Article
Publicly Available
Cationic rhodium(I) complex-catalyzed σ- and π-bond activation cascade: Isomerization of allyl propargyl ethers to allenic aldehydes and dienals
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Ken Tanaka
Published/Copyright:
May 4, 2010
Online erschienen: 2010-5-4
Erschienen im Druck: 2010-5-4
© 2013 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Preface
- Phosphoramidite-rhodium complexes as catalysts for the asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes
- Efficient cyclization routes to substituted heterocyclic compounds mediated by transition-metal catalysts
- Multiple Pd-catalyzed reactions in the synthesis of natural products, drugs, and materials
- Mechanism of the oxidative addition of aryl halides to bis-carbene palladium(0) complexes
- Transition-metal-catalyzed direct arylations via C–H bond cleavages
- Catalytic activation of hydrogen, silicon, and fluorine by transition-metal complexes
- Developing chiral phosphorus ligands for asymmetric hydrogenations
- Chelation-assisted carbonylation reactions catalyzed by Rh and Ru complexes
- Cationic rhodium(I) complex-catalyzed σ- and π-bond activation cascade: Isomerization of allyl propargyl ethers to allenic aldehydes and dienals
- Highly enantioselective isomerization of primary allylic alcohols catalyzed by (P,N)-iridium complexes
- Aerobic oxidation with bifunctional molecular catalysts
- Nickel-catalyzed multicomponent coupling reaction using ynones
- Rhenium- and manganese-catalyzed carbon–carbon bond formation using 1,3-dicarbonyl compounds and alkynes
- Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions
- New pathways in the gold-catalyzed cycloisomerization of furanynes
- Combined coinage metal catalysis for the synthesis of bioactive molecules
- Alkynes as “masked” ylides under noble-metal catalysis
- On direct iron-catalyzed cross-coupling reactions
- Reactions of bridging C3 ligands in diiron complexes: Unconventional routes to new functionalized organic frames
Keywords for this article
cascade reactions;
C–H bond activation;
isomerization;
π-bond activation;
rearrangement;
rhodium
Articles in the same Issue
- Preface
- Phosphoramidite-rhodium complexes as catalysts for the asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes
- Efficient cyclization routes to substituted heterocyclic compounds mediated by transition-metal catalysts
- Multiple Pd-catalyzed reactions in the synthesis of natural products, drugs, and materials
- Mechanism of the oxidative addition of aryl halides to bis-carbene palladium(0) complexes
- Transition-metal-catalyzed direct arylations via C–H bond cleavages
- Catalytic activation of hydrogen, silicon, and fluorine by transition-metal complexes
- Developing chiral phosphorus ligands for asymmetric hydrogenations
- Chelation-assisted carbonylation reactions catalyzed by Rh and Ru complexes
- Cationic rhodium(I) complex-catalyzed σ- and π-bond activation cascade: Isomerization of allyl propargyl ethers to allenic aldehydes and dienals
- Highly enantioselective isomerization of primary allylic alcohols catalyzed by (P,N)-iridium complexes
- Aerobic oxidation with bifunctional molecular catalysts
- Nickel-catalyzed multicomponent coupling reaction using ynones
- Rhenium- and manganese-catalyzed carbon–carbon bond formation using 1,3-dicarbonyl compounds and alkynes
- Catalytic synthesis of amines and N-containing heterocycles: Amidate complexes for selective C–N and C–C bond-forming reactions
- New pathways in the gold-catalyzed cycloisomerization of furanynes
- Combined coinage metal catalysis for the synthesis of bioactive molecules
- Alkynes as “masked” ylides under noble-metal catalysis
- On direct iron-catalyzed cross-coupling reactions
- Reactions of bridging C3 ligands in diiron complexes: Unconventional routes to new functionalized organic frames