Chlorinated Phenolic Compounds in Bleaching Filtrates from a Mixed Eucalyptus and Acacia Pulp Using Different Sequences
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João L. F. Furtado
Summary
Bench filtrates from three-stage conventional bleaching sequences (CEoD) with substitution degrees of chlorine by chlorine dioxide in the first stage equals to zero, 25%, 75% and 100% have been analysed for their content of chlorinated phenolic compounds (CPCs). Alternatively, CPCs filtrates content of an AZEoPD sequence were also determined. A cellulose pulp obtained from a mixture of 85% Eucalyptus saligna (young trees) and 15% Acacia mearnsii delignified with oxygen (kappa number 10.0) was employed in all bleaching tests. Levels of CPCs were determined by using an in situ acetylation method followed by GC/ECD technique. GC/MS of bleaching filtrates was employed in qualitative analyses. CPCs content in filtrates and the Kovacs' equivalent toxicity for the total filtrates of the studied bleaching sequences are presented. The lowest content of CPCs was found in AZEoPD filtrates, as expected due to the utilised bleaching agents. CPCs were not detected in the filtrates of stage D from the AZEoPD sequence probably due to the low lignin content of the pulp. Mixed filtrates of the sequence DEoD, showed the lowest CPCs content among conventional bleachings. Results are in accordance with those found in the literature for hardwood and softwood pulp. The equivalent toxicity in the sequences Dc(75/25), DEoD and AZEoPD was found to be lower than the limit given by Kovacs to characterise chronical toxicity.
Copyright © 2000 by Walter de Gruyter GmbH & Co. KG
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Articles in the same Issue
- Modelling the Moisture Induced Risk of Decay for Treated and Untreated Wood Above Ground
- FTIR Characterization of Copper Ethanolamine—Wood Interaction for Wood Preservation
- Glycerol/Glyoxal: A New Boron Fixation System for Wood Preservation and Dimensional Stabilization
- Removal of Phenolic Hydroxyl Groups in Lignin Model Compounds and Its Effect on Photostability
- Cation Exchange Capacity Tests on Some Lignocellulosic Materials Highlight Some Aspects of the Use of Copper as Wood Preservative
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- A Comparative Study on Reactions of Hydrogen Peroxide and Peracetic Acid with Lignin Chromophores. Part 1. The Reaction of Coniferaldehyde Model Compounds
- A Comparative Study on Reactions of Hydrogen Peroxide and Peracetic Acid with Lignin Chromophores. Part 2. The Reaction of Stilbene-Type Model Compounds
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- Kinetic Studies on Oxidation of Veratryl Alcohol by Laccase-Mediator System. Part 1. Effects of Mediator Concentration
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- Study of the System Wood – Coating Material. I. Wood – Liquid Coating Material
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- A New Air Dehydration Process for Wood Dryers. Part I. Kinetic and Quality of Drying
- A New Air Dehydration Process for Wood Dryers. Part II. Elimination of Organic Compounds
- A New Method of Sample Preparation for Kenaf Bast Fiber Length Analysis with Automated Fiber Length Analyzer
- Literature Reports
