Home Crystal structure of catena-poly[tribenzyl-κ1C-(μ2-6-oxidopyridin-1-ium-3-carboxylato-κ2O:O’)tin(IV)-dichloromethane-methanol (1/1/1), C29H31Cl2NO4Sn
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Crystal structure of catena-poly[tribenzyl-κ1C-(μ2-6-oxidopyridin-1-ium-3-carboxylato-κ2O:O’)tin(IV)-dichloromethane-methanol (1/1/1), C29H31Cl2NO4Sn

  • Zhongjun Gao ORCID logo EMAIL logo and Haifeng Zhang
Published/Copyright: May 20, 2022
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 237 Issue 4

Abstract

C29H31Cl2NO4Sn, monoclinic, P21/n (no. 14), a = 10.638(4) Å, b = 17.168(7) Å, c = 18.399(5) Å, β = 120.573(16)°, V = 2893.1(18) Å3, Z = 4, R gt (F) = 0.0314, wR ref (F2) = 0.0875, T = 298 K.

CCDC no.: 2158088

The asymmetric unit of the title crystal structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colourless block
Size: 0.49 × 0.35 × 0.26 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 1.10 mm−1
Diffractometer, scan mode: φ and ω
θmax, completeness: 25.5°, >99%
N(hkl)measured, N(hkl)unique, Rint: 14894, 5365, 0.024
Criterion for Iobs, N(hkl)gt: Iobs > 2 σ(Iobs), 4501
N(param)refined: 335
Programs: Bruker [1], SHELX [2], Olex2 [3]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z Uiso*/Ueq
Sn1 0.15603 (2) 0.25443 (2) 0.99415 (2) 0.03244 (9)
O1 0.3616 (2) 0.26285 (12) 0.99845 (14) 0.0446 (5)
O2 0.5139 (3) 0.23656 (14) 1.13394 (15) 0.0586 (6)
O4 0.9140 (3) 0.25531 (14) 0.97169 (18) 0.0624 (7)
N1 0.6867 (2) 0.27838 (15) 0.94526 (15) 0.0416 (5)
H1 0.664332 0.294523 0.895866 0.050*
C1 0.8280 (3) 0.25667 (16) 0.99955 (19) 0.0402 (7)
C2 0.8619 (3) 0.23765 (17) 1.0825 (2) 0.0437 (7)
H2 0.957580 0.225427 1.123133 0.052*
C3 0.7563 (3) 0.23705 (16) 1.10335 (19) 0.0400 (6)
H3 0.781090 0.224768 1.158304 0.048*
C4 0.6087 (3) 0.25482 (14) 1.04280 (18) 0.0312 (6)
C5 0.5800 (3) 0.27601 (17) 0.96456 (17) 0.0379 (6)
H5 0.485028 0.289113 0.923545 0.045*
C6 0.4885 (3) 0.25093 (14) 1.06240 (19) 0.0368 (6)
C7 0.1870 (4) 0.36473 (17) 1.05591 (19) 0.0466 (7)
H7A 0.114665 0.371213 1.072650 0.056*
H7B 0.283002 0.366407 1.106361 0.056*
C8 0.1730 (4) 0.42922 (18) 0.99772 (19) 0.0480 (7)
C9 0.2933 (5) 0.4664 (2) 1.0043 (3) 0.0712 (10)
H9 0.386388 0.451898 1.046705 0.085*
C10 0.2769 (6) 0.5254 (3) 0.9481 (3) 0.0953 (15)
H10 0.358764 0.550373 0.953540 0.114*
C11 0.1404 (7) 0.5467 (2) 0.8850 (3) 0.0902 (15)
H11 0.129761 0.585651 0.847146 0.108*
C12 0.0212 (6) 0.5112 (2) 0.8777 (3) 0.0783 (12)
H12 −0.071270 0.526278 0.835053 0.094*
C13 0.0353 (4) 0.4528 (2) 0.9328 (2) 0.0594 (9)
H13 −0.047824 0.428745 0.926779 0.071*
C14 0.0323 (3) 0.25772 (16) 0.85884 (18) 0.0410 (7)
H14A −0.030413 0.212217 0.838847 0.049*
H14B −0.030255 0.303296 0.841483 0.049*
C15 0.1211 (3) 0.25991 (15) 0.81650 (17) 0.0355 (6)
C16 0.1675 (3) 0.32986 (17) 0.79970 (17) 0.0419 (7)
H16 0.142100 0.376700 0.814260 0.050*
C17 0.2515 (3) 0.33054 (19) 0.76137 (19) 0.0484 (7)
H17 0.280408 0.377822 0.749851 0.058*
C18 0.2921 (4) 0.2619 (2) 0.7403 (2) 0.0510 (8)
H18 0.347915 0.262578 0.714524 0.061*
C19 0.2491 (3) 0.1925 (2) 0.75797 (18) 0.0508 (8)
H19 0.277176 0.145837 0.744688 0.061*
C20 0.1645 (3) 0.19142 (18) 0.79533 (18) 0.0440 (7)
H20 0.136080 0.143833 0.806526 0.053*
C21 0.1906 (3) 0.13886 (17) 1.04616 (19) 0.0448 (7)
H21A 0.285568 0.135967 1.097301 0.054*
H21B 0.116831 0.126948 1.060592 0.054*
C22 0.1829 (3) 0.08103 (17) 0.98349 (19) 0.0451 (7)
C23 0.0519 (4) 0.0442 (2) 0.9271 (2) 0.0626 (9)
H23 −0.032079 0.055173 0.928970 0.075*
C24 0.0457 (6) −0.0087 (2) 0.8682 (3) 0.0843 (14)
H24 −0.042286 −0.033141 0.831453 0.101*
C25 0.1663 (6) −0.0254 (2) 0.8634 (3) 0.0851 (14)
H25 0.160854 −0.061045 0.823830 0.102*
C26 0.2961 (5) 0.0108 (2) 0.9175 (3) 0.0795 (12)
H26 0.378872 0.000039 0.914375 0.095*
C27 0.3039 (4) 0.0634 (2) 0.9769 (2) 0.0607 (9)
H27 0.392487 0.087463 1.013261 0.073*
O3 0.6395 (3) 0.33764 (18) 0.78776 (16) 0.0820 (8)
H3A 0.609829 0.315078 0.742637 0.123*
C28 0.6180 (6) 0.4162 (3) 0.7735 (3) 0.1045 (16)
H28A 0.515588 0.426538 0.737753 0.157*
H28B 0.669587 0.434351 0.746579 0.157*
H28C 0.653664 0.442832 0.826360 0.157*
Cl1 0.6663 (2) 0.07753 (11) 0.72801 (10) 0.1408 (7)
Cl2 0.63999 (17) 0.08200 (8) 0.87653 (10) 0.1133 (4)
C29 0.6466 (5) 0.1346 (3) 0.7981 (3) 0.0893 (13)
H29A 0.557529 0.164824 0.767348 0.107*
H29B 0.727612 0.170925 0.824303 0.107*

