Home The crystal structure of poly[di(μ2-aqua)-diaqua-bis(3-aminopyridine-4-carboxylate-κ2 O: O′)-tetra(μ2-3-aminopyridine-4-carboxylate-κ2 O: O′)-dineodymium(III), [Nd2(C6H5N2O2)6(H2O)4] n
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The crystal structure of poly[di(μ2-aqua)-diaqua-bis(3-aminopyridine-4-carboxylate-κ2 O: O′)-tetra(μ2-3-aminopyridine-4-carboxylate-κ2 O: O′)-dineodymium(III), [Nd2(C6H5N2O2)6(H2O)4] n

  • Xiang-Ping Pan , Zhao-Yan Ping , Wang Zhao and Qing-Hua Zheng ORCID logo EMAIL logo
Published/Copyright: February 29, 2024
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 239 Issue 3

Abstract

[Nd2(C6H5N2O2)6(H2O)4] n , monoclinic, P21/c (no. 14), a = 9.383(3) Å, b = 22.741(6) Å, c = 18.775(5) Å, β = 90.231(5)°, V = 4006(2) Å3, Z = 4, Rgt (F) = 0.0427, wRref (F 2) = 0.0862, T = 296 K.

CCDC no.: 2322454

The molecular structure is shown in the figure. Table 1 contains crystallographic data and Table 2 contains the list of the atoms including atomic coordinates and displacement parameters.

Table 1:

Data collection and handling.

Crystal: Colorless block
Size: 0.20 × 0.18 × 0.10 mm
Wavelength: Mo Kα radiation (0.71073 Å)
μ: 2.66 mm−1
Diffractometer, scan mode: Bruker APEX-II, φ and ω
θ max, completeness: 27.6°, >99 %
N(hkl)measured, N(hkl)unique, R int: 24,277, 9122, 0.063
Criterion for I obs, N(hkl)gt: I obs > 2 σ(I obs), 6092
N(param)refined: 605
Programs: Bruker [1], Diamond [2], Olex2 [3], SHELX [4, 5]
Table 2:

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2).

