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Biodegradability and mechanical behavior of novel hybrid green composites fabricated with cashew shell particle, sisal fiber and corn starch resin

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Veröffentlicht/Copyright: 28. März 2024
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Abstract

Increased use of synthetic non-biodegradable polymeric matrices for composite manufacturing, poses a serious threat to the environment. This necessitates the development of 100 % biodegradable green composites using natural plant-based fibers and biodegradable natural polymers. This study focuses on the biodegradability and mechanical characteristics of biodegradable green hybrid composites fabricated with particles of agricultural waste cashew shell, sisal fibers, and corn starch resin using hand layup followed by compression molding. Mechanical characteristics such as tensile, flexural, impact strength, shore D hardness, and soil burial biodegradation characteristics were studied experimentally. The microstructures of the fractured surfaces were also analyzed through SEM images. Composite sample fabricated with an optimum cashew shell particle proportion of 10 wt %, three sisal fiber mat layers and corn starch resin has recorded the highest mechanical strengths such as 11.4 MPa, 10.9 MPa and 310.15 J/m in tensile, flexural and impact strengths respectively. Thus, the green hybrid composite made with agricultural waste cashew shell particles, sisal fibers, and corn starch resin is a potential and eco-friendly modern material for light load and short-life applications.


Corresponding author: Arockia Julias Arulraj, Department of Mechanical Engineering, B S Abdur Rahman Crescent Institute of Science and Technology, Chennai 600048, India, E-mail:

Acknowledgments

The authors are grateful to the Polymer Engineering Department of the B S Abdur Rahman Crescent Institute of Science and Technology, for providing testing facilities to carry out this work.

  1. Research ethics: Not applicable.

  2. Author contributions: The authors has accepted responsibility for the entire content of this manuscript and approved its submission.

  3. Competing interests: The authors states no conflict of interest.

  4. Research funding: None declared.

  5. Data availability: The raw data can be obtained on request from the corresponding author.

References

1. Feraboli, P., Kawakami, H., Wade, B., Gasco, F., DeOto, L., Masini, A. Recyclability and reutilization of carbon fiber fabric/epoxy composites. J. Compos. Mater. 2012, 46, 1459–1473; https://doi.org/10.1177/0021998311420604.Suche in Google Scholar

2. Zhu, J. H., Chen, P. Y., Su, M. N., Pei, C., Xing, F. Recycling of carbon fibre reinforced plastics by electrically driven heterogeneous catalytic degradation of epoxy resin. Green Chem. 2019, 21, 1635–1647; https://doi.org/10.1039/c8gc03672a.Suche in Google Scholar

3. Chee, S. S., Jawaid, M., Sultan, M. T. H., Alothman, O. Y., Abdullah, L. C. Accelerated weathering and soil burial effects on colour, biodegradability and thermal properties of bamboo/kenaf/epoxy hybrid composites. Polym. Test. 2019, 79, 106054. https://doi.org/10.1016/j.polymertesting.2019.106054.Suche in Google Scholar

4. Gholampour, A., Ozbakkaloglu, T. A review of natural fiber composites: properties, modification and processing techniques, characterization, applications. J. Mater. Sci. 2020, 55, 829–892; https://doi.org/10.1007/s10853-019-03990-y.Suche in Google Scholar

5. Joglekar, J. J., Munde, Y. S., Jadhav, A. L., Bhutada, D. S., Radhakrishnan, S., Kulkarni, M. B. Mechanical and morphological properties of Citrus Maxima waste powder filled Low-Density polyethylene composites. Mater. Today Proc. 2021, 47, 5640–5645; https://doi.org/10.1016/j.matpr.2021.03.684.Suche in Google Scholar

6. Joglekar, J. J., Munde, Y. S., Jadhav, A. L., Bhutada, D. S., Radhakrishnan, S., Kulkarni, M. B. Studies on effective utilization of Citrus Maxima fibers based PVC composites. Mater. Today Proc. 2020, 42, 578–583; https://doi.org/10.1016/j.matpr.2020.10.648.Suche in Google Scholar

