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The similarities of the populous Cu2Sb and TlAsPd5 structures: Analysis of the building principles and formula of the TlAsPd5 structure
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August 25, 2010
Abstract
Similarities of the populous Cu2Sb and TlAsPd5 structures (both tetragonal) are noted, and questions concerning the formation of the TlAsPd5 variant and its building principles and MXN5 formula are discussed. These are resolved in terms of the axial ratios (c/a) and interatomic distances found in phases with the TlAsPd5 structure, and the fact that so far it has been found to be formed only with N = Pd, Pt and Ga. The structure is seen to be a Parthé-type segmental intergrowth structure, the building principle of which is a geometrical packing of the atoms.
Published Online: 2010-8-25
Published in Print: 1986-2-1
© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- Crystal structure refinement of K2HfF6
- High-temperature transformation of tridymite single crystals to cristobalite*
- Crystal structure of potassium pentafluorozirconate monohydrate, KZrF5 · H2O
- The similarities of the populous Cu2Sb and TlAsPd5 structures: Analysis of the building principles and formula of the TlAsPd5 structure
- Crystal structure of (η5-pentamethylcyclopentadienyl) (O,O′-diisopropyldithiophosphato) (dicarbonyl)-iron(II), FeS2PO4C18H29
- The crystal structure of U2NiC3
- The crystal structure of Zr3AlN
- Crystal structure of tris (glycine) calcium(II) dichloride
- Einführung in eine anorganische Strukturchemie
- The crystal structure refinement of a natural mordenite
- Characterization of lattice defects by means of a double crystal diffractometer
- Preparation and crystal structures of Ca(N3)2[OS(CH3)2]2 and Sr(N3)2[OS(CH3)2]2
- The crystal structures of Na2TiF6 and Na2SiF6
- The crystal structure of ethyl 5-methyl-l,2,3-triazino [5,4-b]-indole 4-carboxylate N(3)-oxide
- Die Kristallstruktur der orientierungsfehlgeordneten kubischen Hochtemperaturphase des Silberperchlorats AgClO4
- The shortest known interpolyhedral O – O distance in a silicate
- Crystal structure and optical lattice vibrations of SbSBr crystals