Atom x y z U iso*/U eq
Nd1 0.49211 (3) 0.35460 (2) 0.25256 (2) 0.01435 (8)
Nd2 1.04449 (3) 0.39830 (2) 0.26271 (2) 0.01375 (8)
O17 0.3219 (3) 0.43644 (14) 0.28824 (19) 0.0190 (8)
H17A 0.332005 0.444117 0.332611 0.028*
H17B 0.336265 0.465857 0.263161 0.028*
O2 0.3641 (4) 0.32326 (16) 0.3573 (2) 0.0227 (9)
O3 0.1471 (4) 0.36036 (16) 0.3721 (2) 0.0223 (9)
O4 0.3895 (4) 0.38804 (16) 0.14489 (19) 0.0219 (9)
O5 0.1729 (4) 0.42775 (16) 0.1527 (2) 0.0240 (9)
O6 0.6358 (4) 0.38627 (16) 0.3514 (2) 0.0248 (9)
O7 0.8481 (4) 0.42707 (17) 0.3392 (2) 0.0288 (10)
O8 0.8946 (4) 0.36458 (17) 0.1701 (2) 0.0280 (10)
O9 0.6796 (4) 0.32430 (17) 0.1688 (2) 0.0305 (10)
O10 0.9188 (4) 0.48624 (16) 0.2102 (2) 0.0278 (10)
O11 1.0712 (4) 0.50565 (15) 0.2961 (2) 0.0239(10)
O18 1.2009 (3) 0.31453 (14) 0.22682 (19) 0.0196 (8)
H18A 1.190447 0.306198 0.183953 0.029*
H18B 1.183987 0.282718 0.252823 0.029*
O13 0.9118 (4) 0.30711 (15) 0.3059 (2) 0.0242 (9)
H13A 0.966630 0.278136 0.303797 0.036*
H13B 0.827120 0.305276 0.287157 0.036*
O14 0.6150 (4) 0.26242 (15) 0.3004 (2) 0.0250 (9)
O15 0.6233 (3) 0.44527 (15) 0.2172 (2) 0.0222 (9)
H15A 0.663738 0.471007 0.240164 0.033*
H15B 0.611437 0.451907 0.171814 0.033*
N1 0.4474 (5) 0.2346 (2) 0.4431 (3) 0.0498 (17)
H1A 0.500895 0.206943 0.459449 0.060*
H1B 0.463952 0.249337 0.401782 0.060*
N2 0.2119 (5) 0.2420 (2) 0.5932 (3) 0.0292 (12)
N3a 0.1029 (9) 0.5117 (4) 0.0600 (4) 0.036 (3)
H3Aa 0.055540 0.540824 0.042599 0.044*
H3Ba 0.082424 0.498311 0.101494 0.044*
N4 0.3488 (5) 0.4930 (2) −0.0866 (3) 0.0318 (13)
N5 0.6720 (5) 0.2251 (2) 0.0826 (3) 0.0416 (15)
H5A 0.653680 0.234067 0.126133 0.050*
H5B 0.633608 0.194446 0.063716 0.050*
N6 0.8905 (6) 0.2677 (3) −0.0666 (3) 0.0455 (16)
N7 1.1154 (5) 0.61980 (19) 0.3327 (3) 0.0278 (12)
H7A 1.135478 0.584279 0.344883 0.033*
H7B 1.156977 0.648773 0.353677 0.033*
N8 0.8775 (5) 0.70374 (19) 0.2196 (3) 0.0258 (12)
N9 0.5324 (5) 0.3836 (3) 0.4886 (3) 0.0489 (16)
H9A 0.474985 0.374649 0.522530 0.059*
H9B 0.533580 0.362783 0.450327 0.059*
N10 0.6961 (6) 0.5074 (2) 0.5742 (3) 0.0402 (15)
N11 0.3938 (5) 0.1409 (2) 0.1704 (3) 0.0329 (13)
H11A 0.349967 0.114278 0.146312 0.039*
H11B 0.375878 0.177462 0.162787 0.039*
N12 0.6206 (5) 0.0448 (2) 0.2743 (3) 0.0293 (12)
C1 0.2514 (5) 0.3300 (2) 0.3918 (3) 0.0157 (12)
C2 0.2404 (6) 0.2990 (2) 0.4618 (3) 0.0185 (12)
C3 0.3371 (6) 0.2548 (2) 0.4824 (3) 0.0209 (13)
C4 0.3159 (6) 0.2291 (3) 0.5487 (3) 0.0269 (14)
H4 0.380522 0.200365 0.562882 0.032*
