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Structure and properties of a rare-topology [MnII4]-core complex with terminal bromido ligands
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Veröffentlicht/Copyright:
16. Juli 2012
Abstract
A rare-topology [MnII4]-core complex [Mn4Br4(ppko)4(CH3OH)4] (1; ppkoH = phenyl 2-pyridyl ketoxime) was synthesized via a solvothermal route and characterized by X-ray diffraction, IR, EPR, ESI-MS and magnetic properties measurements. In 1 Mn2+ ions are bridged with phenyl 2-pyridyl ketoxime ligands. Bromine atoms and methanol molecules are terminal ligands. A comparison is made to the reported analogues with different terminal ligands pattern.
Published Online: 2012-07-16
Published in Print: 2012-09
© by Oldenbourg Wissenschaftsverlag, München, Germany
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- Crystal structures of two hydrated sodium chromates: Na2CrO4 × 10 H2O and Na2CrO4 × 1.5 H2O
- Investigations of new barium dicarboxylates
- Structure and properties of a rare-topology [MnII4]-core complex with terminal bromido ligands
- Synthesis and crystal structure of cyano-bridged three dimensional polyheteronuclear complex
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Artikel in diesem Heft
- Crystal structures of two hydrated sodium chromates: Na2CrO4 × 10 H2O and Na2CrO4 × 1.5 H2O
- Investigations of new barium dicarboxylates
- Structure and properties of a rare-topology [MnII4]-core complex with terminal bromido ligands
- Synthesis and crystal structure of cyano-bridged three dimensional polyheteronuclear complex
- Hexafluorosilicates of alanine
- Hydrogen-bonding in the structures of the 1 : 1 salts of isonipecotamide with a set of four polyfunctional monocyclic heteroaromatic carboxylic acids