Source of material

A mixture of tribenzyltin oxide (1.6003 g, 2.0 mmol) and 6-hydroxy-nicotinic acid (0.5564 g, 4.0 mmol), in methanol (40 ml) was heated under reflux for 6 h. The obtained clear solution was evaporated under vacuum. The product was crystallized from a mixture of dichloromethane/ethanol (1:1). Yield 1.8892 g, 73%, m.p. 462 K.

Experimental details

H atoms were included in the riding model approximation with C–H 0.93–0.97 Å, and with Uiso(H) = 1.2Ueq(C) or 1.5Ueq(methyl C). The O- and N-bound H atoms were refined with O–H = 0.82+−0.01 Å and N–H = 0.86%A, and with Uiso(H) = 1.5Ueq(O) or 1.2Ueq(N).

Comment

Studies on organotin(IV) compounds having carboxylate ligands with additional donor atom, such as N, O, or S, revealed new structural types which may lead to compounds with different activities [4], [5], [6], [7], [8]. In order to exploring whether or not the hetero-atoms (N, O or S) of the carboxylic acid derivatives influence the coordination mode and extension of triaryltin compounds with heteroatom carboxylate ligands this study was undertaken.

In the title compound, the Sn atom exists in a distorted trigonal bipyramidal, surrounded axially by two oxygen atoms and equatorialy by the carbon atoms of the benzyl groups. It has an infinite one-dimensional polymeric chain structure, due to the Sn1–O1 and Sn1–O4A [symmetry operation: x−1, y, z] distances of 2.153(2) and 2.3391(2) Å, respectively, comparable to a related structure [9]. Translational pseudosymmetry is found in the title structure (klassengleich, c/2). The pseudosymmetry is mainly caused by the solvent molecules. Such a translational symmetry is an often found feature of reported structures [10].

