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How to predict changes in solvolysis mechanisms

  • Herbert Mayr and Armin R. Ofial
Published/Copyright: January 1, 2009
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Pure and Applied Chemistry
From the journal Pure and Applied Chemistry Volume 81 Issue 4

Published Online: 2009-01-01
Published in Print: 2009-01-01

© 2013 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Preface
  2. Symmetry of hydrogen bonds in solution
  3. Stabilizing reactive intermediates through site isolation
  4. Divalent carbon(0) compounds
  5. NMR spectroscopy and ion pairing: Measuring and understanding how ions interact
  6. Photochemical routes to silver and gold nanoparticles
  7. Proton transfers in aromatic systems: How aromatic is the transition state?
  8. How to predict changes in solvolysis mechanisms
  9. Kinetics and mechanism of the aminolysis of thioesters and thiocarbonates in solution
  10. Understanding solvation
  11. Steric and electronic effects in SN2 reactions
  12. Design of carborane molecular architectures with electronic structure computations: From endohedral and polyradical systems to multidimensional networks
  13. Mapping catalytic promiscuity in the alkaline phosphatase superfamily
  14. DNA nucleobase properties and photoreactivity: Modeling environmental effects
  15. Molecular organization and recognition properties of amphiphilic cyclodextrins
  16. Ionic liquids: Solvation ability and polarity
  17. Erratum
  18. Erratum
https://doi.org/10.1351/PAC-CON-08-08-26
Keywords for this article
carbocations; kinetics; linear free energy relationships; nucleofugality; nucleophilicity

Articles in the same Issue

  1. Preface
  2. Symmetry of hydrogen bonds in solution
  3. Stabilizing reactive intermediates through site isolation
  4. Divalent carbon(0) compounds
  5. NMR spectroscopy and ion pairing: Measuring and understanding how ions interact
  6. Photochemical routes to silver and gold nanoparticles
  7. Proton transfers in aromatic systems: How aromatic is the transition state?
  8. How to predict changes in solvolysis mechanisms
  9. Kinetics and mechanism of the aminolysis of thioesters and thiocarbonates in solution
  10. Understanding solvation
  11. Steric and electronic effects in SN2 reactions
  12. Design of carborane molecular architectures with electronic structure computations: From endohedral and polyradical systems to multidimensional networks
  13. Mapping catalytic promiscuity in the alkaline phosphatase superfamily
  14. DNA nucleobase properties and photoreactivity: Modeling environmental effects
  15. Molecular organization and recognition properties of amphiphilic cyclodextrins
  16. Ionic liquids: Solvation ability and polarity
  17. Erratum
  18. Erratum
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