase; B ordering driven by elastic interaction between B atoms
- Symmetry reduction in uranyl compounds with [(UO2)2(TO4)3]2- (T = Se, S, Mo) layers: crystal structures of the new guanidinium uranyl selenate and methylammonium uranyl sulfate
- The pseudo-inversion symmetry of 9,90′ (1,3,4-oxadiazole-2,5-diyldi(1,1′-biphenyl)-2′,4- diyl)bis[9H-carbazole] in the light of OD theory
- Crystal structure determination of organic thin-films: the example of 2,2′ :6′,2″-ternaphthalene
- 1:1 Co-crystals of sulfadimidine with three bipyridine-type molecules: Persistence of N–H…N hydrogen bonded supramolecular chains
- EosFit7c and a Fortran module (library) for equation of state calculations
- Symmetry and the polar state of condensed molecular matter