In detail the distortions from ideal trigonal bipyramidal symmetry for the compound is reflected by the bond angles around the tin atom: C7–Sn1–O1 92.39(10)°, C7–Sn1–O4A 87.01(10)°, C14–Sn1–O1 93.04(10)°, C14–Sn1–O4A 80.10(11)°, C21–Sn1–O1 96.01(10)° and C21–Sn1–O4A 90.48(10)°, respectively. The bond angle O1–Sn1–O4A is 172.05(8)° which is deviating from the linear angle by 7.95°. The sum of the C7–Sn1–C21 129.26(13)°, C14–Sn1–C7 115.45(11)° and C14–Sn1–C21 113.93(11)° bond angles is 358.64°, which shows that the atoms of Sn1, C7, C14 and C21 are almost in the same plane. Therefore the tin atom forms a distorted trigonal bipyramidal structure. Due to the protonation at N, a coordination at this site is impossible, which is different to the tribenyltin 4-picolinate and similar others [11], [12], [13], [14].

There are strong intermolecular N–H⋯O hydrogen bonds (N1–O3 = 2.865 Å) involving pyridinium–N–H and the methanol hydroxyl O atom. There are also intermolecular O–H⋯O hydrogen bonds (O3–O2i = 2.752 Å) [symmetry code: x, −y+0.5, z−0.5] between the methanol hydroxyl O atom and the picolinic carboxyl O atom non-coordinating to Sn center.

Corresponding author: Zhongjun Gao, School of Chemistry, Chemical Engineering and Materials, Jining University, Qufu, 273155, Shandong Province, China, E-mail:

Funding source: National Natural Science Foundation of China

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This study was financially supported by National Natural Science Foundation of China (Grant No. 2217011475).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. BRUKER. SAINT, APEX2 and SADABS; Bruker AXS Inc.: Madison, Wisconsin, USA, 2009.Search in Google Scholar

2. Sheldrick, G. M. SHELXTL – integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8; https://doi.org/10.1107/s2053273314026370.Search in Google Scholar PubMed PubMed Central

3. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Search in Google Scholar

4. Lo, K. M., Lee, S. M., Tiekink, E. R. T. Crystal structure of trans-dichloridobis(4-chlorophenyl-κC1)-(1,10-phenanthroline-κ2N,N’)tin(IV) dimethylsulphoxide solvate, C26H22Cl4N2OSSn. Z. Kristallogr. N. Cryst. Struct. 2020, 235, 1327–1329; https://doi.org/10.1515/ncrs-2020-0302.Search in Google Scholar

5. Gao, Z. J., Tian, G. R., Zhao, G. W., Si, C. D. Synthesis and structure of a novel tetranuclear 32-membered macrocycle of triphenyltin complex with pyridine-4-carboxylic acid N-oxide. Inorg. Chem. Commun. 2010, 13, 461–463; https://doi.org/10.1016/j.inoche.2009.12.026.Search in Google Scholar

6. Lee, S. M., Lo, K. M., Tiekink, E. R. T. Crystal structure of 4-(dimethylamino)pyridinium dibromido-tris(4-chlorophenyl-κC1)stannate(IV), C25H23Br2Cl3N2Sn. Z. Kristallogr. N. Cryst. Struct. 2021, 236, 1267–1269; https://doi.org/10.1515/ncrs-2021-0298.Search in Google Scholar

7. Ma, C. L., Zhang, J. H., Tian, G. R., Zhang, R. F. Syntheses, crystal structures and coordination modes of tri- and di-organotin derivatives with 2-mercapto-4-methylpyrimidine. J. Organomet. Chem. 2005, 690, 519–533; https://doi.org/10.1016/j.jorganchem.2004.10.020.Search in Google Scholar

8. Yin, H. D., Wang, C. H., Wang, Y., Ma, C. L., Wang, D. Q. Synthesis and characterization of triorganotin esters of heteroaromatic carboxylic acid and crystal structure of (Bu3SnO2CCH2C8H6N)–Bu-n and (PhCH2)3SnO2CC5H4N. Indian J. Chem. 2003, 42, 881–888.Search in Google Scholar

9. Vollano, J. F., Day, R. O., Holmes, R. R. Hydrolysis pathway leading to the formation of novel oxo- and halo-bridged tin(IV) ladder compounds. The molecular structure of the dimeric distannoxanes [Ph2(Cl)SnOSnPh2(OH)]2·2(CH3)2CO and [Ph2(Cl)SnOSnPh2(Cl)]2. Organometallics 1984, 3, 745–750; https://doi.org/10.1021/om00083a017.Search in Google Scholar

