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Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}

  • Tiruppatur Subramaniam Lakshmi Narasimhan , Dieter Kath , Egbert Wessel , Torsten Markus EMAIL logo and Klaus Hilpert
Published/Copyright: January 11, 2022
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 97 Issue 6

Abstract

Vaporisation studies on Al–Ni alloys with x(Ni) = 0.43, 0.42, 0.35, and 0.32 were carried out by Knudsen effusion mass spectrometry. Partial pressure-temperature relations of Al(g) over the two phase regions {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni} were determined in the temperature ranges 1104 – 1278 K and 1021 –1122 K, respectively. The corresponding equations are log(p(Al)/Pa) = –(20 039 ± 84)/T(K) + (13.464 ± 0.070) for {AlNi + Al3Ni2} and log(p(Al)/Pa) = – (16 836 ± 235)/T(K) + (11.345 ± 0.219) for {Al3Ni2 + Al3Ni}. The vaporisation reactions, Al3Ni2.025(s) = 2.6436AlNi0.766(s) + 0.3564Al(g) and Al3Ni(s) = 0.572Al3Ni1.747(s) + 1.284Al(g) were evaluated and subsequently the enthalpy and Gibbs energy of formation of Al3Ni1.747(s) were derived.

Keywords: Al– Ni; Knudsen effusion mass spectrometry; Vaporisation; Thermodynamics
Dr. Torsten Markus Forschungszentrum Jülich GmbH Institut für Werkstoffe und Verfahren der Energietechnik (IWV-2) D-52425 Jülich, Germany Tel.: +49 2461 61 4470 Fax: +49 2461 61 3699

Dedicated to Professor Dr. Fritz Aldinger on the occasion of his 65th birthday

  1. We acknowledge Mr. P. Lersch of IWV-2 for XRD characterisation of the samples. TSLN thanks the Indo-German bilateral agreement on cooperation in science and technology for the support.

References

[1] K. Hilpert, D. Kobertz, V. Venugopal, M. Miller, H. Gerads, F.J. Bremer, H. Nickel: Z. Naturforsch. A 42 (1987) 1327.10.1515/zna-1987-1117Search in Google Scholar

[2] D. Raj, L. Bencze, D. Kath, W.A. Oates, J. Herrmann, L.Singheiser, K. Hilpert: Intermetallics 11 (2003) 1119.10.1016/S0966-9795(03)00149-3Search in Google Scholar

[3] L. Bencze, D.D. Raj, D. Kath, W.A. Oates, L.Singheiser, K. Hilpert: Metall. Mater. Trans B 35 (2004) 867.10.1007/s11663-004-0081-xSearch in Google Scholar

[4] T.S. Lakshmi Narasimhan, D. Kath, T. Markus, K. Hilpert: accepted for publication in Z. Metallkd.Search in Google Scholar

[5] K. Hilpert, M. Albers, M. Eckert, D. Kath, in: M.V. Nathal, R. Darolia, C.T. Liu, P.L. Martin, D.B. Miracle, R. Wagner, M. Yamaguchi (Eds.) Structural Intermetallics, Proc. 2nd Int. Symp. Structural Intermetallics, TMS Warrendale, PA (1997) 63.Search in Google Scholar

[6] T.B. Massalski (Ed.): Binary Alloy Phase Diagrams, ASM Metals Park, OH 1 (1986) 140.Search in Google Scholar

[7] R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, K.K. Kelley: Selected Values of the Thermodynamic Properties of Binary Alloys, American Society for Metals, Metals Park, Ohio (1973).Search in Google Scholar

[8] P.D. Desai: J. Phys. Chem. Ref. Data 16 (1987) 109.10.1063/1.555788Search in Google Scholar

[9] O. Kubaschewski: Trans. Faraday Soc. 54 (1958) 814.10.1039/tf9585400814Search in Google Scholar

[10] J. Wang, H.J. Engell: Steel Res. 63 (1992) 320.10.1002/srin.199200527Search in Google Scholar

[11] S.C. Schaefer: Bureau of mines report U.S. No. 7993, 1975.Search in Google Scholar

[12] V.M. Es’kov, V.V. Samokhval, A.A. Vecher: Metall. 2 (1974) 199.Search in Google Scholar

[13] A. Steiner, K.L. Komarek: Trans. Metall. Soc. AIME 230 (1964) 786.Search in Google Scholar

[14] N.C. Oforka: Ind. J. Chem. A 25 (1986) 1027.10.1021/i200035a030Search in Google Scholar

[15] K. Hilpert, K. Ruthardt: Ber. Bunsenges Phys. Chem. 91 (1987) 724.10.1002/bbpc.19870910707Search in Google Scholar

[16] K. Hilpert, K.A. Gingerich: Int. J. Mass Spectrom. Ion Phys. 47 (1983) 247.10.1016/0020-7381(83)87181-2Search in Google Scholar