C5 0.1210 (6) 0.2839 (3) 0.5719 (3) 0.0296 (15)
H5 0.046426 0.293797 0.602089 0.036*
C6 0.1314 (6) 0.3127 (3) 0.5087 (3) 0.0253 (14)
H6 0.065431 0.341665 0.496927 0.030*
C7 0.2865 (6) 0.4183 (2) 0.1197 (3) 0.0179 (12)
C8 0.3049 (6) 0.4428 (2) 0.0468 (3) 0.0204 (13)
C9 0.2134 (6) 0.4862 (3) 0.0205 (3) 0.0272 (14)
H9b 0.135727 0.499106 0.046892 0.033*
C10 0.2420 (7) 0.5094 (3) −0.0459 (4) 0.0351 (16)
H10 0.181564 0.538634 −0.063087 0.042*
C11 0.4343 (6) 0.4511 (3) −0.0616 (3) 0.0348 (16)
H11 0.509144 0.438386 −0.090008 0.042*
C12 0.4173 (6) 0.4258 (3) 0.0041 (3) 0.0243 (14)
H12a 0.481224 0.397333 0.019876 0.029*
C13 0.7369 (6) 0.4174 (2) 0.3733 (3) 0.0190 (12)
C14 0.7974 (6) 0.3347 (2) 0.1421 (3) 0.0174 (12)
C15 0.8287 (5) 0.3098 (2) 0.0700 (3) 0.0200 (12)
C16 0.7620 (6) 0.2595 (3) 0.0435 (3) 0.0243 (13)
C17 0.7982 (7) 0.2409 (3) −0.0258 (4) 0.0373 (17)
H17 0.753572 0.207506 −0.043628 0.045*
C18 0.9557 (7) 0.3152 (3) −0.0399 (4) 0.0413 (17)
H18 1.022357 0.334542 −0.067942 0.050*
C19 0.9289 (6) 0.3366 (3) 0.0267 (3) 0.0323 (15)
H19 0.978297 0.369447 0.043111 0.039*
C20 0.9793 (6) 0.5221 (2) 0.2500 (3) 0.0197 (13)
C21 0.9451 (5) 0.5865 (2) 0.2433 (3) 0.0192 (13)
C22 1.0182 (6) 0.6301 (2) 0.2805 (3) 0.0206 (13)
C23 0.9805 (6) 0.6886 (2) 0.2635 (3) 0.0234 (13)
H23 1.032371 0.718655 0.284970 0.028*
C24 0.8056 (6) 0.6609 (3) 0.1858 (3) 0.0281 (14)
H24 0.731770 0.670806 0.154862 0.034*
C25 0.8390 (5) 0.6025 (2) 0.1960 (3) 0.0221 (13)
H25 0.789617 0.573695 0.170927 0.027*
C26 0.7216 (5) 0.4468 (2) 0.4443 (3) 0.0221 (13)
C27 0.6210 (5) 0.4304 (2) 0.4954 (3) 0.0197 (13)
C28 0.6141 (7) 0.4621 (3) 0.5581 (3) 0.0361 (16)
H28 0.546609 0.450637 0.591448 0.043*
C29 0.7917 (8) 0.5230 (3) 0.5259 (4) 0.0449 (19)
H29 0.851187 0.554587 0.536135 0.054*
C30 0.8077 (6) 0.4950 (3) 0.4614 (3) 0.0343 (16)
H30 0.875733 0.508203 0.429238 0.041*
C31 0.5475 (6) 0.2296 (2) 0.2586 (3) 0.0200 (13)
O16 0.4587 (4) 0.25024 (15) 0.2148 (2) 0.0241 (10)
C33 0.5704 (5) 0.1648 (2) 0.2622 (3) 0.0190 (12)
C34 0.4915 (6) 0.1252 (2) 0.2208 (3) 0.0199 (13)
C35 0.5183 (6) 0.0655 (3) 0.2320 (3) 0.0278 (14)
H35 0.460816 0.038411 0.208341 0.033*
C36 0.6973 (6) 0.0833 (3) 0.3112 (4) 0.0305 (15)
H36 0.769784 0.069407 0.340718 0.037*
C37 0.6739 (6) 0.1422 (2) 0.3075 (3) 0.0221 (13)
H37 0.727830 0.167549 0.335649 0.027*
N3Ab 0.5295 (12) 0.3863 (5) 0.0206 (6) 0.030 (4)
H3AAb 0.597268 0.380750 −0.009397 0.036*
H3ABb 0.529864 0.367833 0.060574 0.036*

