Startseite A study of the physico-chemical properties of dried maritime pine resin to better understand the exudation process
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

A study of the physico-chemical properties of dried maritime pine resin to better understand the exudation process

  • Thomas Cabaret EMAIL logo , Nesrine Harfouche , Léo Leroyer , Jean-Bernard Ledeuil , Hervé Martinez und Bertrand Charrier
Veröffentlicht/Copyright: 18. Juli 2019
Veröffentlichen auch Sie bei De Gruyter Brill

Abstract

The aim of this study was to have a better understanding of the phenomenon of resin exudation on pinewood boards due to the liquefaction of the resin caused by the heat of solar radiation. Resin exudation is a crucial problem for the maritime pine industry, as it may strongly decrease the wood’s aesthetics submitted to outdoor exposure. The softening temperature of dried pine resin was analyzed and the results were examined relative to its physico-chemical properties. To achieve this, resin samples were dried under different conditions (60°C, 120°C during 16 h and at 150°C during 24 h). After 3 months of post-drying at ambient temperature, their softening temperatures were measured by thermomechanical analysis. These same samples were subsequently studied to determine their chemical, structural and morphological properties. Samples with a low drying temperature (60°C) had high opacity attributed to crystallinity and porosity. These elements partially explained a higher softening temperature than for the other samples. Different chemical modifications of resin were also observed due to temperature, with a significant amount of oxidized derivatives for samples dried at low temperature and dehydrogenated compounds for samples dried at high temperature.

Acknowledgments

The text was proofread by Anne-Marie Pollaud-Duliand and Jean-François Delannoy.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: We gratefully acknowledge the financial support from the Nouvelle Aquitaine region and the Landes departmental council. This work was also funded by ANR-10-EQPX-16 XYLOFOREST (Mont-de-Marsan). We also gratefully acknowledge the support from our partners: Bardage Bois Neoclin, FCBA, FPbois, Gascogne Bois, Lesbats Scieries d’Aquitaine, Scierie Labadie, and Holiste.

  3. Employment or leadership: None declared.

  4. Honorarium: None declared.

References

Arrieta, M.P., Samper, M.D., Jiménez-López, M., Aldas, M., López, J. (2017) Combined effect of linseed oil and gum rosin as natural additives for PVC. Ind. Crops Prod. 99:196–204.10.1016/j.indcrop.2017.02.009Suche in Google Scholar

Artaki, I., Ray, U., Gordon, H.M., Gervasio, M.S. (1992) Thermal degradation of rosin during high temperature solder reflow. Thermochim. Acta 198:7–20.10.1016/0040-6031(92)85053-XSuche in Google Scholar

Azémard, C., Vieillescazes, C., Ménager, M. (2014) Effect of photodegradation on the identification of natural varnishes by FT-IR spectroscopy. Microchem. J. 112:137–149.10.1016/j.microc.2013.09.020Suche in Google Scholar

Baldwin, D.E., Loeblich, V.M., Lawrence, R.V. (1958) Acidic composition of oleoresins and rosins. Ind. Eng. Chem. 3:342–346.10.1021/i460004a036Suche in Google Scholar

Behtash, O., Nasrollahi, S.A., Nafisi, S. (2018) Design, synthesis of novel vesicular systems using turpentine as a skin permeation enhancer. J. Drug Deliv. Sci. Technol. 43:327–332.10.1016/j.jddst.2017.10.015Suche in Google Scholar

Blanche, C.A., Lorio, P.L., Sommers, R.A., Hodges, J.D., Nebeker, T.E. (1992) Seasonal cambial growth and development of loblolly pine: xylem formation, inner bark chemistry, resin ducts, and resin flow. For. Ecol. Manag. 49:151–165.10.1016/0378-1127(92)90167-8Suche in Google Scholar

