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Fabrication of modified lignin-based liquid mulching film and its potential application

  • Zhonghua Sun , Jie Liang EMAIL logo , Menghua Qin , Ruxia Ning , Xin Liu , Wei Sun and Xiang Li
Published/Copyright: April 3, 2024
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Abstract

Liquid mulching film is an emerging film material to replace the traditional plastic film, which causes wide public concern. In this study, a graft copolymer (LS-AA) was synthesized from sodium lignosulfonate (LS) by free radical polymerization, which was added as enhancer to the cationic starch (CS) solutions to obtain the CLA based film. The grafting conditions was optimized by response surface methodology (RSM) for the preparation of LS-AA, after that the LS-AA was characterized by FTIR, XRD, and TG. The highest grafting rate was obtained under the reaction conditions of 80 °C for 2.6 h with the mass ratio of monomer and LS of 5.5/5 at initiator dosage of 1 %. The fabricated liquid mulching film with addition of LS-AA showed outstanding anti-ultraviolet, biodegradation, anti-erosion, which provided theoretical base and practical references for popularizing and application of liquid mulching film in the dust prevention and sand fixation.


Corresponding author: Jie Liang, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210018, China, E-mail:
Zhonghua Sun and Jie Liang contributed equally to this work.

Funding source: Shandong Provincial Key Research & Development Project

Award Identifier / Grant number: 2019GSF109110

Funding source: Research Starting Funds for Imported Talents

Award Identifier / Grant number: Y-01-2021023

Acknowledgments

The authors are grateful for the support of the Shandong Provincial Key Research & Development Project, China (Grant No. 2019GSF109110) and Research Starting Funds for Imported Talents, Taishan University, China (Grant No. Y-01-2021023).

  1. Research ethics: Not applicable.

  2. Author contributions: Zhonghua Sun: conceptualization, validation, investigation, supervision, funding acquisition. Jie Liang: conceptualization, methodology, investigation, writing-original draft, writing-review and editing. Menghua Qin: methodology, investigation, data curation. Ruxia Ning: formal analysis, visualization, investigation. Xin Liu: data curation, methodology, investigation. Wei Sun: conceptualization, investigation. Xiang Li: conceptualization, methodology, investigation.

  3. Competing interests: The authors state no conflict of interest.

  4. Research funding: Shandong Provincial Key Research & Development Project, Grant number 2019GSF109110, Research Starting Funds for Imported Talents, Grant number Y-01-2021023.

  5. Data availability: Data will be made available on request.

References

Baki, M. and Abedi-Koupai, J. (2018). Preparation and characterization of a superabsorbent slow-release fertilizer with sodium alginate and biochar. J. Appl. Polym. Sci. 135: 45966, https://doi.org/10.1002/app.45966.Search in Google Scholar

Bao, Q., Liu, Y., Li, C., Jia, L., Yan, J., Yuan, M., and Zhou, W. (2020). Development and performance characterization of a hybrid dust suppressant based on sodium ligninsulfonate modification. Starch - Stärke 73: 2000207, https://doi.org/10.1002/star.202000207.Search in Google Scholar

Barisik, G., Isci, A., Kutlu, N., Bagder Elmaci, S., and Akay, B. (2016). Optimization of organic acid pretreatment of wheat straw. Biotechnol. Prog. 32: 1487–1493, https://doi.org/10.1002/btpr.2347.Search in Google Scholar PubMed

Borrowman, C.K., Johnston, P., Adhikari, R., Saito, K., and Patti, A.F. (2020). Environmental degradation and efficacy of a sprayable, biodegradable polymeric mulch. Polym. Degrad. Stab. 175: 109126, https://doi.org/10.1016/j.polymdegradstab.2020.109126.Search in Google Scholar

Chohan, N.A., Aruwajoye, G.S., Sewsynker-Sukai, Y., and Gueguim Kana, E.B. (2020). Valorisation of potato peel wastes for bioethanol production using simultaneous saccharification and fermentation: process optimization and kinetic assessment. Renew. Energy 146: 1031–1040, https://doi.org/10.1016/j.renene.2019.07.042.Search in Google Scholar

Chung, Y.C., Park, J.E., Choi, J.W., and Chun, B.C. (2018). Synthesis and characterizations of antifungal polyurethanes with enhanced tensile and shape recovery performances. Adv. Polym. Technol. 37: 3392–3400, https://doi.org/10.1002/adv.22123.Search in Google Scholar

Dang, X., Yuan, H., and Shan, Z. (2018). An eco-friendly material based on graft copolymer of gelatin extracted from leather solid waste for potential application in chemical sand-fixation. J. Clean. Product. 188: 416–424, https://doi.org/10.1016/j.jclepro.2018.04.007.Search in Google Scholar