  1. aOccupancy: 0.596(9), bOccupancy: 0.404(9).

1 Source of materials

3-Aminoisonicotinic acid (0.6 mmol 0.083 g), Nd2O3 (0.2 mmol 0.067 g), and 0.4 mol L−1 NaOH solution (1 mL), were dissolved in deionized water (7 mL). The mixture was sealed in a 25-mL Teflon-lined steel autoclave, and heated at 453 K for 8 days, then slowly cooled to room temperature. Colorless crystals of title complex could be found in the product.

2 Experimental details

All hydrogen atoms were placed in calculated positions and refined as riding atoms. The values were set to be 1.2U eq or 1.5U eq of the parent atoms.

3 Comment

Lanthanide complexes of 3-aminoisonicotinic acid have attracted some attentions during recent decades [6–11]. However, transition metal complexes for this ligand are relatively rare. A complex ([Nd2(C6H5N2O2)6(H2O)4] n ) of 3-aminoisonicotinic acid has been prepared under solvothermal reaction conditions. The asymmetric unit of title complex contains one Nd13+ ion, one Nd23+ ion, six L− (HL = 3-aminoisonicotinic acid) ligands and four coordinated aqua molecules. Each Nd1(III) ion is nine-coordinated by four oxygen atoms of four bridging L− ligands, two chelating oxygen atoms of one L− ligand and three oxygen atoms of three coordinated aqua molecules. The environment of the Nd23+ ion is similar to Nd13+. Each of Nd2(III) ions is surrounded by two chelating oxygen atoms of a L− ligand, four oxygen atoms of four μ 2-bridging L− ligands and three water oxygen atoms, forming a nine-coordination geometry, too. The Nd–O distances vary from 2.359(4) to 2.918(3) Å [12], [13], [14]. The O–Nd1–O angles are in the range 51.35(12)–145.45(13)°. Among the six L− ligands of the asymmetric unit, four act as μ 2-bridges, linking Nd1(III) and Nd2(III) ions, and two chelate to Nd(III) ions. While two of the four coordinated aqua molecules also play the roles of bridges, connecting Nd1(III) and Nd2(III) ions, and the other two act as monodentate ligands.

Each Nd1(III) ion is connected to one Nd2(III) ion via two μ 2–L− and two water molecules, and to another Nd2(III) ion by two μ 2–L−–L ligands, forming the 1–D zigzag-chain structure of the title complex with nonbonding Nd····Nd separations of 4.32–5.28 Å and Nd–Nd–Nd angles of 155.408(11)°. The zigzag chains stack parallel along the b axis, constructing the 3–D architecture of the title complex.