Cabaret, T., Boulicaud, B., Chatet, E., Charrier, B. (2018) Study of rosin softening point through thermal treatment for a better understanding of maritime pine exudation. Eur. J. Wood Wood Prod. 76:1453–1459.10.1007/s00107-018-1339-3Suche in Google Scholar

Cabaret, T., Gardere, Y., Frances, M., Leroyer, L., Charrier, B. (2019) Measuring interactions between rosin and turpentine during the drying process for a better understanding of exudation in maritime pine wood used as outdoor siding. Ind. Crops Prod. 130:325–331.10.1016/j.indcrop.2018.12.080Suche in Google Scholar

Cannac, M., Barboni, T., Ferrat, L., Bighelli, A., Castola, V., Costa, J., Trecul, D., Morandini, F., Pasqualini, V. (2009) Oleoresin flow and chemical composition of Corsican pine (Pinus nigra subsp. laricio) in response to prescribed burnings. For. Ecol. Manag. 257:1247–1254.10.1016/j.foreco.2008.11.017Suche in Google Scholar

Chen, G.-F. (1992) Developments in the field of rosin chemistry and its implications in coatings. Prog. Org. Coat. 20:139–167.10.1016/0033-0655(92)80002-ESuche in Google Scholar

Cheniclet, C. (1987) Effects of wounding and fungus inoculation on terpene producing systems of maritime pine. J. Exp. Bot. 38:1557–1572.10.1093/jxb/38.9.1557Suche in Google Scholar

Coppen, J.J.W., Hone, G.A. (1995) Gum naval stores: turpentine and rosin from pine resin. Non-wood forest products. 2:71pp.Suche in Google Scholar

Croteau, R., Gurkewitz, S., Johnson, M.A., Fisk, H.J. (1987) Biochemistry of oleoresinosis. Monoterpene and diterpene biosynthesis in lodgepole pine saplings infected with Ceratocystis clavigera or treated with carbohydrate elicitors. Plant Physiol. 85:1123–1128.10.1104/pp.85.4.1123Suche in Google Scholar PubMed PubMed Central

Dubey, P., Gupta, R. (2018) Influences of dual bio-fuel (Jatropha biodiesel and turpentine oil) on single cylinder variable compression ratio diesel engine. Renew. Energ. 115:1294–1302.10.1016/j.renene.2017.09.055Suche in Google Scholar

Echard, J.-P., Bertrand, L., von Bohlen, A., Le Hô, A.-S., Paris, C., Bellot-Gurlet, L., Soulier, B., Lattuati-Derieux, A., Thao, S., Robinet, L., Lavédrine, B., Vaiedelich, S. (2010) The nature of the extraordinary finish of Stradivari’s instruments. Angew. Chem. Int. Ed. 49:197–201.10.1002/anie.200905131Suche in Google Scholar PubMed

Franceschi, V.R., Krokene, P., Christiansen, E., Krekling, T. (2005) Anatomical and chemical defenses of conifer bark against bark beetles and other pests. New Phytol. 167:353–376.10.1111/j.1469-8137.2005.01436.xSuche in Google Scholar PubMed

Gaillard, Y., Mija, A., Burr, A., Darque-Ceretti, E., Felder, E., Sbirrazzuoli, N. (2011) Green material composites from renewable resources: polymorphic transitions and phase diagram of beeswax/rosin resin. Thermochim. Acta 521:90–97.10.1016/j.tca.2011.04.010Suche in Google Scholar

Ghanmi, M., Satrani, B., Chaouch, A., Aafi, A., El Abib, A., Ismail, M.R., Farah, A. (2007) Composition chimique et activité antimicrobienne de l’essence de térébenthine du pin maritime (Pinus pinaster) et du pin d’Alep (Pinus hale-pensis) du Maroc [Chemical composition and antimicrobial activity of turpentine from moroccan (Pinus pinaster) maritime pine and aleppo pine (Pinus halepensis)]. Acta Bot. Gallica 145:293–300.10.1080/12538078.2007.10516058Suche in Google Scholar

