2. CO2-Controlled Polymer Self-Assembly and Application
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Bing Yu
Abstract
In this chapter, we present a brief introduction of the synthesis and properties of the CO2-responsive polymers with different CO2-responsive functional groups (tertiary amine, amidine, guanidine, imidazole, and carboxylic acid). Then we focus on the self-assembly behaviors of CO2-responsive polymers and the size, shape, and morphology transformation behaviors of their assemblies as triggered by CO2. Finally, we provide a review of selected recent studies demonstrating the potential applications of CO2-responsive polymer assemblies in the field of controllable encapsulation and release, CO2-induced gelation, and CO2-switchable surfactants.
Abstract
In this chapter, we present a brief introduction of the synthesis and properties of the CO2-responsive polymers with different CO2-responsive functional groups (tertiary amine, amidine, guanidine, imidazole, and carboxylic acid). Then we focus on the self-assembly behaviors of CO2-responsive polymers and the size, shape, and morphology transformation behaviors of their assemblies as triggered by CO2. Finally, we provide a review of selected recent studies demonstrating the potential applications of CO2-responsive polymer assemblies in the field of controllable encapsulation and release, CO2-induced gelation, and CO2-switchable surfactants.
Kapitel in diesem Buch
- Frontmatter I
- Preface V
- Contents IX
- List of Contributors XI
- 1. Design Principles for Organic Semiconductors 1
- 2. CO2-Controlled Polymer Self-Assembly and Application 51
- 3. Self-Healing Materials: Design and Applications 87
- 4. Redox-Responsive Self-Assembled Amphiphilic Materials: Review and Application to Biological Systems 113
- 5. Ultrafine Nanofiber Formation by Centrifugal Spinning 143
- 6. Rational Design of Highly Efficient Non-precious Metal Catalysts for Oxygen Reduction in Fuel Cells and Metal–Air Batteries 161
- 7. Toward the Assembly of Dynamic and Complex DNA Nanostructures 183
- 8. Alternating Copolymer Nanotubes 209
- 9. Molecular Glasses: Emerging Materials for the Next Generation 239
- 10. Production of Pluripotent Stem Cell-Derived Pancreatic Cells by Manipulating Cell-Surface Interactions 261
- 11. Phase Diagram of an Au–Pt Solid Core–Liquid Shell Nanoparticle 285
- 12. Directing the Self-Assembly of Nanoparticles for Advanced Materials 307
- 13. Toward Well-Defined Carbon Nanotubes and Graphene Nanoribbons 327
- 14. Modeling of Lithium-Ion Batteries 353
- Index 389
Kapitel in diesem Buch
- Frontmatter I
- Preface V
- Contents IX
- List of Contributors XI
- 1. Design Principles for Organic Semiconductors 1
- 2. CO2-Controlled Polymer Self-Assembly and Application 51
- 3. Self-Healing Materials: Design and Applications 87
- 4. Redox-Responsive Self-Assembled Amphiphilic Materials: Review and Application to Biological Systems 113
- 5. Ultrafine Nanofiber Formation by Centrifugal Spinning 143
- 6. Rational Design of Highly Efficient Non-precious Metal Catalysts for Oxygen Reduction in Fuel Cells and Metal–Air Batteries 161
- 7. Toward the Assembly of Dynamic and Complex DNA Nanostructures 183
- 8. Alternating Copolymer Nanotubes 209
- 9. Molecular Glasses: Emerging Materials for the Next Generation 239
- 10. Production of Pluripotent Stem Cell-Derived Pancreatic Cells by Manipulating Cell-Surface Interactions 261
- 11. Phase Diagram of an Au–Pt Solid Core–Liquid Shell Nanoparticle 285
- 12. Directing the Self-Assembly of Nanoparticles for Advanced Materials 307
- 13. Toward Well-Defined Carbon Nanotubes and Graphene Nanoribbons 327
- 14. Modeling of Lithium-Ion Batteries 353
- Index 389
