Erythro/threo ratio of β-O-4-5 structures as an important structural characteristic of lignin. Part 4: Variation in the erythro/threo ratio in softwood and hardwood lignins and its relation to syringyl/guaiacyl ratio
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Takuya Akiyama
, Hitoshi Goto , Deded S. Nawawi , Wasrin Syafii , Yuji Matsumoto and Gyosuke Meshitsuka
Abstract
The proportion of erythro- and threo-forms of β-O-4-structures in lignin was elucidated by ozonation analysis of 21 wood species, and the relationship to the syringyl and guaiacyl composition was investigated. For all hardwood species, the erythro-form of β-O-4-structures predominated, although the extent varied widely, depending on wood species. In contrast, the proportion and amount of erythro- and threo-forms were very similar in all softwood species. The proportion of the erythro-form was greater in species with a higher methoxyl content in the lignin (correlation coefficient, R2=0.83). The S/V ratio (molar ratio of syringaldehyde and syringic acid to that of vanillin and vanillic acid) obtained by nitrobenzene oxidation was also strongly correlated with the proportion of the erythro-form (R2=0.99). Accordingly, the syringyl/guaiacyl ratio is closely related to the erythro/threo ratio. This stereochemical characteristic of β-O-4-structures is discussed in relation to the process of lignin formation.
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Articles in the same Issue
- Molecular dynamics study of lignin constituents in water
- Oxidative cellulose degradation by cellobiose dehydrogenase from Phanerochaete chrysosporium: A model compound study
- Characterization of active oxygen species under oxygen-alkali bleaching conditions
- Erythro/threo ratio of β-O-4-5 structures as an important structural characteristic of lignin. Part 4: Variation in the erythro/threo ratio in softwood and hardwood lignins and its relation to syringyl/guaiacyl ratio
- Stereoisomers of 3,3′-dimethoxy-4,4′-stilbenequinone
- Liquefaction of CCA-treated wood and elimination of metals from the solvent by precipitation
- Condensed tannins from steamed Acacia mearnsii bark
- Chemical composition and antifungal activity of essential oil isolated from Chamaecyparis formosensis Matsum. wood
- Direct measurement of strain distribution along a wood bond line. Part 1: Shear strain concentration in a lap joint specimen by means of electronic speckle pattern interferometry
- Direct measurement of strain distribution along a wood bond line. Part 2: Effects of adhesive penetration on strain distribution
- Rate-independent mechanical behavior of biaxially stressed wood: Experimental observations and constitutive modeling as an orthotropic two-surface elasto-plastic material
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- New insights into wood and cement interaction
- Wood-water sorption isotherm prediction with artificial neural networks: A preliminary study
- Hygroscopicity of resorcinol-formaldehyde resin and aqueous vinyl polymer-isocyanate resin in high humidity
- Modelling anisotropic maturation strains in wood in relation to fibre boundary conditions, microstructure and maturation kinetics
- Properties of chemically and mechanically isolated fibres of spruce (Picea abies [L.] Karst.). Part 3: Mechanical characterisation
- Resistance of thermo-hygro-mechanically densified wood to colonisation and degradation by brown-rot fungi
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