7. Sathish, K. R., Durgam Muralidharan, N. D. Mechanical characteristics study of chemically modified kenaf fiber reinforced epoxy composites. J. Nat. Fibers 2022, 19, 2457–2467. https://doi.org/10.1080/15440478.2020.1818350.Suche in Google Scholar

8. Kumar, R. S., Mohanraj, M., Natarajan, P., Julias, A. A., Ravishankar, S. Experimental study on the drilling parameter analysis of banana fiber reinforced vajram mixed phenolic resin composite laminates. J. Nat. Fibers 2022, 19, 9827–9844. https://doi.org/10.1080/15440478.2021.1993412.Suche in Google Scholar

9. Rajamanickam, S. K., Manoharan, M., Ganesan, S., Natarajan, P., Rajasekaran, P. Mechanical and morphological characteristics study of chemically treated banana fiber reinforced phenolic resin composite with vajram resin. J. Nat. Fibers 2022, 19, 4731–4746. https://doi.org/10.1080/15440478.2020.1870622.Suche in Google Scholar

10. Shekar, H. S. S., Ramachandra, M. Green composites: a review. Mater. Today Proc. 2018, 5, 2518–2526. https://doi.org/10.1016/j.matpr.2017.11.034.Suche in Google Scholar

11. Vieira, A. C., Guedes, R. M., Tita, V. Considerations for the design of polymeric biodegradable products. J. Polym. Eng. 2013, 33, 293–302; https://doi.org/10.1515/polyeng-2012-0150.Suche in Google Scholar

12. Jha, K., Kataria, R., Verma, J., Pradhan, S. Potential biodegradable matrices and fiber treatment for green composites: a review. AIMS Mater. Sci. 2019, 6, 119–138; https://doi.org/10.3934/matersci.2019.1.119.Suche in Google Scholar

13. Bulatović, V. O., Mandić, V., Kučić Grgić, D., Ivančić, A. Biodegradable polymer blends based on thermoplastic starch. J. Polym. Environ. 2021, 29, 492–508. https://doi.org/10.1007/s10924-020-01874-w.Suche in Google Scholar

14. Lu, D. R., Xiao, C. M., Xu, S. J. Starch-based completely biodegradable polymer materials. Express Polym. Lett. 2009, 3, 366–375; https://doi.org/10.3144/expresspolymlett.2009.46.Suche in Google Scholar

15. Wattanakornsiri, A., Pachana, K., Kaewpirom, S., Sawangwong, P., Migliaresi, C. Green composites of thermoplastic corn starch and recycled paper cellulose fibers. Songklanakarin J. Sci. Technol. 2011, 33, 461–467.Suche in Google Scholar

16. Santana Á, L., Angela, A., Meireles, M. New starches are the trend for industry applications: a review. Food Publ. Health 2014, 4, 229–241; https://doi.org/10.5923/j.fph.20140405.04.Suche in Google Scholar

17. Ji, M., Li, F., Li, J., Li, J., Zhang, C., Sun, K., Guo, Z. Enhanced mechanical properties, water resistance, thermal stability, and biodegradation of the starch-sisal fibre composites with various fillers. Mater. Des. 2021, 198, 109373. https://doi.org/10.1016/j.matdes.2020.109373.Suche in Google Scholar

18. de Freitas, R. R. M., do Carmo, K. P., de Souza Rodrigues, J., de Lima, V. H., Osmari da Silva, J., Botaro, V. R. Influence of alkaline treatment on sisal fibre applied as reinforcement agent in composites of corn starch and cellulose acetate matrices. Plast. Rubber Compos. 2021, 50, 9–17. https://doi.org/10.1080/14658011.2020.1816119.Suche in Google Scholar

19. Xie, Q., Li, F., Li, J., Wang, L., Li, Y., Zhang, C., Xu, J., Chen, S. A new biodegradable sisal fiber–starch packing composite with nest structure. Carbohydr. Polym. 2018, 189, 56–64. https://doi.org/10.1016/j.carbpol.2018.01.063.Suche in Google Scholar PubMed

