Critical Evaluation of Equilibrium Constants of 4f Metal Mixed Complexes with Acidic (Chelating) Ligands in Combination with Various Organophosphorus O-donor Molecules
A critical evaluation survey of equilibrium constants concerning the complexation of 4f-ions by acidic (chelating) ligands in combination with organophosphorus O-donor molecules in various molecular or ionic diluents with particular regard to synergism will be done during the execution of a project under IUPAC auspices. Stability constants of metal complexes are extremely important for academic and industrial research and are widely used in analytical chemistry. The subject is of utmost importance, and this contribution has the potential for wide application (geology, material science, metallurgy, metal recycling, industrial wastewater treatment, handling of radioactive waste, etc.). Solvent extraction is a distinguished process for metal refining that stands at the frontier between organic synthesis, analytical, physical, coordination, and green chemistry and is the only industrial technology for lanthanoids separation. Therefore, developing a database review containing useful information of already applied synergistic systems will offer opportunities to the scientists of diversified fields in chemistry and chemical technology to make comparisons, draw conclusions, and choose better ideas when planning their next research investigations. In terms of the increase of safety, prevention of pollution, and improvement of extraction efficiency, the research, development, and implementation of innovative green chemical technologies is indispensable. The very limited set of data available today concerning metal behavior in ionic liquids raise the hope for greater extraction efficiencies accompanied with increased selectivity.
This project is part of a series titled “Critical evaluation of stability constants of metal complexes in solution”.
For further information, contact the Task Group Chair Maria A. Petrova <ma@uctm.edu>
©2016 by Walter de Gruyter Berlin/Boston
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- Names and Symbols of the Elements With Atomic Numbers 113, 115, 117, and 118
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- ChemCYS 2016. An Inspiring and Stimulating Conference for Young Chemists Worldwide
- Photochemistry
- Research and Education in the Middle East
- Gender Issues in Field Research
- Mark Your Calendar
Articles in the same Issue
- Masthead - Full issue pdf
- Contents
- Features
- The Art of Building Small
- Chemistry for the Future Solvay Prize
- CAMEO: The Science in Art
- Colorimetric Sensor
- The Discovery of Phytochrome
- Stamps International
- Raman’s Gift to the Art World
- IUPAC Wire
- Kicking off the Preparations for the IUPAC Centenary
- IUPAC Elections for the 2018–2019 Term
- IUPAC Announces the Winners of the 2016 IUPAC-Solvay International Award for Young Chemists
- Volker Hessel Is Awarded the 2016 IUPAC ThalesNano Prize for Flow Chemistry
- Dan Kunkel to Receive the IUPAC International Award for Advances in Crop Protection Chemistry
- Ali Maleki Is Awarded the 2016 IUPAC-CHEMRAWN VII Prize for Green Chemistry
- 2016 Andrei Sakharov Prize Awarded to Zafra Lerman
- In Memoriam—Paul De Bièvre
- Project Place
- Guide (and Brief Guide) to Polymer Semiconductors
- Critical Evaluation of Equilibrium Constants of 4f Metal Mixed Complexes with Acidic (Chelating) Ligands in Combination with Various Organophosphorus O-donor Molecules
- Network for Heterocyclic Chemistry among Countries of the Mediterranean Sea Area, Including Europe and North Africa
- Nomenclature for Properties and Units or NPU Terminology
- Making an imPACt
- Human Errors in a Routine Analytical Laboratory—Classification, Modeling and Quantification: Overview of the IUPAC/CITAC Guide*
- IUPAC Provisional Recommendations
- Names and Symbols of the Elements With Atomic Numbers 113, 115, 117, and 118
- Preferred Names of Constitutional Units for Use in Structure-based Names of Polymers
- Conference Call
- Ecological Risk Assessment Workshop
- ChemCYS 2016. An Inspiring and Stimulating Conference for Young Chemists Worldwide
- Photochemistry
- Research and Education in the Middle East
- Gender Issues in Field Research
- Mark Your Calendar
