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Reactions of ozone and intermediate products of its decomposition with actinides, lanthanides and transition metals in aqueous solutions

  • Boris G. Ershov EMAIL logo and Bladimir P. Shilov
Published/Copyright: June 8, 2021
Radiochimica Acta
From the journal Radiochimica Acta Volume 109 Issue 8

Abstract

The properties and stability of ozone in aqueous solutions of various compositions in the рН range of 0–14 were considered. The effect of anions and cations, which are involved in the redox reactions of actinides, on the stability of ozone and its reactivity has been studied. The reactions of О3 with ions of d- and f-elements were analyzed. Depending on the solution composition and рН value, the reaction can occur directly with the O3 molecule (direct mechanism) and/or with short-lived ion-radical products (•OH, HO2•/O2−•, H2O2/HO2−, O3−•) formed upon ozone decomposition in water (indirect mechanism). Ions with inert coordination sphere react with О3 in the outer-sphere fashion with electron transfer. Polyvalent ions with labile coordination spheres are oxidized in acidic medium via О atom transfer, possibly, with intermediate peroxy addition (H2O2, HNO4, H2SO5, etc.). In alkaline medium, О3 is converted to the O3−•radical ion, which is the key oxidant for actinides. The results of studies and the mechanisms of reactions of ozone and its intermediates decomposition products with U, Np, Pu, and Am in various oxidation states and with some transition metals (Fe, Mn, Ag, Co, etc.) in aqueous solutions are presented and discussed.

Keywords: aqueous solutions; d- and f-element ions; electron or oxygen atom transfer; kinetics; ozone; ozonide ion
Corresponding author: Boris G. Ershov, Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky Pr. 31 – 4, 119071, Moscow, Russia, E-mail:

Funding source: Ministry of Science and Higher Education of the Russian Federation

Award Identifier / Grant number: AAAA-A16-116121410087-6

Funding source: Russian Foundation for Basic Research

Award Identifier / Grant number: 19-03-00501

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The study was supported by Ministry of Science and Higher Education of the Russian Federation (project no. AAAA-A16-116121410087-6) and partially by the Russian Foundation for Basic Research (project no. 19-03-00501).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-01-19
Accepted: 2021-04-28
Published Online: 2021-06-08
Published in Print: 2021-08-26

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Original Paper
  3. Reactions of ozone and intermediate products of its decomposition with actinides, lanthanides and transition metals in aqueous solutions
  4. Review
  5. A review of the alpha radiolysis of extractants for actinide lanthanide separation in spent nuclear fuel reprocessing
  6. Original Papers
  7. Third phase formation behaviour of tris(2-methylbutyl) phosphate and tri-n-alkyl phosphates in the extraction of mineral acids and tetravalent metal ions
  8. Effect of gamma irradiation processing on total phenol and antioxidant capacities of the Iranian extract of propolis
  9. Radiometric analysis of micas used in many industries and evaluation of radiological hazards
https://doi.org/10.1515/ract-2021-1007
Keywords for this article
aqueous solutions; d- and f-element ions; electron or oxygen atom transfer; kinetics; ozone; ozonide ion

Articles in the same Issue

  1. Frontmatter
  2. Original Paper
  3. Reactions of ozone and intermediate products of its decomposition with actinides, lanthanides and transition metals in aqueous solutions
  4. Review
  5. A review of the alpha radiolysis of extractants for actinide lanthanide separation in spent nuclear fuel reprocessing
  6. Original Papers
  7. Third phase formation behaviour of tris(2-methylbutyl) phosphate and tri-n-alkyl phosphates in the extraction of mineral acids and tetravalent metal ions
  8. Effect of gamma irradiation processing on total phenol and antioxidant capacities of the Iranian extract of propolis
  9. Radiometric analysis of micas used in many industries and evaluation of radiological hazards
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