10. Gielen, M., Dalil, H., Ghys, L., Boduszek, B., Tiekink, E. R. T., Martins, J. C., Biesemans, M., Willem, R. Synthesis and structure of di-n-butyltin pyridine-2-phosphonate-6-carboxylate. Organometallics 1998, 17, 4259–4262; https://doi.org/10.1021/om9803725.Search in Google Scholar

11. Reiss, G. J. The pseudosymmetric crystal structure of bis((dimethylphosphoryl)-methanaminium oxonium tribromide, C6H25Br3N2O3P2. Z. Kristallogr. N. Cryst. Struct. 2013, 228, 431–433; https://doi.org/10.1524/ncrs.2013.0203.Search in Google Scholar

12. Lee, M. S., Lo, K. M., Tiekink, E. R. T. Redetermination of the crystal structure of catena-poly[[tribenzyltin(IV)]-(μ2-pyridine-4- carboxylato-κ2N:O)], C27H25NO2Sn. Z. Kristallogr. N. Cryst. Struct. 2019, 234, 835–837; https://doi.org/10.1515/ncrs-2019-0146.Search in Google Scholar

13. Li, F. H., Yin, H. D., Li, G., Wang, D. Q. Tri-n-butyl(5-chloro-6- hydroxypyridine-3-carboxylato)tin(IV). Acta Crystallogr. 2006, E62, 645–647; https://doi.org/10.1107/S1600536806006659.Search in Google Scholar

14. Gao, Z. J., Yin, H. D., Li, G., Wang, D. Q. catena- Poly[[triphenyltin(IV)]-μ-6-hydroxypyridine-3-carboxylato]. Acta Crystallogr. 2006, E62, 666–667; https://doi.org/10.1107/S1600536806006726.Search in Google Scholar
Received: 2022-03-27
Accepted: 2022-05-05
Published Online: 2022-05-20
Published in Print: 2022-08-26

