Mechanism of decomposition of peracetic acid by manganese ions and diethylenetriaminepentaacetic acid (DTPA)
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Evgeny Popov
Abstract
The decomposition mechanism of peracetic acid by free Mn2+ ions and by Mn2+-diethylenetriaminepentaacetic acid complexes was studied by UV/Vis, electrospray ionization-time of flight-mass spectrometry (ESI-TOF-MS), electron spin resonance (ESR), and Raman spectroscopy. The experimental results demonstrate that a number of different oxidation states of manganese are involved in the decomposition reaction. Furthermore, the kinetics observed show oscillatory features that are characteristic of autocatalytic processes. Radical pathways were found to play a negligible role in the reaction. Based on the experimental observations, an overall reaction scheme for the decomposition process is proposed.
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Articles in the same Issue
- The prediction of pulp yield using selected fiber properties
- Surface lignin and extractives on hardwood RDH kraft pulp chemically characterized by ToF-SIMS
- NMR studies on Fraser fir Abies fraseri (Pursh) Poir. lignins
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- Mechanism of decomposition of peracetic acid by manganese ions and diethylenetriaminepentaacetic acid (DTPA)
- The effect of chlorophorin and its derivative on melanin biosynthesis
- Long-term development of VOC emissions from OSB after hot-pressing
- Assessment of continuous distribution of wood properties from a low number of samples: Application to the variability of modulus of elasticity between trees and within a tree
- Earlywood and latewood elastic properties in loblolly pine
- Combined shear and compression analysis using a modified Iosipescu shear test device. Experimental studies on dry wood
- An approach to viscoelastic behaviour analysis of wood-based panels by an inverse method of characterisation
- The mechanosorptive effect in Pinus radiata D. Don.
- Advances in understanding bioactivity of chitosan and chitosan oligomers against selected wood-inhabiting fungi
- Comparison of quantitative real-time PCR, chitin and ergosterol assays for monitoring colonization of Trametes versicolor in birch wood
- Rate and extent of adsorption of ACQ preservative components in wood
- Prediction of long-term leaching potential of preservative-treated wood by diffusion modeling
