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Evaluation of promoted Ni-based nanocatalysts in wall-coated microchannel reactor on the dry reforming of methane and effect of ultrasound waves on physiochemical properties of synthesized nanocatalysts

  • Seied Reza Yahyavi and Gholamreza Moradi ORCID logo EMAIL logo
Published/Copyright: October 20, 2022
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International Journal of Chemical Reactor Engineering
From the journal International Journal of Chemical Reactor Engineering Volume 21 Issue 6

Abstract

The deactivation of nickel catalysts in the dry reforming of methane (DRM) process has been one of the issues of interest to researchers. In this research, the effect of active phase and support promoter uses and synthesis method on synthesized Ni–Co/Al2O3–MgO nanocatalysts efficiency in wall coated microreactor on dry reforming of methane process studied. To determine the characteristics of the synthesized samples, XRD, BET, FESEM, and Ft-IR analyses have been performed. Analyses show that the use of ultrasound waves in the synthesis of catalysts improves the catalyst surface morphology so that about 82% of the particles of the synthesized sample are smaller than 100 nm and , increases the specific surface area to an average of 10%, and makes its structure smaller. Also, the total pore volume on the surface of the samples also shows a 10% increase. The use of promoters increases the catalyst activity and makes it more stable up to 18 h on stream. The use of a wall-coated microreactor improves heat transfer, easier access of reactants to active sites, no pressure drop, and higher activity than a conventional U-type fixed bed reactor. Nanocatalysts with Ni/Co = 5 and Al/Mg = 5 has shown the highest and most stable activity throughout the temperature range in the DRM process.

Keywords: hydrogen yield; microreactor; promoter; sonochemical; stability
Corresponding author: Gholamreza Moradi, Petroleum Engineering, Catalyst Research Center, Faculty of Chemical and Petroleum Engineering, Razi University, Tagh Boston, Kermanshah 6714414971, Iran, E-mail:

Funding source: Razi University

Award Identifier / Grant number: Unassigned

Acknowledgments

The authors gratefully acknowledge Razi University for the financial support of the research and the provision of laboratory equipment.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-06-26
Accepted: 2022-10-08
Published Online: 2022-10-20

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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  2. Articles
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  4. Quantification of motion characteristics of vertically ascending bubbles in NaCl solution via image processing
  5. Particle crystallization by supercritical antisolvent processing techniques: the case of Retama raetam powder for pharmaceutical purposes
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  9. Evaluation of promoted Ni-based nanocatalysts in wall-coated microchannel reactor on the dry reforming of methane and effect of ultrasound waves on physiochemical properties of synthesized nanocatalysts
  10. Reaction engineering of continuous crystallization of β-ammonium tetramolybdate in concentric structure reactor and its application
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https://doi.org/10.1515/ijcre-2022-0133
Keywords for this article
hydrogen yield; microreactor; promoter; sonochemical; stability

Articles in the same Issue

  1. Frontmatter
  2. Articles
  3. Design and parametric optimization of a fan-notched baffle structure mixer for enhancement of liquid-liquid two-phase chemical process
  4. Quantification of motion characteristics of vertically ascending bubbles in NaCl solution via image processing
  5. Particle crystallization by supercritical antisolvent processing techniques: the case of Retama raetam powder for pharmaceutical purposes
  6. Evaluation the performance of the tin (IV) oxide (SnO2) in the removal of sulfur compounds via oxidative-extractive desulfurization process for production an eco-friendly fuel
  7. Experimental and kinetic studies of biogas production from petroleum oily sludge by anaerobic co-digestion with animals’ dung at thermophilic conditions
  8. A study on the adsorption property and mechanism of β-cyclodextrin/polyvinyl alcohol/polyacrylic acid hydrogel for ciprofloxacin
  9. Evaluation of promoted Ni-based nanocatalysts in wall-coated microchannel reactor on the dry reforming of methane and effect of ultrasound waves on physiochemical properties of synthesized nanocatalysts
  10. Reaction engineering of continuous crystallization of β-ammonium tetramolybdate in concentric structure reactor and its application
  11. Bio-lubricant production based on epoxidized oleic acid derived dated palm oil using in situ peracid mechanism
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