Corresponding author: Qing-Hua Zheng, School of Chemistry & Materials Engineering, Huainan Normal University, Huainan, Anhui 232038, P.R. China, E-mail:

Funding source: NSF (Natural Science Foundation) of Anhui Province

Award Identifier / Grant number: 2108085MB53

Funding source: The NSF for Distinguished Young Scholars of Anhui University

Award Identifier / Grant number: 2022AH020087

Funding source: University NSF of Anhui Province, Research

Award Identifier / Grant number: KJ2020A0647

  1. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

  2. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  3. Research funding: NSF (Natural Science Foundation) of Anhui Province (2108085MB53), the NSF for Distinguished Young Scholars of Anhui University (2022AH020087), University NSF of Anhui Province (KJ2020A0647), Research.

References

1. Bruker. SAINT, APEX3 and SADABS; Bruker AXS Inc.: Madison, WI, USA, 2013.Search in Google Scholar

2. Brandenburg, K. DIAMOND. Visual Crystal Structure Information System. Ver. 4.6.8; Crystal Impact GbR: Bonn, Germany, 2022.Search in Google Scholar

3. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K., Puschmann, H. OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Crystallogr. 2009, 42, 339–341; https://doi.org/10.1107/s0021889808042726.Search in Google Scholar

4. Sheldrick, G. M. Crystal structure refinement with SHELXL. Acta Crystallogr. 2015, C71, 3–8; https://doi.org/10.1107/s2053229614024218.Search in Google Scholar PubMed PubMed Central

5. Sheldrick, G. M. SHELXTL - integrated space-group and crystal-structure determination. Acta Crystallogr. 2015, A71, 3–8.10.1107/S2053273314026370Search in Google Scholar PubMed PubMed Central

6. Xue, X., Shao, Z., Cui, Y., Wen, T., Chen, J., Geng, K., Mi, L., Hou, H. Water-stable amino-functionalized coordination polymer for efficient Hg2+capture. Cryst. Growth Des. 2022, 22, 1412–1420; https://doi.org/10.1021/acs.cgd.1c01370.Search in Google Scholar

7. Ghosh, D., Fukushima, T., Kobayashi, K., Sen, S., Kitagawa, S., Katod, T., Tanaka, K. Base assisted C -C coupling between carbonyl and polypyridyl ligands in a Ru -NADH-type carbonyl complex. Dalton Trans. 2017, 46, 4373–4381; https://doi.org/10.1039/c7dt00312a.Search in Google Scholar PubMed

8. Ruan, M., Li, A., Wen, Y., Zhou, L., Zhang, J., Xuan, X. Adenine-based Bio -MOFs with high water and acid? Base stability for ammonia capture. CrystEngComm 2022, 24, 7420–7426; https://doi.org/10.1039/d2ce01092e.Search in Google Scholar

9. Gantzler, N., Kim, M.-B., Robinson, A., Terban, M. W., Ghose, S., Dinnebier, R. E., York, A. H., Tiana, D., Simon, C. M., Thallapally, P. K. Computation-informed optimization of Ni(PyC)2 functionalization for noble gas separations. Cell. Rep. Phys. Sci. 2022, 3, 101025; https://doi.org/10.1016/j.xcrp.2022.101025.Search in Google Scholar

10. Alduhaish, O., Li, B., Arman, H., Lin, R.-B., Zhao, J. C.-G., Chen, B. A Two-dimensional microporous metal -organic framework for highly selective adsorption of carbon dioxide and acetylene. Chinese Chem. Lett. 2017, 28, 1653–1658; https://doi.org/10.1016/j.cclet.2017.04.025.Search in Google Scholar

11. Liu, F.-F., Ping, Z.-Y., Zhou, W.-W., Zhao, W. The crystal structure of poly[(μu2-3-Aminopyridine-4-Carboxylate-κ2Nu: O)2Zinc(II)], [Zn(C6H5N2O2)2]n. Z. Kristallogr. N. Cryst. Struct. 2023, 238, 1131–1132; https://doi.org/10.1515/ncrs-2023-0358.Search in Google Scholar

12. Tiihonen, A., Lahtinen, M. In-depth structural analysis of lanthanoid coordination networks based on a flexible tripodal zwitterionic isonicotinate ligand. CrystEngComm 2019, 21, 2286–2302; https://doi.org/10.1039/c8ce01015c.Search in Google Scholar

13. Mondal, K. C., Sengupta, O., Dutta, P., Seehra, M., Nayak, S. K., Mukherjee, P. S. Three-dimensional 3d-4f heterometallic polymers containing both azide and carboxylate as co-LIGANDS. Inorg. Chim. Acta 2009, 362, 1913–1917; https://doi.org/10.1016/j.ica.2008.09.018.Search in Google Scholar