[17] V.S. Yungmann, V.A. Medvedev, I.V. Veits, G.A. Bergman: IVTAN-THERMO – A Thermodynamic Database and Software System for the Personal Computer, CRC Press and Begel House, Boca Raton, FL, 1993.Search in Google Scholar

[18] J.B. Mann, in: K. Ogata, T. Hayakawa (Eds.), Recent Developments in Mass Spectrometry. In: Proceedings of the International Conference on Mass Spectrometry, Univ. Tokyo Press, Tokyo, Japan (1970) 814 and personal communication.Search in Google Scholar

[19] M.W. Chase, Jr.: NIST-JANAF Thermochemical Tables Fourth Edition, J. Phys. Chem. Ref. Data monograph No. 9 (1998).Search in Google Scholar

[20] I. Barin: Thermochemical Data of Pure Substances, Third Edition, VCH, Weinheim (1995).10.1002/9783527619825Search in Google Scholar

[21] T.S. Lakshmi Narasimhan, M. Sai Baba, R. Balasubramanian, S. Nalini, R. Viswanathan: J. Chem. Thermodyn. 34 (2002) 103.10.1006/jcht.2001.0871Search in Google Scholar
Received: 2006-01-19
Accepted: 2006-03-08
Published Online: 2022-01-11

© 2006 Carl Hanser Verlag, München

Articles in the same Issue

  1. Frontmatter
  2. Microstructure and mechanical behavior of Pt-modified NiAl diffusion coatings
  3. Evolution of C-rich SiOC ceramics
  4. Evolution of C-rich SiOC ceramics
  5. Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
  6. Thermodynamic analysis of structural transformations induced by annealing of amorphous Si–C–N ceramics derived from polymer precursors
  7. Thermodynamic modelling of the Ce–Ni system
  8. Thermodynamic assessment of the Ce–O system in solid state from 60 to 67 mol.% O
  9. Phase transformations of iron nitrides at low temperatures (< 700 K) – application of mechanical mixtures of powders of nitrides and iron
  10. Effect of organic self-assembled monolayers on the deposition and adhesion of hydroxyapatite coatings on titanium
  11. Reconstruction and structural transition at metal/diamond interfaces
  12. Microstructure, hardness, and fracture toughness evolution of hot-pressed SiC/Si3N4 nano/micro composite after high-temperature treatment
  13. High-temperature plasticity of SiC sintered with Lu2O3-AlN additives
  14. Interaction of functionalised surfaces on silica with dissolved metal cations in aqueous solutions
  15. XRD and TEM study of NiO–LSGM reactivity
  16. Microstructure and dielectric properties of nanoscale oxide layers on sintered capacitor-grade niobium and V-doped niobium powder compacts
  17. Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}
  18. Aqueous solution deposition of indium hydroxide and indium oxide columnar type thin films
  19. Thermodynamic properties of B2-AlFeNi alloys: modelling of the B2-AlFe and B2-AlNi phases
  20. Kinetics of precipitate formation in (TixWyCrz)B2 solid solutions: influence of Cr concentration and Co impurities
  21. On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)
  22. Out-of-pile chemical compatibility of Pb–Bi eutectic alloy with Graphite
  23. Microstructural characterisation of a Co–Cr–Mo laser clad applied on railway wheels
  24. The Na–H system: from first-principles calculations to thermodynamic modeling
  25. Personal
  26. Conferences
  27. Frontmatter
  28. Basic
  29. Microstructure and mechanical behavior of Pt-modified NiAl diffusion coatings
  30. Evolution of C-rich SiOC ceramics
  31. Evolution of C-rich SiOC ceramics
  32. Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
  33. Thermodynamic analysis of structural transformations induced by annealing of amorphous Si–C–N ceramics derived from polymer precursors
  34. Thermodynamic modelling of the Ce–Ni system
  35. Thermodynamic assessment of the Ce–O system in solid state from 60 to 67 mol.% O
  36. Phase transformations of iron nitrides at low temperatures (< 700 K) – application of mechanical mixtures of powders of nitrides and iron
  37. Effect of organic self-assembled monolayers on the deposition and adhesion of hydroxyapatite coatings on titanium
  38. Reconstruction and structural transition at metal/diamond interfaces
  39. Applied
  40. Microstructure, hardness, and fracture toughness evolution of hot-pressed SiC/Si3N4 nano/micro composite after high-temperature treatment
  41. High-temperature plasticity of SiC sintered with Lu2O3-AlN additives
  42. Interaction of functionalised surfaces on silica with dissolved metal cations in aqueous solutions
  43. XRD and TEM study of NiO–LSGM reactivity
  44. Microstructure and dielectric properties of nanoscale oxide layers on sintered capacitor-grade niobium and V-doped niobium powder compacts
  45. Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}
  46. Aqueous solution deposition of indium hydroxide and indium oxide columnar type thin films
  47. Thermodynamic properties of B2-AlFeNi alloys: modelling of the B2-AlFe and B2-AlNi phases
  48. Regular Articles
  49. Kinetics of precipitate formation in (TixWyCrz)B2 solid solutions: influence of Cr concentration and Co impurities
  50. On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)
  51. Out-of-pile chemical compatibility of Pb–Bi eutectic alloy with Graphite
  52. Microstructural characterisation of a Co–Cr–Mo laser clad applied on railway wheels
  53. The Na–H system: from first-principles calculations to thermodynamic modeling
  54. Notifications
  55. Personal
  56. Conferences
https://doi.org/10.1515/ijmr-2006-0129
Keywords for this article
Al– Ni; Knudsen effusion mass spectrometry; Vaporisation; Thermodynamics