Ghanmi, M., Satrani, B., Aafi, A., Ismail, M.R., Farah, A., Chaouch, A. (2009) Évaluation de la qualité de la colophane du pin maritime (Pinus pinaster) et du pin d’Alep (Pinus halepensis) du Maroc [Quality assessment of rosin from moroccan (Pinus pinaster) maritime pine and aleppo pine (Pinus halepensis)]. Acta Bot. Gallica 156:427–435.10.1080/12538078.2009.10516168Suche in Google Scholar

Hawley, L.F., Palmer, R.C. (1912) Distillation of resinous wood by saturated steam. J. Ind. Eng. Chem. 4:789–795.10.1021/ie50047a003Suche in Google Scholar

Hermans, P.H., Weidinger, A. (1948) Quantitative X-ray investigations on the crystallinity of cellulose fibers. A background analysis. J. Appl. Phys. 19:491–506.10.1063/1.1698162Suche in Google Scholar

Joye, N.M., Lawrence, R.V. (1967) Resin acid composition of pine oleoresins. J. Chem. Eng. Data 12:279–281.10.1021/je60033a034Suche in Google Scholar

Kersten, P.J., Kopper, B.J., Raffa, K. F., Illman, B.L. (2006) Rapid analysis of abietanes in conifers. J. Chem. Ecol. 32:2679–2685.10.1007/s10886-006-9191-zSuche in Google Scholar

Lee, C.-M., Lim, S., Kim, G.-Y., Kim, D., Kim, D.-W., Lee, H.-C., Lee, K.-Y. (2004) Rosin microparticles as drug carriers: influence of various solvents on the formation of particles and sustained-release of indomethacin. Biotechnol. Bioprocess Eng. 9:476–481.10.1007/BF02933489Suche in Google Scholar

Li, H., McDonald, A.G. (2014) Fractionation and characterization of industrial lignins. Ind. Crops Prod. 62:67–76.10.1016/j.indcrop.2014.08.013Suche in Google Scholar

Lloyd, W.D., Hedrick, G.W. (1965) Levopimaric acid. Org. Synth. 45:64.10.1002/0471264180.os045.20Suche in Google Scholar

Loeblich, V.M., Baldwin, D.E., O’Connor, R.T., Lawrence, R.V. (1955) Thermal isomerization of levopimaric acid. J. Am. Chem. Soc. 77:6311–6313.10.1021/ja01628a071Suche in Google Scholar

Luchi, N., Ma, R., Capretti, P., Bonello, P. (2005) Systemic induction of traumatic resin ducts and resin flow in Austrian pine by wounding and inoculation with Sphaeropsis sapinea and Diplodia scrobiculata. Planta 221:75–84.10.1007/s00425-004-1414-3Suche in Google Scholar

Maiti, S., Ray, S.S., Kundu, A.K. (1989) Rosin: a renewable resource for polymers and polymer chemicals. Prog. Polym. Sci. 14:297–338.10.1016/0079-6700(89)90005-1Suche in Google Scholar

Moreira, X., Sampedro, L., Zas, R. (2009) Defensive responses of Pinus pinaster seedlings to exogenous application of methyl jasmonate: Concentration effect and systemic response. Environ. Exp. Bot. 67:94–100.10.1016/j.envexpbot.2009.05.015Suche in Google Scholar

Moreira, F., Arianoutsou, M., Corona, P., De las Heras, J. Post-Fire Management and Restoration of Southern European Forests. Springer Netherlands, Dordrecht, 2012.10.1007/978-94-007-2208-8Suche in Google Scholar

Narayanan, M., Loganathan, S., Valapa, R.B., Thomas, S., Varghese, T.O. (2017) UV protective poly(lactic acid)/rosin films for sustainable packaging. Int. J. Biol. Macromol. 99:37–45.10.1016/j.ijbiomac.2017.01.152Suche in Google Scholar

