Startseite Preparation and characterization of tannin-based adhesives reinforced with cellulose nanofibrils for wood bonding
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Preparation and characterization of tannin-based adhesives reinforced with cellulose nanofibrils for wood bonding

  • Uasmim Lira Zidanes ORCID logo EMAIL logo , Matheus Cordazzo Dias , Mário Sérgio Lorenço , Elesandra da Silva Araujo , Maryella Júnnia Ferreira e Silva , Thaís Brito Sousa , Saulo Rocha Ferreira , Júlio César Ugucioni , Gustavo Henrique Denzin Tonoli , Maria Lucia Bianchi und Fábio Akira Mori
Veröffentlicht/Copyright: 3. August 2020
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Abstract

Adhesives based on vegetable tannins are already a reality in the market. However, their use is still limited due to their low mechanical resistance and weak humidity resistance. Cellulose nanofibrils (CNFs) are being used as reinforcing materials in various composites, resulting in an improvement of mechanical proprieties in general. The objective of this work was to evaluate the incorporation of CNFs in adhesives made of tannins obtained from the Angico tree (Anadenanthera peregrine). Concentrations of nanofibrils at 1, 5, and 10% were added to the adhesives on a dry basis. Tests of viscosity, pH, solids content, and gel time were performed to determine the physical proprieties of the adhesives. The Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Raman spectra measurements were also determined to understand the interaction between tannins and CNFs. Thermogravimetric analyses (TGA) were carried out to determine the thermal resistance of the composite. The FTIR and Raman characterization identified some differences in the peaks in the chemical composition of the adhesives with different percentages of CNFs. The adhesives showed no different decomposition in the thermogravimetric analyses. The shear strength in the glue line of the adhesive with 5% of CNFs in Toona ciliata woods was determined. Among all the adhesives analyzed, the one with 5% of CNFs produced an improvement in the mechanical resistance and humidity resistance on the glue line.

Keywords: Anadenanthera peregrina; FTIR; nanostructured adhesive; natural adhesive; Raman
Corresponding author: Uasmim Lira Zidanes, Department of Forest Science, Federal University of Lavras, PO Box 3037, 372000-000, Lavras, MG, Brazil, E-mail:

Funding source: FINEP

Funding source: FAPEMIG

Award Identifier / Grant number: TEC-AUC-00026-16

Funding source: CNPq

Funding source: CAPES

Award Identifier / Grant number: 001

Acknowledgments

The authors would like to thank the Centre of Analysis and Chemical Prospecting of the Federal University of Lavras for technical support involving all analyses.

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding:We would like to thank FINEP, FAPEMIG (grant # TEC-AUC-00026-16), CNPq and CAPES (Finance Code 001) for supplying the equipment and financial support.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/hf-2020-0033).

Received: 2020-01-30
Accepted: 2020-05-05
Published Online: 2020-08-03
Published in Print: 2021-02-23

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Original articles
  3. Inheritance of static bending properties and classification of load-deflection curves in Cryptomeria japonica
  4. Hardness of chemically densified Yellow birch in relation to wood density, polymer content and polymer properties
  5. Comparison of silicate impregnation methods to reinforce Chinese fir wood
  6. Hydrophobic and UV-resistant properties of environmentally friendly nano-ZnO-coated wood
  7. A novel approach to determine charring of wood in natural fire implemented in a coupled heat-mass-pyrolysis model
  8. Preparation and characterization of tannin-based adhesives reinforced with cellulose nanofibrils for wood bonding
  9. Intraspecific variability of quantity and chemical composition of ethanolic knotwood extracts along the stems of three industrially important softwood species: Abies alba, Picea abies and Pseudotsuga menziesii
  10. Creation and structural evaluation of the three-dimensional cellulosic material “White-Colored Bamboo”
  11. The furfuryl alcohol (FA) resin distribution in the furfurylated bamboo
  12. Short note
  13. Use of LA-ICP-MS for determination of elemental concentrations of boron in preservative treated solid wood and engineered wood panels
https://doi.org/10.1515/hf-2020-0033
Schlagwörter für diesen Artikel
Anadenanthera peregrina; FTIR; nanostructured adhesive; natural adhesive; Raman

Artikel in diesem Heft

  1. Frontmatter
  2. Original articles
  3. Inheritance of static bending properties and classification of load-deflection curves in Cryptomeria japonica
  4. Hardness of chemically densified Yellow birch in relation to wood density, polymer content and polymer properties
  5. Comparison of silicate impregnation methods to reinforce Chinese fir wood
  6. Hydrophobic and UV-resistant properties of environmentally friendly nano-ZnO-coated wood
  7. A novel approach to determine charring of wood in natural fire implemented in a coupled heat-mass-pyrolysis model
  8. Preparation and characterization of tannin-based adhesives reinforced with cellulose nanofibrils for wood bonding
  9. Intraspecific variability of quantity and chemical composition of ethanolic knotwood extracts along the stems of three industrially important softwood species: Abies alba, Picea abies and Pseudotsuga menziesii
  10. Creation and structural evaluation of the three-dimensional cellulosic material “White-Colored Bamboo”
  11. The furfuryl alcohol (FA) resin distribution in the furfurylated bamboo
  12. Short note
  13. Use of LA-ICP-MS for determination of elemental concentrations of boron in preservative treated solid wood and engineered wood panels
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