14. Feng, R., Chen, L., Chen, Q.-H., Shan, X.-C., Gai, Y.-L., Jiang, F.-L., Hong, M.-C. Novel luminescent three-dimensional heterometallic complexes with 2-fold interpenetrating (3,6)-connected nets. Cryst. Growth Des. 2011, 11, 1705–1712; https://doi.org/10.1021/cg101642j.Search in Google Scholar
Received: 2023-12-29
Accepted: 2024-02-05
Published Online: 2024-02-29
Published in Print: 2024-06-25

© 2024 the author(s), published by De Gruyter, Berlin/Boston

This work is licensed under the Creative Commons Attribution 4.0 International License.

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  38. Crystal structure of N-(acridin-9-yl)-2-(4-methylpiperidin-1-yl) acetamide monohydrate, C21H25N3O2
  39. The crystal structure of dichlorido-bis(3-methyl-3-imidazolium-1-ylpropionato-κ2 O,O′)-zinc(II), C14H20Cl2N4O4Zn
  40. The crystal structure of 2,8-diethyl-1,3,7,9-tetramethyl-4λ4,5λ4-spiro[dipyrrolo[1,2-c:2′,1′-f][1,3,2]diazaborinine-5,2′-naphtho[1,8-de][1,3,2]dioxaborinine], C25H29BN2O2
  41. The crystal structure of 5-tert-butyl-2-(5-tert-butyl-3-iodo-benzofuran-2-yl)-3-iodobenzofuran, C24H24I2O2
  42. Synthesis and crystal structure of methyl 2-{[4-(4-cyclopropyl-1-naphthyl)-4H-1,2,4-triazole-3-yl]thio} acetate, C18H17N3O2S
  43. The crystal structure of n-propylammonium bis(2,3-dimethylbutane-2,3-diolato)borate-boric acid (1/1), [C3H10N][C12H24BO4]·B(OH)3
  44. Crystal structure of methyl 1-(2-bromophenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate, C19H17BrN2O2
  45. Crystal structure of (4-bromobenzyl)triphenylphosphonium bromide ethanol solvate, C52H48Br4OP2
  46. The crystal structure of unsymmetrical BOPHY C26H27BN4
  47. The crystal structure of Tb3B5O11(OH)2
  48. The crystal structure of (Z)-4-ethyl-2-((4-ethyl-3,5-dimethyl-1H-pyrrol-2-yl)methylene)-3,5-dimethyl-2H-pyrrol-1-ium 2,2'-spirobi[naphtho[1,8-de][1,3,2]dioxaborinin]-2-uide, C37H37BN2O4
  49. Crystal structure of bis(methylammonium) hexadecaselenidopalladate(II), (CH3NH3)2PdSe16
  50. The crystal structure of (2-diphenylphosphanylphenyl) 2-[7-(dimethylamino)-2-oxochromen-4-yl]acetate, C31H26NO4P
  51. Crystal structure of (E)-6-(4-ethylpiperazin-1-yl)-2-(3-fluorobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C23H25FN2O
  52. The structure of RUB-56, (C6H16N)8 [Si32O64(OH)8]·32 H2O, a hydrous layer silicate (2D-zeolite) that contains microporous levyne-type silicate layers
  53. Crystal structure of 4-amino-3,5-dibromobenzonitrile, C7H4Br2N2
  54. Crystal structure of 2-(naphthalen-1-yl)ethyl 2-acetoxybenzoate, C21H18O4
  55. Single-crystal structure determination of Tm3B12O19(OH)7
  56. Crystal structure determination of NdB3.6O7
  57. The crystal structure of NdB6O8(OH)5·H3BO3
  58. Crystal structure of 2-(5-ethylpyridin-2-yl)ethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C23H25NO3
  59. Crystal structure of N-(1-(3,4-dimethoxyphenyl)-2-methylpropyl)aniline, C18H23NO2
  60. Crystal structure of Ba6Cd12Mn4SiF48
  61. Synthesis and crystal structure of 5-fluoro-1-methyl-2-oxo-3-(2-oxochroman-4-yl)indolin-3-yl acetate, C20H16FNO5
  62. The crystal structure of 6-methacryloylbenzo[d][1,3]dioxol-5-yl 4-nitrobenzenesulfonate, C17H13NO8S
  63. Crystal structure of ethyl 2-(3-benzyl-4-oxo-3,4-dihydrophthalazin-1-yl)- 2,2-difluoroacetate, C19H16F2N2O3
  64. The crystal structure of tetrakis(μ 2-(1H-benzimidazole-2-methoxo-κ2 N,O:O:O)-(n-butanol-κO)-chlorido)-tetranickel(II), C48H68Cl4N8O8Ni4
  65. Synthesis and crystal structure of trans-tetraaqua-bis((1-((7-hydroxy-3-(4-methoxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)piperidin-1-ium-4-carbonyl)oxy-κO)zinc(II)hexahydrate, C46H64N2O28S2Zn
  66. The crystal structure of 1-(4-carboxybutyl)-3-methyl-1H-imidazol-3-ium hexafluoridophosphate, C9H15F6N2O2P
  67. Crystal structure of 1-(4-chlorophenyl)-4-(2-furoyl)-3-phenyl-1H-pyrazol-5-ol, C20H13ClN2O3
  68. Crystal structure of dimethyl (R)-2-(3-(1-phenylethyl)thioureido)-[1,1′-biphenyl]-4,4′-dicarboxylate, C25H24N2O4S
  69. The crystal structure of 1-(3-carboxypropyl)-1H-imidazole-3-oxide, C7H10N2O3
  70. Synthesis and crystal structure of dimethyl 4,4′-(propane-1,3-diylbis(oxy))dibenzoate, C19H20O6
  71. Crystal structure of methyl-1-(p-tolyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate, C20H20N2O2
  72. The crystal structure of 1-(1-adamantan-1-yl)ethyl-3-(3-methoxyphenyl)thiourea, C20H28N2OS
  73. The crystal structure of N,N′-carbonylbis(2,6-difluorobenzamide), C15H8F4N2O3
https://doi.org/10.1515/ncrs-2023-0558
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Articles in the same Issue