20. Deshmukh, G. S. Advancement in hemp fibre polymer composites: a comprehensive review. J. Polym. Eng. 2022, 42, 575–598; https://doi.org/10.1515/polyeng-2022-0033.Suche in Google Scholar

21. Yang, F., Long, H., Xie, B., Zhou, W., Luo, Y., Zhang, C., Dong, X. Mechanical and biodegradation properties of bamboo fiber-reinforced starch/polypropylene biodegradable composites. J. Appl. Polym. Sci. 2020, 137, 1–8; https://doi.org/10.1002/app.48694.Suche in Google Scholar

22. Gómez, C., Torres, F. G., Nakamatsu, J., Arroyo, O. H. Thermal and structural analysis of natural fiber reinforced starch-based biocomposites. Int. J. Polym. Mater. Polym. Biomater. 2006, 55, 893–907; https://doi.org/10.1080/00914030500522547.Suche in Google Scholar

23. Prabhakar, M. N., Song, J. Fabrication and characterisation of starch/chitosan/flax fabric green flame-retardant composites. Int. J. Biol. Macromol. 2018, 119, 1335–1343. https://doi.org/10.1016/j.ijbiomac.2018.07.006.Suche in Google Scholar PubMed

24. Guna, V., Ilangovan, M., Hu, C., Venkatesh, K., Reddy, N. Valorization of sugarcane bagasse by developing completely biodegradable composites for industrial applications. Ind. Crop. Prod. 2019, 131, 25–31. https://doi.org/10.1016/j.indcrop.2019.01.011.Suche in Google Scholar

25. De Moura, C. V. R., Da Cruz Sousa, D., De Moura, E. M., De Araújo, E. C. E., Sittolin, I. M. New biodegradable composites from starch and fibers of the babassu coconut. Polimeros 2021, 31, 1–11; https://doi.org/10.1590/0104-1428.09519.Suche in Google Scholar

26. Chotikhun, A., Hiziroglu, S. Some properties of composite panels manufactured from eastern redcedar (juniperus virginiana L.) using modified starch as a green binder. J. Nat. Fibers 2017, 14, 541–550. https://doi.org/10.1080/15440478.2016.1240642.Suche in Google Scholar

27. Vijay, R., Vinod, A., Kathiravan, R., Siengchin, S., Singaravelu, D. L. Evaluation of Azadirachta indica seed/spent Camellia sinensis bio-filler based jute fabrics–epoxy composites: experimental and numerical studies. J. Ind. Textil. 2020, 49, 1252–1277; https://doi.org/10.1177/1528083718811086.Suche in Google Scholar

28. Di Franco, C. R., Cyras, V. P., Busalmen, J. P., Ruseckaite, R. A., Vázquez, A. Degradation of polycaprolactone/starch blends and composites with sisal fibre. Polym. Degrad. Stabil. 2004, 86, 95–103; https://doi.org/10.1016/j.polymdegradstab.2004.02.009.Suche in Google Scholar

29. Alsaadi, M., Erkliğ, A., Albu-khaleefah, K. Effect of pistachio shell particle content on the mechanical properties of polymer composite. Arab. J. Sci. Eng. 2018, 43, 4689–4696; https://doi.org/10.1007/s13369-018-3073-x.Suche in Google Scholar

30. Salasinska, K., Barczewski, M., Górny, R., Kloziński, A. Evaluation of highly filled epoxy composites modified with walnut shell waste filler. Polym. Bull. 2018, 75, 2511–2528; https://doi.org/10.1007/s00289-017-2163-3.Suche in Google Scholar

31. Muralidhar, N., Kaliveeran, V., Arumugam, V., Srinivasula Reddy, I. A study on areca nut husk fibre extraction, composite panel preparation and mechanical characteristics of the composites. J. Inst. Eng. India D 2019, 100, 135–145. https://doi.org/10.1007/s40033-019-00186-1.Suche in Google Scholar