© 2022 Zhongjun Gao and Haifeng Zhang, published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  58. Crystal structure of 2-(1H-pyrazol-3-yl-κN)pyridine-κN-bis(2-(2,4-difluorophenyl)pyridinato-κ2C,N)iridium(III) sesquihydrate, C30H18F4IrN5·1.5[H2O]
  59. Crystal structure of 2-(2-hydroxy-5-nitrophenyl)-5-methyl-1,3-dioxane-5-carboxylic acid, C12H13N1O7
  60. The crystal structure of 1,2-bis(pyridinium-4-yl)ethane diperchlorate, C12H14N2·2ClO4 – a second polymorph
  61. The crystal structure of [(1,10-phenantroline-κ2N,N′)-bis(6-phenylpyridine-2-carboxylato-κ2N,O)manganese(II)] monohydrate, C36H26N4O5Mn
  62. Crystal structure of 1,2-bis(2,2,3,3,5,5,5-heptamethyl-1,1,4,4- tetrakis(trimethylsilyl)pentasilan-1-yl)ditellane, C38H114Si18Te2
  63. Crystal structure of 1,2-bis(2,4-dinitro-1H-imidazol-1-yl)ethane – dimethylformamide (1/1), C11H13N9O9
  64. Crystal structure of (Z)-3-((tert-butylamino) methylene)-2-(2-hydroxynaphthalen-1-yl) chroman-4-one, C24H23NO3
  65. Synthesis and crystal structure of (E)-1-(4-(((E)-3-(tert-butyl)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-ethyl oxime, C21H26N2O2
  66. Crystal structure of the double salt bis(5-amino-1,2,4-triazol-4-ium-3-yl)methane hydrogen oxalate hemioxalate, C8H11N8O6
  67. Hydrothermal synthesis and crystal structure of catena-poly[diaqua-bis(μ2-4-[(4-pyridinylmethyl)amino]benzoato-κ2N:O)cobalt(II)]–1,2bi(4-pyridyl)ethene–water (1/1/1), C50H50N8O8Co
  68. Crystal structure of 3-(3-bromophenyl)-1′,3′-dimethyl-2′H,3H,4H-spiro[furo[3, 2-c]chromene-2,5′-pyrimidine]-2′,4,4′,6′(1′H,3′H) tetraone, C22H15BrN2O6
  69. The crystal structure of poly[aqua-(μ2-4,4′- bis(imidazolyl)biphenyl-κ2N:N′)-(μ2-3-nitrobenzene-1,2-dicarboxylato-κ2O:O′)]copper (II) hydrate, C26H21N5O8Cu
  70. The crystal structure of bis(4-(6-carboxy-8-ethyl-3-fluoro-5-oxo-5,8-dihydro-1,8-naphthyridin-2- yl)piperazin-1-ium) adipate tetrahydrate, C36H52F2N8O14
  71. Synthesis and crystal structure of poly[aqua(μ4-(1R,2S,4R)-4-hydroxy-1-((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)pyrrolidin-1-ium-2-carboxylate-κ4O:O′:O″:O‴)sodium(I)] monohydrate, C21H22NNaO12S
  72. Crystal structure of chlorido-(η6-toluene)(2,2′-bipyridine-κ2N,N′)ruthenium(II) hexafluorophosphate, C17H16ClN2RuPF6
  73. The crystal structure of (R)-6-hydroxy-8-methoxy-3-methylisochroman-1-one, C11H12O4
  74. Crystal structure of catena-poly[(5,5,7,12,12,14-hexamethyl -1,4,8,11-tetraazacyclotetradecane- κ4N,N′,Nʺ,N‴)nickel(II)-(μ2-perchlorato-κ2O:O′)] 3,5-dicarboxybenzoate – methanol (1/2), C27H49ClN4NiO12
  75. The crystal structure of 4-(chloromethyl)benzonitrile, C8H6ClN
  76. The crystal structure of dimethylammonium 8-[(7,9-dioxo-6,10-dioxaspiro[4.5]decan-8-ylidene)methyl]-9-oxo-6,10-dioxaspiro[4.5]dec-7-en-7-olate, C19H25NO8
  77. Crystal structure of (2R,3S,4S,5R,6S)-2-(acetoxymethyl)-6-((1-acetyl-5-bromo-4-chloro-1H-indol-3-yl)oxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate hemihydrate C24H25BrClNO11
  78. The crystal structure of the co-crystal tetrakis[2-(tris(4-methoxyphenyl)stannyl)ethyl]silane – tetrahydrofuran – toluene – tetrahydrofurane (1/1/1), C103H116O13SiSn4
  79. Crystal structure of methyl 3-(1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)propanoate, C16H13NO4
  80. Crystal structure of ethyl (Z)-3-amino-2-cyano-3-(2-oxo-2H-chromen-3-yl)acrylate, C15H12N2O4
  81. Crystal structure of methyl 2-(1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)acetate, C15H11NO4