  1. Frontmatter
  2. New Crystal Structures
  3. The crystal structure of tris((Z)-2-hydroxy-N-((E)-pyridin-2-ylmethylene)benzohydrazonato-k2O,N)europium(III), C39H30N9O6Eu
  4. Crystal structure of (E)-3-(benzylideneamino)-2-phenylthiazolidin-4-one, C16H14N2OS
  5. The crystal structure of (E)-4-fluoro-N′-(1-(o-tolyl)ethylidene)benzohydrazide, C16H15FN2O
  6. Crystal structure of (6-chloropyridin-3-yl)methyl 2-(6-methoxynaphthalen-2-yl)propanoate, C20H18ClNO3
  7. Crystal structure of methyl 3-methoxy-4-(2-methoxy-2-oxoethoxy)benzoate, C12H14O6
  8. The crystal structure of bis[(4-methoxyphenyl)(picolinoyl)amido-κ2 N:N′]copper(II), C26H22CuN4O4
  9. The crystal structure of poly[di(μ2-aqua)-diaqua-bis(3-aminopyridine-4-carboxylate-κ2 O: O′)-tetra(μ2-3-aminopyridine-4-carboxylate-κ2 O: O′)-dineodymium(III), [Nd2(C6H5N2O2)6(H2O)4] n
  10. The crystal structure of t-butyl 7-[3-(4-fluorophenyl)-1-(propan-2-yl)-1H-indol-2-yl]-3,5-dihydroxyhept-6-enoate, C28H34FNO4
  11. Crystal structure of catena-poly[(benzylamine-κ1 N)-(sorbato-κ1 O)-(μ2-sorbato-κ2 O,O′)-copper(II), C19H23CuNO4
  12. Crystal structure of (4-(2-chlorophenyl)-1H-pyrrol-3-yl)(ferrocenyl) methanone, C21H16ClFeNO
  13. The crystal structure of N-[4-(4-bromophenyl)-1,3-thiazol-2-yl]-3-(2-methylphenyl)-2-sulfanylprop-2-enamide hydrate, C19H17BrN2O2S2
  14. The crystal structure of N′-{5-[2-(2,6-dimethylphenoxy) acetamido]-4-hydroxy-1,6-diphenylhexan-2-yl}-3-methyl-2-(2-oxo-1,3-diazinan-1-yl)butanamide hydrate
  15. Crystal structure of 2-(naphthalen-1-yl)ethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C26H24O3
  16. Crystal structure of naphthalen-1-ylmethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C25H22O3
  17. Crystal structure of poly[diaqua- (μ4-5-(1H-1,2,4-triazol-1-yl)benzene-1,3-dicarboxylato-κ5N:O,O’:O’’:O’’’)calcium(II), C10H9CaN3O6
  18. Crystal structure of (E)-N′-(4-((E)-3-(dimethylamino)acryloyl)-3-hydroxyphenyl)-N, N-dimethylformimidamide, C14H19N3O2
  19. Crystal structure of (E)-3-(dimethylamino)-1-(2-hydroxy-4,6-dimethoxyphenyl)prop-2-en-1-one, C13H17NO4
  20. Crystal structure of (2-chloropyridin-3-yl)methyl-2-(6-methoxynaphthalen-2-yl)propanoate, C20H18ClNO3
  21. The crystal structure of diethyl 4-(3,4-dimethylphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate, C21H27NO4
  22. Crystal structure of (8R,9S,10R,13S,14S,17S)-17-hydroxy-10,13-dimethyl-17-((4-(2-phenylpropyl)phenyl)ethynyl)-1,2,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-3H-cyclopenta[a]phenanthren-3-one, C36H42O2
  23. Synthesis and crystal structure of 4-(4-cyclopropylnaphthalen-1-yl)-2,4-dihydro-3H-1,2,4-triazole-3-thione, C15H13N3S
  24. Crystal structure of catena-poly[aqua-(2,6-di-(2-pyridyl)-pyridine-κ3 N,N′, N″)(μ2-1,4-naphthalene dicarboxylato-κ2 O,O′)nickel(II)], C27H19NiN3O5
  25. Crystal structure of 3-(diphenylphosphoryl)-3-hydroxy-1-phenylpropan-1-one, C21H19O3P
  26. The crystal structure of R,S-{N-[(2-oxidonaphthalen-1-yl)methylidene]phenylglycinato}divinylsilicon, C23H19NO3Si
  27. The crystal structure of 1,2,4-tris(bromomethyl)benzene, C9H9Br3
  28. Crystal structure of chlorido-[4-(pyridin-2-yl)benzaldehyde-κ2 N,C]-(diethylamine-κ1 N)platinum(II), C16H18ClN2OPt
  29. Crystal structure of 3-(methoxycarbonyl)-1-(4-methoxyphenyl)-2,3,4,9- tetrahydro-1H-pyrido[3,4-b]indol-2-ium chloride hydrate, C40H48Cl2N4O9
  30. The crystal structure of 1-(2-chlorobenzyl)-3-(3-chlorophenyl)urea, C14H12Cl2N2O
  31. Hydrothermal synthesis and crystal structure of aqua-tris(4-acetamidobenzoato-κ2 O,O′)-(1,10-phenanthroline-κ2 N,N′)terbium(III) hydrate C39H36N5O11Tb
  32. The crystal structure of zwitterionic 3-aminoisonicotinic acid, C6H6N2O2
  33. The crystal structure of bis{[monoaqua-μ2-4-[(pyridine-4-carbonyl)-amino]-phthalato-κ3 N:O,O′-(2,2′-bipyridine κ2 N,N′)copper(II)]}decahydrate, C48H56N8O22Cu2
  34. Crystal structure of poly[μ10-4,4′-methylene-bis(oxy)benzoatodipotassium], C15H10K2O6
  35. The crystal structure of catena-poly[[tetraaqua[(μ2-1,4-di(4-methyl-1-imidazolyl)benzene] cobalt(II)]bis(formate)], C16H24CoN4O8