Articles in the same Issue

  1. Frontmatter
  2. Microstructure and mechanical behavior of Pt-modified NiAl diffusion coatings
  3. Evolution of C-rich SiOC ceramics
  4. Evolution of C-rich SiOC ceramics
  5. Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
  6. Thermodynamic analysis of structural transformations induced by annealing of amorphous Si–C–N ceramics derived from polymer precursors
  7. Thermodynamic modelling of the Ce–Ni system
  8. Thermodynamic assessment of the Ce–O system in solid state from 60 to 67 mol.% O
  9. Phase transformations of iron nitrides at low temperatures (< 700 K) – application of mechanical mixtures of powders of nitrides and iron
  10. Effect of organic self-assembled monolayers on the deposition and adhesion of hydroxyapatite coatings on titanium
  11. Reconstruction and structural transition at metal/diamond interfaces
  12. Microstructure, hardness, and fracture toughness evolution of hot-pressed SiC/Si3N4 nano/micro composite after high-temperature treatment
  13. High-temperature plasticity of SiC sintered with Lu2O3-AlN additives
  14. Interaction of functionalised surfaces on silica with dissolved metal cations in aqueous solutions
  15. XRD and TEM study of NiO–LSGM reactivity
  16. Microstructure and dielectric properties of nanoscale oxide layers on sintered capacitor-grade niobium and V-doped niobium powder compacts
  17. Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}
  18. Aqueous solution deposition of indium hydroxide and indium oxide columnar type thin films
  19. Thermodynamic properties of B2-AlFeNi alloys: modelling of the B2-AlFe and B2-AlNi phases
  20. Kinetics of precipitate formation in (TixWyCrz)B2 solid solutions: influence of Cr concentration and Co impurities
  21. On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)
  22. Out-of-pile chemical compatibility of Pb–Bi eutectic alloy with Graphite
  23. Microstructural characterisation of a Co–Cr–Mo laser clad applied on railway wheels
  24. The Na–H system: from first-principles calculations to thermodynamic modeling
  25. Personal
  26. Conferences
  27. Frontmatter
  28. Basic
  29. Microstructure and mechanical behavior of Pt-modified NiAl diffusion coatings
  30. Evolution of C-rich SiOC ceramics
  31. Evolution of C-rich SiOC ceramics
  32. Nanostructured SiC/BN/C ceramics derived from mixtures of B3N3H6 and [HSi(Me)C≡C]n
  33. Thermodynamic analysis of structural transformations induced by annealing of amorphous Si–C–N ceramics derived from polymer precursors
  34. Thermodynamic modelling of the Ce–Ni system
  35. Thermodynamic assessment of the Ce–O system in solid state from 60 to 67 mol.% O
  36. Phase transformations of iron nitrides at low temperatures (< 700 K) – application of mechanical mixtures of powders of nitrides and iron
  37. Effect of organic self-assembled monolayers on the deposition and adhesion of hydroxyapatite coatings on titanium
  38. Reconstruction and structural transition at metal/diamond interfaces
  39. Applied
  40. Microstructure, hardness, and fracture toughness evolution of hot-pressed SiC/Si3N4 nano/micro composite after high-temperature treatment
  41. High-temperature plasticity of SiC sintered with Lu2O3-AlN additives
  42. Interaction of functionalised surfaces on silica with dissolved metal cations in aqueous solutions
  43. XRD and TEM study of NiO–LSGM reactivity
  44. Microstructure and dielectric properties of nanoscale oxide layers on sintered capacitor-grade niobium and V-doped niobium powder compacts
  45. Knudsen effusion mass spectrometric studies of the Al–Ni system: Thermodynamic properties over {AlNi + Al3Ni2} and {Al3Ni2 + Al3Ni}
  46. Aqueous solution deposition of indium hydroxide and indium oxide columnar type thin films
  47. Thermodynamic properties of B2-AlFeNi alloys: modelling of the B2-AlFe and B2-AlNi phases
  48. Regular Articles
  49. Kinetics of precipitate formation in (TixWyCrz)B2 solid solutions: influence of Cr concentration and Co impurities
  50. On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)
  51. Out-of-pile chemical compatibility of Pb–Bi eutectic alloy with Graphite
  52. Microstructural characterisation of a Co–Cr–Mo laser clad applied on railway wheels
  53. The Na–H system: from first-principles calculations to thermodynamic modeling
  54. Notifications
  55. Personal
  56. Conferences
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