64 Streptocyanine dyes
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Heinz Mustroph
Abstract
The simplest possible type of polymethine dye consists of an odd-numbered polymethine chain sandwiched between two terminal nitrogen atoms, which do not form part of an unsaturated heterocyclic ring. Originally, this type of colorant was termed streptopolymethine dyes. For systematic reasons they are usually called streptocyanine dyes today. Their color is mainly determined by the lengths of their polymethine chains. Owing to their simple structure they are the favorite compounds for investigation of fundamental structure-property relationships. In the form of dianil hydrochlorides mainly streptocyanines are used to prepare cyanine, hemicyanine, merocyanine, oxonol, pyrylium and thiopyrylium dyes.
Abstract
The simplest possible type of polymethine dye consists of an odd-numbered polymethine chain sandwiched between two terminal nitrogen atoms, which do not form part of an unsaturated heterocyclic ring. Originally, this type of colorant was termed streptopolymethine dyes. For systematic reasons they are usually called streptocyanine dyes today. Their color is mainly determined by the lengths of their polymethine chains. Owing to their simple structure they are the favorite compounds for investigation of fundamental structure-property relationships. In the form of dianil hydrochlorides mainly streptocyanines are used to prepare cyanine, hemicyanine, merocyanine, oxonol, pyrylium and thiopyrylium dyes.
Kapitel in diesem Buch
- Frontmatter I
- Preface V
- Contents VII
- List of contributors XV
- 45 Mixed metal oxide pigments 849
- 46 Monoazo (Monohydrazone) pigments based on acetoacetanilides 859
- 47 Monoazo (Monohydrazone) pigments based on benzimidazolones 871
- 48 Monoazo (Monohydrazone) pigments based on 2-naphthol and derivatives 885
- 49 Naphthopyran dyes 909
- 50 Organic pigments: general principles 925
- 51 Oxonitride pigments 955
- 52 Oxonol dyes 959
- 53 Perylene and perinone pigments 967
- 54 Photochromic dyes 979
- 55 Phthalocyanine blue pigments 1015
- 56 Phthalocyanine green pigments 1029
- 57 Phthalocyanine pigments: general principles 1035
- 58 Pigments: general aspects 1041
- 59 Polymethine dyes 1057
- 60 Quinacridone pigments 1071
- 61 Special effect pigments 1081
- 62 Spirooxazine dyes 1105
- 63 Spiropyran dyes 1125
- 64 Streptocyanine dyes 1153
- 65 Streptomerocyanine dyes 1165
- 66 Titanium dioxide pigments 1177
- 67 Transparent pigments 1195
- 68 Ultramarine pigments 1203
- 69 White pigments 1211
- 70 Zinc oxide pigments 1213
- 71 Zinc sulfide pigments 1219
- Index 1225
Kapitel in diesem Buch
- Frontmatter I
- Preface V
- Contents VII
- List of contributors XV
- 45 Mixed metal oxide pigments 849
- 46 Monoazo (Monohydrazone) pigments based on acetoacetanilides 859
- 47 Monoazo (Monohydrazone) pigments based on benzimidazolones 871
- 48 Monoazo (Monohydrazone) pigments based on 2-naphthol and derivatives 885
- 49 Naphthopyran dyes 909
- 50 Organic pigments: general principles 925
- 51 Oxonitride pigments 955
- 52 Oxonol dyes 959
- 53 Perylene and perinone pigments 967
- 54 Photochromic dyes 979
- 55 Phthalocyanine blue pigments 1015
- 56 Phthalocyanine green pigments 1029
- 57 Phthalocyanine pigments: general principles 1035
- 58 Pigments: general aspects 1041
- 59 Polymethine dyes 1057
- 60 Quinacridone pigments 1071
- 61 Special effect pigments 1081
- 62 Spirooxazine dyes 1105
- 63 Spiropyran dyes 1125
- 64 Streptocyanine dyes 1153
- 65 Streptomerocyanine dyes 1165
- 66 Titanium dioxide pigments 1177
- 67 Transparent pigments 1195
- 68 Ultramarine pigments 1203
- 69 White pigments 1211
- 70 Zinc oxide pigments 1213
- 71 Zinc sulfide pigments 1219
- Index 1225