  82. Crystal structure of catena-poly[diaqua-bis(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2N:N′)cobalt(II)] tetrafluoroterephthalate, C26H28N8O6F4Co
https://doi.org/10.1515/ncrs-2022-0147
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. Crystal structure of N-((3s,5s,7s)-adamantan-1-yl)-2-(3-benzoylphenyl)propanamide, C26H29NO2
  4. The crystal structure of bis(μ2-5-chloro-2-oxido-N-(1-oxidopropylidene)benzohydrazonato-κ5 N,O,O′:N′,O′′)-octakis(pyridine-κ1 N)trinickel(II) C60H56Cl2N12Ni3O6
  5. The crystal structure of 3-(4-chlorophenyl)-1,5-di-p-tolylpentane-1,5-dione, C25H23ClO2
  6. The crystal structure of 2,4,4-triphenyl-4H-benzo[b][1,4]oxaphosphinin-4-ium bromide – dichloromethane (1/1), C27H22BrCl2OP
  7. The crystal structure of 2-(3,6-di-tert-butyl-1,8-diiodo-9H-carbazol-9-yl)acetonitrile, C22H24I2N2
  8. Crystal structure of 3-phenylpropyl 2-(6-methoxynaphthalen-2-yl)propanoate, C23H24O3
  9. The crystal structure of (4-fluorophenyl)(5-(hydroxymethyl)furan-2-yl)methanol, C12H11FO3
  10. Crystal structure of the dihydrate of tetraethylammonium 1,3,5-thiadiazole-5-amido-2-carbamate, C11H27N5O4S
  11. Crystal structure of (Z)-4-[(p-tolylamino)(furan-2-yl)methylene]-3-phenyl-1-1-p-tolyl-1H-phenyl-1H-pyrazol-5(4H)-one, C28H23N3O2
  12. The crystal structure of (E)-3-(2-chlorophenyl)-1-ferrocenylprop-2-en-1-one, C19H15ClFeO
  13. The pseudosymmetric crystal structure of 3-((1R,2S)-1-methylpyrrolidin-1-ium-2-yl)pyridin-1-ium hexachloridostannate(IV), C10H16N2SnCl6
  14. Crystal structure of (2-(1-hydroxyheptyl)octahydro-8aH-chromene-5,8,8a-triol), C16H30O5
  15. The crystal structure of N-cyclohexyl-3-hydroxy-4-methoxybenzamide, C14H19NO3
  16. Crystal structure of 1-(4-hydroxybenzyl)-4-methoxy-9,10-dihydrophenanthrene-2,7-diol from Arundina graminifolia, C22H20O4
  17. The crystal structure of N-cyclopentyl-3-hydroxy-4-methoxybenzamide, C13H17NO3
  18. The crystal structure of 2,5,5-triphenyl-3,5-dihydro-4H-imidazol-4-one, C21H16N2O
  19. Crystal structure of 1H-1,2,3-Triazolo[4,5-b]-pyridin-4-ium nitrate, C5H5N5O3
  20. Crystal structure of (Z)-4-(((4-bromophenyl)amino)(furan-2-yl)methylene)-2,5-diphenyl-2,4-dihydro-3H-pyrazol-3-one, C26H18BrN3O2
  21. Crystal structure of 2-(4-methoxyphenyl)-3-methyl-1,8-naphthyridine, C16H14N2O
  22. The crystal structure of 3-([1,1′-biphenyl]-2-yl)-1,2-diphenylbenzo[b]phosphole-1-oxide, C32H23OP
  23. The crystal structure of ammonium (E)-4-((4-carboxyphenyl)diazenyl)benzoate, C14H13N3O4
  24. Crystal structure of bis(5-amino-1,2,4-triazol-4-ium-3-yl)methane sulfate, C5H10N8O4S
  25. The crystal structure of phenantroline-κ2 N,N′-bis(6-phenylpyridine-2-carboxylato-κ2 N,O)copper(II), C36H24N4O4Cu
  26. The crystal structure of tris(6-methylpyridin-2-yl)phosphine oxide, C18H18N3OP
  27. The crystal structure of N-(2′-hydroxymethyl-5′-phenyl-3′,4′-dihydro-[1,1′:3′,1″-terphenyl]- 1′(2′H)-yl)-P,P-diphenylphosphinic amide, C37H34NO2P
  28. Crystal structure of (E)-4-(6-(4-(2-(pyridin-4-yl)vinyl)phenoxy)pyrimidin-4-yl)morpholine, C21H20N4O2
  29. Crystal structure of 5-(adamantan-1-yl)-3-[(4-trifluoromethylanilino)methyl]-2,3-dihydro-1,3,4-oxadiazole-2-thione, C20H22F3N3OS
  30. Crystal structure of 2,2-dichloro-1-(4-chloro-1H-indol-1-yl)ethan-1-one, C10H6Cl3NO
  31. The crystal structure of 4-(((3-bromo-5-(trifluoromethyl)pyridin-2-yl)oxy)methyl)benzonitrile, C28H16Br2F6N4O2
