17. Bergman Cyclization

Chapters in this book

1. Frontmatter I
2. Preface and Overview VII
3. Contents 1
4. List of Acronyms and Abbreviations 6
5. 1. Electrophilic Addition Mechanism 10
6. 2. Nucleophilic Substitution Mechanism 12
7. 3. Aromatic Electrophilic Substitution Mechanism 14
8. 4. Aromatic Nucleophilic Substitution Mechanism 16
9. 5. Aromatic Radical Nucleophilic Substitution Mechanism 18
10. 6. Elimination Mechanism 22
11. 7. Acyloin Condensation 26
12. 8. Alkyne Zipper Reaction 28
13. 9. Arbuzov Reaction 30
14. 10. Arndt‒Eistert Synthesis 32
15. 11. Baeyer‒Villiger Oxidation 34
16. 12. Barton Decarboxylation 36
17. 13. Baylis‒Hillman Reaction 38
18. 14. Beckmann Rearrangement 40
19. 15. Benzoin Condensation 42
20. 16. Benzyne Mechanism 44
21. 17. Bergman Cyclization 46
22. 18. Birch Reduction 48
23. 19. Bischler‒Napieralski Cyclization 50
24. 20. Brown Hydroboration 52
25. 21. Buchwald‒Hartwig Cross Coupling 54
26. 22. Cannizzaro Reaction 56
27. 23. Chan‒Evans‒Lam Cross Coupling 58
28. 24. Chichibabin Amination 60
29. 25. Claisen Condensation 62
30. 26. Claisen Rearrangement 64
31. 27. Cope Elimination 66
32. 28. Cope Rearrangement 68
33. 29. Criegee & Malaprade Oxidation 70
34. 30. CuAAC 72
35. 31. Curtius Rearrangement 74
36. 32. Darzens Condensation 78
37. 33. Dess‒Martin Oxidation 80
38. 34. Diazotization (Diazonium Salt) 82
39. 34. Diazotization (Diazonium Salt) 84
40. 36. Di‒π‒Methane Rearrangement 86
41. 37. Favorskii Rearrangement 88
42. 38. Fischer Indole Synthesis 90
43. 39. Friedel‒Crafts Acylation & Alkylation 92
44. 40. Gabriel Synthesis 94
45. 41. Gewald Reaction 96
46. 42. Glaser–Eglinton–Hay Coupling 98
47. 43. Grignard Reaction 100
48. 44. Grob Fragmentation 102
49. 45. Haloform Reaction 104
50. 46. Heck Cross Coupling 106
51. 47. Hell–Volhard–Zelinsky Reaction 108
52. 48. Hiyama Cross Coupling 110
53. 49. Hofmann Elimination 112
54. 50. Horner–Wadsworth–Emmons Olefination 114
55. 51. Jones Oxidation 116
56. 52. Kucherov Reaction 118
57. 53. Kumada Cross Coupling 120
58. 54. Ley–Griffith Oxidation 122
59. 55. Liebeskind–Srogl Cross Coupling 124
60. 56. Mannich Reaction 126
61. 57. McMurry Coupling 128
62. 58. Meerwein–Ponndorf–Verley Reduction 130
63. 59. Michael Addition 132
64. 60. Minisci Reaction 134
65. 61. Mitsunobu Reaction 136
66. 62. Miyaura Borylation 138
67. 63. Mukaiyama RedOx Hydration 140
68. 64. Nazarov Cyclization 142
69. 65. Nef Reaction 144
70. 66. Negishi Cross Coupling 146
71. 67. Norrish Type I & II Reaction 148
72. 68. Olefin (Alkene) Metathesis 150
73. 69. Oppenauer Oxidation 154
74. 70. Ozonolysis 156
75. 71. Paal–Knorr Syntheses 158
76. 72. Paternò–Büchi Reaction 162
77. 73. Pauson–Khand Reaction 164
78. 74. Peptide (Amide) Coupling 166
79. 75. Pictet–Spengler Reaction 170
80. 76. Pinacol–Pinacolone Rearrangement 172
81. 77. Polonovski Reaction 174
82. 78. Prilezhaev Epoxidation 176
83. 79. Prins Reaction 178
84. 80. Pummerer Rearrangement 180
85. 81. Ramberg–Bäcklund Rearrangement 182
86. 82. Reformatsky Reaction 184
87. 83. Robinson Annulation 186
88. 84. Shapiro Reaction 188
89. 85. Sonogashira Cross Coupling 190
90. 86. Staudinger Reaction 192
91. 87. Steglich Esterification 194
92. 88. Stille Cross Coupling 196
93. 89. Suzuki Cross Coupling 198
94. 90. Swern Oxidation 200
95. 91. Ugi Reaction 202
96. 92. Ullmann Aryl–Aryl Coupling 204
97. 93. Upjohn Dihydroxylation 206
98. 94. Vilsmeier–Haack Reaction 208
99. 95. Wacker Oxidation 210
100. 96. Wagner–Meerwein Rearrangement 212
101. 97. Weinreb Ketone Synthesis 214
102. 98. Wittig Reaction 216
103. 99. Wohl–Ziegler Reaction 218
104. 100. Wolff–Kishner Reduction 220
105. Acknowledgments 223
106. Bibliography and References 225