Pastorova, I., Van der Berg, K.J., Boon, J.J., Verhoeven, J.W. (1997) Analysis of oxidised diterpenoid acids using thermally assisted methylation with TMAH. J. Anal. Appl. Pyrolysis 43:41–57.10.1016/S0165-2370(97)00058-2Suche in Google Scholar

Penaranda Moren, M.S., Korjenic, A. (2017) Hotter and colder – how do photovoltaics and greening impact exterior facade temperatures: the synergies of a multifunctional system. Energ. Build. 147:123–141.10.1016/j.enbuild.2017.04.082Suche in Google Scholar

Rani, M., Govindarajan, R., Surana, R., Suryanarayanan, R. (2006) Structure in dehydrated trehalose dihydrate – evaluation of the concept of partial crystallinity. Pharm. Res. 23:2356–2367.10.1007/s11095-006-9058-6Suche in Google Scholar

Ren, F., Zheng, Y.-F., Liu, X.-M., Yang, Q.-Q., Zhang, Q., Shen, F. (2015a) Thermal oxidation reaction process and oxidation kinetics of abietic acid. RSC Adv. 5:17123–17130.10.1039/C4RA16791KSuche in Google Scholar

Ren, F., Zheng, Y.-F., Liu, X.-M., Yue, X.-Y., Ma, L., Li, W.-G., Lai, F., Liu, J.-L., Guan, W.-L. (2015b) An investigation of the oxidation mechanism of abietic acid using two-dimensional infrared correlation spectroscopy. J. Mol. Struct. 1084:236–243.10.1016/j.molstruc.2014.12.055Suche in Google Scholar

Ruel, J.J., Ayres, M.P., Lorio, P.L. (1998) Loblolly pine responds to mechanical wounding with increased resin flow. Can. J. For. Res. 28:596–602.10.1139/x98-030Suche in Google Scholar

Scalarone, D., Lazzari, M., Chiantore, O. (2002) Ageing behaviour and pyrolytic characterisation of diterpenic resins used as art materials: colophony and Venice turpentine. J. Anal. Appl. Pyrolysis 64:345–361.10.1016/S0165-2370(02)00046-3Suche in Google Scholar

Takeda, H., Kanno, H., Schuller, W.H., Laurence, R.V. (1968) Effect of temperature on various rosins and pine gum. Ind. Eng. Chem. Prod. Res. Dev. 7:186–189.10.1021/i360027a006Suche in Google Scholar

Tirat, S., Degano, I., Echard, J.-P., Lattuati-Derieux, A., Lluveras- Tenorio, A., Marie, A., Serfaty, S., Le Huerou, J.-Y. (2016) Historical linseed oil/colophony varnishes formulations: study of their molecular composition with micro-chemical chromatographic techniques. Microchem. J. 126:200–213.10.1016/j.microc.2015.11.045Suche in Google Scholar

Ulukanli, Z., Karabörklü, S., Bozok, F., Ates, B., Erdogan, S., Cenet, M., Karaaslan, M.G. (2014) Chemical composition, antimicrobial, insecticidal, phytotoxic and antioxidant activities of Mediterranean Pinus brutia and Pinus pinea resin essential oils. Chin. J. Nat. Med. 12:0901–0910.10.1016/S1875-5364(14)60133-3Suche in Google Scholar

Wiyono, B., Tachibana, S., Tinambunal, D. (2006) Chemical compositions of pine resin, rosin and turpentine oil from west java. J. For. Res. 3:7–17.10.20886/ijfr.2006.3.1.7-17Suche in Google Scholar

Yoshihara, A., Maeda, T., Imai, Y. (2009) Spectroscopic characterization of ambers and amber-like materials. Vib. Spectrosc. 50:250–256.10.1016/j.vibspec.2009.01.003Suche in Google Scholar

Received: 2018-11-13
Accepted: 2019-06-14
Published Online: 2019-07-18
Published in Print: 2019-11-26

©2019 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 2.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/hf-2018-0264/pdf
Button zum nach oben scrollen