Dumitriu, R.P., Stoica, I., Vasilescu, D.S., Cazacu, G., and Vasile, C. (2017). Alginate/lignosulfonate blends with photoprotective and antioxidant properties for active packaging applications. J. Polym. Environ. 26: 1100–1112, https://doi.org/10.1007/s10924-017-1018-1.Search in Google Scholar

Franzoso, F., Causone, D., Tabasso, S., Antonioli, D., Montoneri, E., Persico, P., Laus, M., Mendichi, R., and Negre, M. (2015). Films made from polyethylene-co-acrylic acid and soluble biopolymers sourced from agricultural and municipal biowaste. J. Appl. Polym. Sci. 132: 41909, https://doi.org/10.1002/app.41909.Search in Google Scholar

Guo, T., Song, J., Jin, Y., Sun, Z., and Li, L. (2019). Thermally stable and green cellulose-based composites strengthened by styrene-co-acrylate latex for lithium-ion battery separators. Carbohydr. Polym. 206: 801–810, https://doi.org/10.1016/j.carbpol.2018.11.025.Search in Google Scholar PubMed

Liang, J., Ning, R., Sun, Z., Liu, X., Sun, W., and Zhou, X. (2021). Preparation and characterization of an eco-friendly dust suppression and sand-fixation liquid mulching film. Carbohydr. Polym. 256: 117429, https://doi.org/10.1016/j.carbpol.2020.117429.Search in Google Scholar PubMed

Lin, Q., Li, H., Ren, J., Deng, A., Li, W., Liu, C., and Sun, R. (2017). Production of xylooligosaccharides by microwave-induced, organic acid-catalyzed hydrolysis of different xylan-type hemicelluloses: optimization by response surface methodology. Carbohydr. Polym. 157: 214–225, https://doi.org/10.1016/j.carbpol.2016.09.091.Search in Google Scholar PubMed

Liu, H. and Chung, H. (2017). Lignin-based polymers via graft copolymerization. J. Polym. Sci. Part A: Polym. Chem. 55: 3515–3528, https://doi.org/10.1002/pola.28744.Search in Google Scholar

Liu, Y., Nie, W., Mu, Y., Zhang, H., Wang, H., Jin, H., and Liu, Z. (2018). A synthesis and performance evaluation of a highly efficient ecological dust depressor based on the sodium lignosulfonate–acrylic acid graft copolymer. RSC Adv. 8: 11498–11508, https://doi.org/10.1039/c7ra12556a.Search in Google Scholar PubMed PubMed Central

Lu, W., Zhang, H., Qi, G., Hu, X., Sun, L., Su, H., and Zhang, Q. (2022). Synthesis and properties of environmentally friendly double-network fire fighting gel: based on natural polymer/industrial solid waste. J. Appl. Polym. Sci. 139: e53111, https://doi.org/10.1002/app.53111.Search in Google Scholar

Lu, X., Que, H., Guo, H., Ding, C., Liu, X., Qin, Y., Robin, H.M., Xu, C., and Gu, X. (2021). α-Cellulose-based films: effect of sodium lignosulfonate (SLS) incorporation on physicochemical and antibacterial performance. Cellulose 28: 7243–7256, https://doi.org/10.1007/s10570-021-03949-w.Search in Google Scholar

Ma, G., Ran, F., Feng, E., Dong, Z., and Lei, Z. (2015). Effectiveness of an eco-friendly polymer composite sand-fixing agent on sand fixation. Water Air Soil Pollut. 226: 221, https://doi.org/10.1007/s11270-015-2490-7.Search in Google Scholar

Malakar, B., Das, D., and Mohanty, K. (2020). Optimization of glucose yield from potato and sweet lime peel waste through different pre-treatment techniques along with enzyme assisted hydrolysis towards liquid biofuel. Renew. Energy 145: 2723–2732, https://doi.org/10.1016/j.renene.2019.08.037.Search in Google Scholar

Nath, A. and Chattopadhyay, P.K. (2007). Optimization of oven toasting for improving crispness and other quality attributes of ready to eat potato-soy snack using response surface methodology. J. Food Eng. 80: 1282–1292, https://doi.org/10.1016/j.jfoodeng.2006.09.023.Search in Google Scholar

Núñez-Flores, R., Giménez, B., Fernández-Martín, F., López-Caballero, M.E., Montero, M.P., and Gómez-Guillén, M.C. (2012). Role of lignosulphonate in properties of fish gelatin films. Food Hydrocolloids 27: 60–71, https://doi.org/10.1016/j.foodhyd.2011.08.015.Search in Google Scholar