  32. The crystal structure of 1H-benzimidazole-2-carboxamide, C8H7N3O
  33. The crystal structure of Histidinium hydrogensquarate, C10H11N3O6
  34. The crystal structure of 3-amino-5-carboxypyridin-1-ium iodide, C6H7IN2O2
  35. Crystal structure of (E)-amino(2-(3-ethoxy-4-hydroxybenzylidene)hydrazineyl)methaniminium nitrate hemihydrate C10H16N5O5.5
  36. Crystal structure of 1,2-bis(4,5-dinitro-1H-imidazol-1-yl)ethane, C8H6N8O8
  37. The crystal structure of diaqua-bis(pyrazolo[1,5-a]pyrimidine-3-carboxylato-κ2N,O)manganese(II), C14H12N6O6Mn
  38. The crystal structure of catena-poly[aqua-2,2′bipyridine-κ2N,N′-(μ2-5-ethoxyisophthalato-κ 4O,O′:Oʺ,O′ʺ)cadmium(II)] monohydrate, C20H20CdN2O7
  39. The crystal structure of (1S,3R)-1-(4-isopropylphenyl)-3-(methoxycarbonyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indol-2-iumchloride monohydrate, C22H27ClN2O3
  40. Crystal structure of 1-isopropyl-3-(prop-1-en-2-yl)-1H-pyrazolo[3,4-d]pyrimidin-4-amine, C11H15N5
  41. The crystal structure of (2,2′-bipyridine-κ2N,N′)- bis(6-phenylpyridine-2-carboxylate-κ2N,O)manganese(II)] monohydrate, C34H26N4O5Mn
  42. Crystal structure of the cocrystal 1,3,5,7-tetranitro-1,3,5,7-tetrazoctane ─ 2,3-dihydroindole (1/1), C12H17N9O8
  43. Crystal structure of 3-acetyl-6-hydroxy-2H-chromen-2-one monohydrate, C11H10O5
  44. Crystal structure of 6,9-diamino-2-ethoxyacridinium 3,5-dinitrobenozate — dimethylsulfoxide — water (1/1/1), C24H27N5O9S
  45. The crystal structure of 4,4′-bipyridinium bis-(2-hydroxy-3-methoxybenzoate), 2(C8H7.68O4)·C10H8.64N2
  46. Crystal structure of (Z)-4-(((4-fluorophenyl)amino)(furan-2-yl)methylene)-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one
  47. The crystal structure of bis(4-chloro-2-(((2-chloroethyl)imino)methyl)phenolato-κ2N,O)-oxidovanadium(IV), C18H16Cl4N2O3V
  48. The crystal structure of 17-(bromoethynyl)-17-hydroxy-10, 13-dimethyl- 1,2,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-3H-cyclopenta[a]phenanthren-3-one, C21H27BrO2
  49. The crystal structure of 4-((6-fluoropyridin-2-yloxy)methyl)benzonitrile, C13H9FN2O
  50. Crystal structure of (Z)-2-(1-bromo-2-phenylvinyl)-5-ethyl-2-methyl-1,3-dioxane-5-carboxylic acid, C15H17Br1O4
  51. Crystal structure of catena-poly[tribenzyl-κ1C-(μ2-6-oxidopyridin-1-ium-3-carboxylato-κ2O:O’)tin(IV)-dichloromethane-methanol (1/1/1), C29H31Cl2NO4Sn
  52. Crystal structure of bis{2-(tert-butyl)-6-((E)-((4-((E)-1-(methoxyimino)ethyl)phenyl)imino)methyl)phenolato-κ2N,O}zinc(II), C40H46N4O4Zn
  53. Crystal structure of diaqua-bis(μ2-2-carboxy-3,4,5,6-tetrafluorobenzoato-κ2O:O′)-bis(phenanthroline-κ2N,N′)-bis(μ2-3,4,5,6-tetrafluorophthalato-κ3O:O,O′)dieuropium(III) – phenanthroline (1/2), C40H19EuF8N4O9
  54. The crystal structure of diaqua-bis(6-phenylpyridine-2-carboxylato-κ2N,O) manganese(II) — water — dimethylformamide (1/2/1), C27H31N3O9Mn
  55. The crystal structure of bis(pyrazolo[1,5-a]pyrimidine-3-carboxylato-κ2N,O)-copper(ii), C14H8N6O4Cu
  56. Crystal structure of poly[(μ2-1-(1-imidazolyl)-4-(imidazol-1-ylmethyl)benzene-κ2N:N′)-(μ3-pyridazine-4,5-dicarboxylate-κ3O:O′:N)]copper(II) hydrate, C19H16CuN6O5
  57. Crystal structure of acrinidinium tetrafluorohydrogenphthalate, C21H11F4NO4
  58. Crystal structure of 2-(1H-pyrazol-3-yl-κN)pyridine-κN-bis(2-(2,4-difluorophenyl)pyridinato-κ2C,N)iridium(III) sesquihydrate, C30H18F4IrN5·1.5[H2O]
