Comparative evaluation of various lignin determination methods on hemicellulose-rich fractions of spruce and birch obtained by pressurized hot-water extraction (PHWE) and subsequent ultrafiltration (UF)
-
Risto Korpinen
, Mari Kallioinen
, Jarl Hemming , Andrey Pranovich , Mika Mänttäri and Stefan Willför
Abstract
Various lignin determination methods have been applied to hemicellulose-rich wood extracts obtained after pressurized hot-water extraction (PHWE) and membrane ultrafiltration (UF). In focus were the chlorine number (Cl no.) method, the acetyl bromide method, and the four modifications of the Klason lignin determination, such as the KCL, TAPPI, LAP, and Goldschmid methods. The furfural (F) and hydroxymethylfurfural (HMF) concentrations in the acid hydrolysates were also determined. The mass balances of the fraction were calculated with respect to the contents of dry solids and lignin, including the acid-soluble lignin. The reliability of the methods was evaluated based on the lignin mass balances and the gross chemical composition of the extracts. Although the results were dependent on the method applied, the lignin mass balance calculations yielded similar results in general.
Acknowledgments
This research was part of the activities at the Åbo Akademi Process Chemistry Centre. This study was financed by the Finnish Bioeconomy Cluster (FIBIC) and the Finnish Funding Agency for Innovation (Tekes) within the framework of the Future Biorefinery (FuBio) Joint Research 2 program. The Finnish Forest Research Institute is acknowledged for performing the PHWE and the Lappeenranta University of Technology, Laboratory of Separation Technology, is acknowledged for performing the UF experiments.
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©2014 by De Gruyter
Articles in the same Issue
- Frontmatter
- Original Articles
- Influence of cellulose supramolecular structure on strength properties of chemical pulp
- Morphological, mechanical, and optical properties of cypress papers
- Determination of ion exchange constants for pairs of metal ions to lignocellulosic materials by column chromatography
- Combustion behavior of oak wood (Quercus mongolica L.) modified by 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU)
- Synthesis and antifungal activity of camphoric acid-based acylhydrazone compounds
- Lignification of ray parenchyma cells in the xylem of Pinus densiflora. Part I: Microscopic investigation by POM, UV microscopy, and TOF-SIMS
- Lignification of ray parenchyma cells in the xylem of Pinus densiflora. Part II: Microchemical analysis by laser microdissection and thioacidolysis
- Distribution of lignin in vascular bundles of coconut wood (Cocos nucifera) by cellular UV-spectroscopy and relationship between lignification and tensile strength in single vascular bundles
- Compression properties of vascular boundles and parenchyma of rattan (Plectocomia assamica Griff)
- Properties of wood-plastic composites (WPCs) reinforced with extracted and delignified wood flour
- Anisotropic elastic properties of common ash (Fraxinus excelsior L.)
- Destructive and non-destructive evaluation of seven hardwoods and analysis of data correlation
- Experimental validation of green wood peeling assisted by IR heating – some considerations of the analytical system design
- The influence of felling season and log-soaking temperature on the wetting and phenol formaldehyde adhesive bonding characteristics of birch veneer
- Comparative evaluation of various lignin determination methods on hemicellulose-rich fractions of spruce and birch obtained by pressurized hot-water extraction (PHWE) and subsequent ultrafiltration (UF)
- Conversion between basic density and apparent density at any moisture content in Eucalyptus grandis
- Postpeak residual capacity of nailed connections of a shear wall
- Obituary
- Memorial on Horst H. Nimz (1930–2013)
Articles in the same Issue
- Frontmatter
- Original Articles
- Influence of cellulose supramolecular structure on strength properties of chemical pulp
- Morphological, mechanical, and optical properties of cypress papers
- Determination of ion exchange constants for pairs of metal ions to lignocellulosic materials by column chromatography
- Combustion behavior of oak wood (Quercus mongolica L.) modified by 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU)
- Synthesis and antifungal activity of camphoric acid-based acylhydrazone compounds
- Lignification of ray parenchyma cells in the xylem of Pinus densiflora. Part I: Microscopic investigation by POM, UV microscopy, and TOF-SIMS
- Lignification of ray parenchyma cells in the xylem of Pinus densiflora. Part II: Microchemical analysis by laser microdissection and thioacidolysis
- Distribution of lignin in vascular bundles of coconut wood (Cocos nucifera) by cellular UV-spectroscopy and relationship between lignification and tensile strength in single vascular bundles
- Compression properties of vascular boundles and parenchyma of rattan (Plectocomia assamica Griff)
- Properties of wood-plastic composites (WPCs) reinforced with extracted and delignified wood flour
- Anisotropic elastic properties of common ash (Fraxinus excelsior L.)
- Destructive and non-destructive evaluation of seven hardwoods and analysis of data correlation
- Experimental validation of green wood peeling assisted by IR heating – some considerations of the analytical system design
- The influence of felling season and log-soaking temperature on the wetting and phenol formaldehyde adhesive bonding characteristics of birch veneer
- Comparative evaluation of various lignin determination methods on hemicellulose-rich fractions of spruce and birch obtained by pressurized hot-water extraction (PHWE) and subsequent ultrafiltration (UF)
- Conversion between basic density and apparent density at any moisture content in Eucalyptus grandis
- Postpeak residual capacity of nailed connections of a shear wall
- Obituary
- Memorial on Horst H. Nimz (1930–2013)