Qing, Q., Huang, M., He, Y., Wang, L., and Zhang, Y. (2015). Dilute oxalic acid pretreatment for high total sugar recovery in pretreatment and subsequent enzymatic hydrolysis. Appl. Biochem. Biotechnol. 177: 1493–1507, https://doi.org/10.1007/s12010-015-1829-2.Search in Google Scholar PubMed

Shankar, S., Reddy, J.P., and Rhim, J.W. (2015). Effect of lignin on water vapor barrier, mechanical, and structural properties of agar/lignin composite films. Int. J. Biol. Macromol. 81: 267–273, https://doi.org/10.1016/j.ijbiomac.2015.08.015.Search in Google Scholar PubMed

Shen, D.K., Gu, S., Luo, K.H., Wang, S.R., and Fang, M.X. (2010). The pyrolytic degradation of wood-derived lignin from pulping process. Bioresour. Technol. 101: 6136–6146, https://doi.org/10.1016/j.biortech.2010.02.078.Search in Google Scholar PubMed

Sun, Z. and Chen, F. (2016). Hydrophilicity and antifouling property of membrane materials from cellulose acetate/polyethersulfone in DMAc. Int. J. Biol. Macromol. 91: 143–150, https://doi.org/10.1016/j.ijbiomac.2016.05.072.Search in Google Scholar PubMed

Tahari, N., de Hoyos-Martinez, P.L., Abderrabba, M., Ayadi, S., and Labidi, J. (2020). Lignin - montmorillonite hydrogels as toluene adsorbent. Coll. Surfaces A Physicochem. Eng. Aspects 602: 125108, https://doi.org/10.1016/j.colsurfa.2020.125108.Search in Google Scholar

Tang, M., Han, M., Gu, W., Xu, W., Lei, F., Li, P., Jiang, J., and Ji, L. (2022). Preparation and characterization of eco-friendly polysaccharide-based liquid mulch with soil amendment function. J. Clean. Product. 363: 132586, https://doi.org/10.1016/j.jclepro.2022.132586.Search in Google Scholar

Tian, D., Zhang, J., Hu, J., Huang, M., Zhao, L., Lei, Y., Zou, J., Zhang, S., and Shen, F. (2023). A new water-soluble lignin incorporation enhanced the barrier performance of liquid mulching film. Chem. Eng. J. 452: 139383, https://doi.org/10.1016/j.cej.2022.139383.Search in Google Scholar

Wang, A., Sun, Z., Ning, R., Liang, J., Li, L., and Zhou, X. (2019). Study on cellulose/nylon 6 lithium battery separators modification by polyacrylonitrile in ionic liquid [Emim]Ac. AIP Adv. 9: 085027, https://doi.org/10.1063/1.5116286.Search in Google Scholar

Wu, R.L., Wang, X.L., Li, F., Li, H.Z., and Wang, Y.Z. (2009). Green composite films prepared from cellulose, starch and lignin in room-temperature ionic liquid. Bioresour. Technol. 100: 2569–2574, https://doi.org/10.1016/j.biortech.2008.11.044.Search in Google Scholar PubMed

Yadav, N. and Hakkarainen, M. (2021). Degradable or not? Cellulose acetate as a model for complicated interplay between structure, environment and degradation. Chemosphere 265: 128731, https://doi.org/10.1016/j.chemosphere.2020.128731.Search in Google Scholar PubMed

Yang, K. and Tang, Z. (2012). Effectiveness of fly ash and polyacrylamide as a sand-fixing agent for wind erosion control. Water Air Soil Pollut. 223: 4065–4074, https://doi.org/10.1007/s11270-012-1173-x.Search in Google Scholar

Yao, F., Shen, F., Wan, X., and Hu, C. (2020). High yield and high concentration glucose production from corncob residues after tetrahydrofuran + H2O co-solvent pretreatment and followed by enzymatic hydrolysis. Renew. Sustain. Energy Rev. 132: 110107, https://doi.org/10.1016/j.rser.2020.110107.Search in Google Scholar

Yemis, O. and Mazza, G. (2011). Acid-catalyzed conversion of xylose, xylan and straw into furfural by microwave-assisted reaction. Bioresour. Technol. 102: 7371–7378, https://doi.org/10.1016/j.biortech.2011.04.050.Search in Google Scholar PubMed

Zhang, W., Zhang, Y., Liang, H., Liang, D., Cao, H., Liu, C., Qian, Y., Lu, Q., and Zhang, C. (2019). High bio-content castor oil based waterborne polyurethane/sodium lignosulfonate composites for environmental friendly UV absorption application. Ind. Crops Prod. 142: 111836, https://doi.org/10.1016/j.indcrop.2019.111836.Search in Google Scholar

Received: 2023-10-31
Accepted: 2024-03-12
Published Online: 2024-04-03
Published in Print: 2024-06-25

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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