  59. Crystal structure of 2-(2-hydroxy-5-nitrophenyl)-5-methyl-1,3-dioxane-5-carboxylic acid, C12H13N1O7
  60. The crystal structure of 1,2-bis(pyridinium-4-yl)ethane diperchlorate, C12H14N2·2ClO4 – a second polymorph
  61. The crystal structure of [(1,10-phenantroline-κ2N,N′)-bis(6-phenylpyridine-2-carboxylato-κ2N,O)manganese(II)] monohydrate, C36H26N4O5Mn
  62. Crystal structure of 1,2-bis(2,2,3,3,5,5,5-heptamethyl-1,1,4,4- tetrakis(trimethylsilyl)pentasilan-1-yl)ditellane, C38H114Si18Te2
  63. Crystal structure of 1,2-bis(2,4-dinitro-1H-imidazol-1-yl)ethane – dimethylformamide (1/1), C11H13N9O9
  64. Crystal structure of (Z)-3-((tert-butylamino) methylene)-2-(2-hydroxynaphthalen-1-yl) chroman-4-one, C24H23NO3
  65. Synthesis and crystal structure of (E)-1-(4-(((E)-3-(tert-butyl)-2-hydroxybenzylidene)amino)phenyl)ethan-1-one O-ethyl oxime, C21H26N2O2
  66. Crystal structure of the double salt bis(5-amino-1,2,4-triazol-4-ium-3-yl)methane hydrogen oxalate hemioxalate, C8H11N8O6
  67. Hydrothermal synthesis and crystal structure of catena-poly[diaqua-bis(μ2-4-[(4-pyridinylmethyl)amino]benzoato-κ2N:O)cobalt(II)]–1,2bi(4-pyridyl)ethene–water (1/1/1), C50H50N8O8Co
  68. Crystal structure of 3-(3-bromophenyl)-1′,3′-dimethyl-2′H,3H,4H-spiro[furo[3, 2-c]chromene-2,5′-pyrimidine]-2′,4,4′,6′(1′H,3′H) tetraone, C22H15BrN2O6
  69. The crystal structure of poly[aqua-(μ2-4,4′- bis(imidazolyl)biphenyl-κ2N:N′)-(μ2-3-nitrobenzene-1,2-dicarboxylato-κ2O:O′)]copper (II) hydrate, C26H21N5O8Cu
  70. The crystal structure of bis(4-(6-carboxy-8-ethyl-3-fluoro-5-oxo-5,8-dihydro-1,8-naphthyridin-2- yl)piperazin-1-ium) adipate tetrahydrate, C36H52F2N8O14
  71. Synthesis and crystal structure of poly[aqua(μ4-(1R,2S,4R)-4-hydroxy-1-((7-hydroxy-3-(4-hydroxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)pyrrolidin-1-ium-2-carboxylate-κ4O:O′:O″:O‴)sodium(I)] monohydrate, C21H22NNaO12S
  72. Crystal structure of chlorido-(η6-toluene)(2,2′-bipyridine-κ2N,N′)ruthenium(II) hexafluorophosphate, C17H16ClN2RuPF6
  73. The crystal structure of (R)-6-hydroxy-8-methoxy-3-methylisochroman-1-one, C11H12O4
  74. Crystal structure of catena-poly[(5,5,7,12,12,14-hexamethyl -1,4,8,11-tetraazacyclotetradecane- κ4N,N′,Nʺ,N‴)nickel(II)-(μ2-perchlorato-κ2O:O′)] 3,5-dicarboxybenzoate – methanol (1/2), C27H49ClN4NiO12
  75. The crystal structure of 4-(chloromethyl)benzonitrile, C8H6ClN
  76. The crystal structure of dimethylammonium 8-[(7,9-dioxo-6,10-dioxaspiro[4.5]decan-8-ylidene)methyl]-9-oxo-6,10-dioxaspiro[4.5]dec-7-en-7-olate, C19H25NO8
  77. Crystal structure of (2R,3S,4S,5R,6S)-2-(acetoxymethyl)-6-((1-acetyl-5-bromo-4-chloro-1H-indol-3-yl)oxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate hemihydrate C24H25BrClNO11
  78. The crystal structure of the co-crystal tetrakis[2-(tris(4-methoxyphenyl)stannyl)ethyl]silane – tetrahydrofuran – toluene – tetrahydrofurane (1/1/1), C103H116O13SiSn4
  79. Crystal structure of methyl 3-(1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)propanoate, C16H13NO4
  80. Crystal structure of ethyl (Z)-3-amino-2-cyano-3-(2-oxo-2H-chromen-3-yl)acrylate, C15H12N2O4
  81. Crystal structure of methyl 2-(1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)acetate, C15H11NO4
  82. Crystal structure of catena-poly[diaqua-bis(μ2-1,3-di(1H-imidazol-1-yl)propane-κ2N:N′)cobalt(II)] tetrafluoroterephthalate, C26H28N8O6F4Co
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