The Application of Photocatalytic Oxidation in Removing Pentachlorophenol from Contaminated Water
-
D. P. Ho
,
H. H. Ngo
Abstract
The degradation of sodiumsalt of pentachlorophenol (PCPS) by photocatalysis with titaniumdioxide (TiO2) as the catalyst was investigated. The residual PCPS after photo-degradation was analyzed by high performance liquid chromatograph (HPLC) while the concentration of the chloride ion (Cl-) was measured by ion chromotography. The results show that the degradation of PCPS by heterogeneous photocatalysis with UV/TiO2 reaction was much faster and more complete compared to the rate of UV irradiation alone. The suitable dose of catalyst to degrade the [PCPS] with a concentration of 10-40 mg.L-1 was found to be as low as 0.05 g.L-1. As the influent PCPS concentration increased to 60-80 mg.L-1, the required TiO2 dose doubled. The first order and Sips (combination of Langmuir - Hinshelwood kinetics) kinetics were used to predict the degradation rate of organic contaminants treated by illuminated TiO2. The results showed that the Sips model fitted well with the experimental data. During the photocatalytic degradation of PCPS, the pH value reduced (from 8.1 to 3.5) with the reaction time while the concentration of Cl- increased significantly. This finding indicates the decholorination and formation of intermediates during the oxidation process.
© 2016 by Walter de Gruyter Berlin/Boston
Articles in the same Issue
- Achieving Stable Biological Oxidation of Erratic Waste Gas Streams by Utilizing Cyclic Adsorption/Desorption Beds
- Production of Titanium Dioxide Nanoparticles and Nanostructures from Dye Wastewater Sludge - Characterisation and Evaluation of Photocatalytic activity
- The Application of Photocatalytic Oxidation in Removing Pentachlorophenol from Contaminated Water
- H2O2/UV-C Treatment of the Economically Important Naphthalene Sulfonate J-Acid: Process Optimization, Kinetic Evaluation and Activated Sludge Inhibition
- Nonthermal Plasma Destruction of Trifluoromethane Using a Dielectric- Packed Bed Reactor
- Investigation of Electric Discharge Sound in Atmospheric Pressure Plasma
- Chlorophenols Contaminated Soil Remediation by Peroxidation
- Synthesis, Characterization and Visible-Light Photocatalytic Activity of La2O3/SnO2 Nanocomposite
- Electrical Discharge Characteristics Using a Bubble in Water and Their Applications to the Water Treatment
- Development of Higher Yield Ozonizer Based on Nano-Seconds Pulsed Discharge
- Ozone Mass Transfer in a Recirculating Loop Semibatch Reactor Operated at High Pressure
- Arc Plasma for Materials Detoxification and their Conversion
- Comparison of Photocatalytic Activities of Commercial Titanium Dioxide Powders Immobilised on Glass Substrates
- Coupling of Adsorption on Zeolite and V-UV Irradiation for the Treatment of VOC Containing Air Streams: Effect of TiO2 on the VOC Degradation Efficiency
- Anaerobic Photocatalytic Oxidation of Carbohydrates in Aqueous Pt/TiO2 Suspensions with Simultaneous Production of Hydrogen
- Using Water Hydrogen Instead of Reducing Gas in the Production of Direct Reduced Iron (DRI)
Articles in the same Issue
- Achieving Stable Biological Oxidation of Erratic Waste Gas Streams by Utilizing Cyclic Adsorption/Desorption Beds
- Production of Titanium Dioxide Nanoparticles and Nanostructures from Dye Wastewater Sludge - Characterisation and Evaluation of Photocatalytic activity
- The Application of Photocatalytic Oxidation in Removing Pentachlorophenol from Contaminated Water
- H2O2/UV-C Treatment of the Economically Important Naphthalene Sulfonate J-Acid: Process Optimization, Kinetic Evaluation and Activated Sludge Inhibition
- Nonthermal Plasma Destruction of Trifluoromethane Using a Dielectric- Packed Bed Reactor
- Investigation of Electric Discharge Sound in Atmospheric Pressure Plasma
- Chlorophenols Contaminated Soil Remediation by Peroxidation
- Synthesis, Characterization and Visible-Light Photocatalytic Activity of La2O3/SnO2 Nanocomposite
- Electrical Discharge Characteristics Using a Bubble in Water and Their Applications to the Water Treatment
- Development of Higher Yield Ozonizer Based on Nano-Seconds Pulsed Discharge
- Ozone Mass Transfer in a Recirculating Loop Semibatch Reactor Operated at High Pressure
- Arc Plasma for Materials Detoxification and their Conversion
- Comparison of Photocatalytic Activities of Commercial Titanium Dioxide Powders Immobilised on Glass Substrates
- Coupling of Adsorption on Zeolite and V-UV Irradiation for the Treatment of VOC Containing Air Streams: Effect of TiO2 on the VOC Degradation Efficiency
- Anaerobic Photocatalytic Oxidation of Carbohydrates in Aqueous Pt/TiO2 Suspensions with Simultaneous Production of Hydrogen
- Using Water Hydrogen Instead of Reducing Gas in the Production of Direct Reduced Iron (DRI)