  36. The crystal structure of (E)-2-chloro-5-((2-(nitromethylene)imidazolidin-1-yl)methyl)pyridine, C10H11ClN4O2
  37. The crystal structure of (E)-1-(((2-amino-4,5-dimethylphenyl)iminio)methyl)naphthalen-2-olate, C19H18N2O
  38. Crystal structure of N-(acridin-9-yl)-2-(4-methylpiperidin-1-yl) acetamide monohydrate, C21H25N3O2
  39. The crystal structure of dichlorido-bis(3-methyl-3-imidazolium-1-ylpropionato-κ2 O,O′)-zinc(II), C14H20Cl2N4O4Zn
  40. The crystal structure of 2,8-diethyl-1,3,7,9-tetramethyl-4λ4,5λ4-spiro[dipyrrolo[1,2-c:2′,1′-f][1,3,2]diazaborinine-5,2′-naphtho[1,8-de][1,3,2]dioxaborinine], C25H29BN2O2
  41. The crystal structure of 5-tert-butyl-2-(5-tert-butyl-3-iodo-benzofuran-2-yl)-3-iodobenzofuran, C24H24I2O2
  42. Synthesis and crystal structure of methyl 2-{[4-(4-cyclopropyl-1-naphthyl)-4H-1,2,4-triazole-3-yl]thio} acetate, C18H17N3O2S
  43. The crystal structure of n-propylammonium bis(2,3-dimethylbutane-2,3-diolato)borate-boric acid (1/1), [C3H10N][C12H24BO4]·B(OH)3
  44. Crystal structure of methyl 1-(2-bromophenyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate, C19H17BrN2O2
  45. Crystal structure of (4-bromobenzyl)triphenylphosphonium bromide ethanol solvate, C52H48Br4OP2
  46. The crystal structure of unsymmetrical BOPHY C26H27BN4
  47. The crystal structure of Tb3B5O11(OH)2
  48. The crystal structure of (Z)-4-ethyl-2-((4-ethyl-3,5-dimethyl-1H-pyrrol-2-yl)methylene)-3,5-dimethyl-2H-pyrrol-1-ium 2,2'-spirobi[naphtho[1,8-de][1,3,2]dioxaborinin]-2-uide, C37H37BN2O4
  49. Crystal structure of bis(methylammonium) hexadecaselenidopalladate(II), (CH3NH3)2PdSe16
  50. The crystal structure of (2-diphenylphosphanylphenyl) 2-[7-(dimethylamino)-2-oxochromen-4-yl]acetate, C31H26NO4P
  51. Crystal structure of (E)-6-(4-ethylpiperazin-1-yl)-2-(3-fluorobenzylidene)-3,4-dihydronaphthalen-1(2H)-one, C23H25FN2O
  52. The structure of RUB-56, (C6H16N)8 [Si32O64(OH)8]·32 H2O, a hydrous layer silicate (2D-zeolite) that contains microporous levyne-type silicate layers
  53. Crystal structure of 4-amino-3,5-dibromobenzonitrile, C7H4Br2N2
  54. Crystal structure of 2-(naphthalen-1-yl)ethyl 2-acetoxybenzoate, C21H18O4
  55. Single-crystal structure determination of Tm3B12O19(OH)7
  56. Crystal structure determination of NdB3.6O7
  57. The crystal structure of NdB6O8(OH)5·H3BO3
  58. Crystal structure of 2-(5-ethylpyridin-2-yl)ethyl 2-(6-methoxynaphthalen-2-yl)propanoate, C23H25NO3
  59. Crystal structure of N-(1-(3,4-dimethoxyphenyl)-2-methylpropyl)aniline, C18H23NO2
  60. Crystal structure of Ba6Cd12Mn4SiF48
  61. Synthesis and crystal structure of 5-fluoro-1-methyl-2-oxo-3-(2-oxochroman-4-yl)indolin-3-yl acetate, C20H16FNO5
  62. The crystal structure of 6-methacryloylbenzo[d][1,3]dioxol-5-yl 4-nitrobenzenesulfonate, C17H13NO8S
  63. Crystal structure of ethyl 2-(3-benzyl-4-oxo-3,4-dihydrophthalazin-1-yl)- 2,2-difluoroacetate, C19H16F2N2O3
  64. The crystal structure of tetrakis(μ 2-(1H-benzimidazole-2-methoxo-κ2 N,O:O:O)-(n-butanol-κO)-chlorido)-tetranickel(II), C48H68Cl4N8O8Ni4
  65. Synthesis and crystal structure of trans-tetraaqua-bis((1-((7-hydroxy-3-(4-methoxy-3-sulfonatophenyl)-4-oxo-4H-chromen-8-yl)methyl)piperidin-1-ium-4-carbonyl)oxy-κO)zinc(II)hexahydrate, C46H64N2O28S2Zn
  66. The crystal structure of 1-(4-carboxybutyl)-3-methyl-1H-imidazol-3-ium hexafluoridophosphate, C9H15F6N2O2P
  67. Crystal structure of 1-(4-chlorophenyl)-4-(2-furoyl)-3-phenyl-1H-pyrazol-5-ol, C20H13ClN2O3
  68. Crystal structure of dimethyl (R)-2-(3-(1-phenylethyl)thioureido)-[1,1′-biphenyl]-4,4′-dicarboxylate, C25H24N2O4S
  69. The crystal structure of 1-(3-carboxypropyl)-1H-imidazole-3-oxide, C7H10N2O3
  70. Synthesis and crystal structure of dimethyl 4,4′-(propane-1,3-diylbis(oxy))dibenzoate, C19H20O6
  71. Crystal structure of methyl-1-(p-tolyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylate, C20H20N2O2
  72. The crystal structure of 1-(1-adamantan-1-yl)ethyl-3-(3-methoxyphenyl)thiourea, C20H28N2OS
  73. The crystal structure of N,N′-carbonylbis(2,6-difluorobenzamide), C15H8F4N2O3
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