Abstract
The possibility of precipitating high molecular weight (MW) softwood hemicelluloses has been investigated. Solids were precipitated from a sodium-based spent sulfite liquor with the anti-solvents acetone, ethanol and methanol and the effects of solute concentration, pH and temperature on the precipitation were studied. The product yield, degree of separation, MW and structure of the different fractions were determined using gravimetric analysis, high performance liquid chromatography (HPLC), ultraviolet–visible (UV-Vis) spectroscopy, size exclusion chromatography (SEC), and two-dimensional nuclear magnetic resonance (2D NMR). A direct correlation was found between the dielectric constant (also called relative permittivity) of the bulk solution and the yield of precipitants, based on which the separation of the solutes was predictable. The highest yield and degree of separation observed was an intercept around 76% with 47.5% acetone, which was the most efficient anti-solvent.
Acknowledgments
This research was funded by the Swedish Foundation for Strategic Research (SSF), which is gratefully acknowledged. Many thanks to Domsjö Fabriker (Sweden) for their support and for providing us with the raw material used in this research. Thanks to Dr. Göran Carlström for the help with the NMR analysis.
Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: The research was funded by the Swedish Foundation for Strategic Research (SSF).
Employment or leadership: None declared.
Honorarium: None declared.
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©2018 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Original Articles
- Increasing pulp yield in kraft cooking of softwoods by high initial effective alkali concentration (HIEAC) during impregnation leading to decreasing secondary peeling of cellulose
- Effects of wet-pressing induced fiber hornification on hydrogen bonds of cellulose and on properties of eucalyptus paper sheets
- Antisolvent precipitation of hemicelluloses, lignosulfonates and their complexes from ultrafiltrated spent sulfite liquor (SSL)
- Simultaneous pyrolysis and trimethylsilylation with N-methyl-(trimethylsilyl) trifluoroacetamide for the characterisation of lignocellulosic materials from kraft pulping
- Hygro-mechanical analysis of wood subjected to constant mechanical load and varying relative humidity
- In-situ density estimation by four nondestructive techniques on Norway spruce from built-in wood structures
- Formability of wood veneers: a parametric approach for understanding some manufacturing issues
- Influence of grain direction on the time-dependent behavior of wood analyzed by a 3D rheological model. A mathematical consideration
- Isolation of secondary metabolites from Stenochlaena palustris stems and structure-activity relationships of 20-hydroxyecdysone derivatives on antitermite activity
- Effects of white rot and brown rot decay on the drilling resistance measurements in wood
Articles in the same Issue
- Frontmatter
- Original Articles
- Increasing pulp yield in kraft cooking of softwoods by high initial effective alkali concentration (HIEAC) during impregnation leading to decreasing secondary peeling of cellulose
- Effects of wet-pressing induced fiber hornification on hydrogen bonds of cellulose and on properties of eucalyptus paper sheets
- Antisolvent precipitation of hemicelluloses, lignosulfonates and their complexes from ultrafiltrated spent sulfite liquor (SSL)
- Simultaneous pyrolysis and trimethylsilylation with N-methyl-(trimethylsilyl) trifluoroacetamide for the characterisation of lignocellulosic materials from kraft pulping
- Hygro-mechanical analysis of wood subjected to constant mechanical load and varying relative humidity
- In-situ density estimation by four nondestructive techniques on Norway spruce from built-in wood structures
- Formability of wood veneers: a parametric approach for understanding some manufacturing issues
- Influence of grain direction on the time-dependent behavior of wood analyzed by a 3D rheological model. A mathematical consideration
- Isolation of secondary metabolites from Stenochlaena palustris stems and structure-activity relationships of 20-hydroxyecdysone derivatives on antitermite activity
- Effects of white rot and brown rot decay on the drilling resistance measurements in wood