32. Guna, V., Ilangovan, M., Rather, M. H., Giridharan, B. V., Prajwal, B., Vamshi Krishna, K., Venkatesh, K., Reddy, N. Groundnut shell/rice husk agro-waste reinforced polypropylene hybrid biocomposites. J. Build. Eng. 2020, 27, 100991; https://doi.org/10.1016/j.jobe.2019.100991.Suche in Google Scholar

33. Pradesh, A., Nadu, T., Units, C. P., Kannada, D., Gagr, T., Area, C. Executive Summary of Cashew Processing Units in State of Karnataka, 2016. www.trademap.org.Suche in Google Scholar

34. Sathishkumar, T. P., Kumar, S. A., Navaneethakrishnan, P., Siva, I., Rajini, N. Synergy of cashew nut shell filler on tribological behaviors of natural-fiber-reinforced epoxy composite. Sci. Eng. Compos. Mater. 2018, 25, 761–772; https://doi.org/10.1515/secm-2016-0243.Suche in Google Scholar

35. Ike, D. C., Ibezim-Ezeani, M. U., Akaranta, O. Cashew nutshell liquid and its derivatives in oil field applications: an update. Green Chem. Lett. Rev. 2021, 14, 618–631; https://doi.org/10.1080/17518253.2021.1991485.Suche in Google Scholar

36. Quirino, R. L., Garrison, T. F., Kessler, M. R. Matrices from vegetable oils, cashew nut shell liquid, and other relevant systems for biocomposite applications. Green Chem. 2014, 16, 1700–1715; https://doi.org/10.1039/c3gc41811a.Suche in Google Scholar

37. Kini, U. A., Nayak, S. Y., Shenoy Heckadka, S., Thomas, L. G., Adarsh, S. P., Gupta, S. Borassus and tamarind fruit fibers as reinforcement in cashew nut shell liquid-epoxy composites. J. Nat. Fibers 2018, 15, 204–218. https://doi.org/10.1080/15440478.2017.1323697.Suche in Google Scholar

38. Ugoamadi, C. C. Comparison of cashew nut shell liquid (CNS) resin with polyester resin in composite development. Niger. J. Technol. Dev. 2013, 10, 17–21.Suche in Google Scholar

39. Ramamoorthi, R., Soundararajan, R., Jeyakumar, R. Experimental investigations of mechanical properties of sisal fiber/cashew nut shell dust strengthened hybrid epoxy composites. Indian J. Sci. Technol. 2019, 12, 1–6; https://doi.org/10.17485/ijst/2019/v12i9/141798.Suche in Google Scholar

40. Jung, J. S., Song, K. H., Kim, S. H. Mechanical properties and biodegradability of enzyme-retted kenaf fiber composites. Textil. Res. J. 2019, 89, 1782–1791; https://doi.org/10.1177/0040517518779996.Suche in Google Scholar

41. Julias, A. A., Murali, V. Experimental impact study on unidirectional glass-carbon hybrid composite laminates. Sci. Eng. Compos. Mater. 2016, 23, 721–728; https://doi.org/10.1515/secm-2013-0063.Suche in Google Scholar

42. Vinod, A., Vijay, R., Singaravelu, D. L. ThermoMechanical characterization of calotropis gigantea stem powder-filled jute fiber-reinforced epoxy composites. J. Nat. Fibers 2018, 15, 648–657. https://doi.org/10.1080/15440478.2017.1354740.Suche in Google Scholar

43. Dinesh, S., Kumaran, P., Mohanamurugan, S., Vijay, R., Singaravelu, D. L., Vinod, A., Sanjay, M. R., Siengchin, S., Bhat, K. S. Influence of wood dust fillers on the mechanical, thermal, water absorption and biodegradation characteristics of jute fiber epoxy composites. J. Polym. Res. 2020, 27, 9; https://doi.org/10.1007/s10965-019-1975-2.Suche in Google Scholar

Received: 2023-10-04
Accepted: 2024-03-06
Published Online: 2024-03-28
Published in Print: 2024-05-27

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