Band 35, Heft 6

Environmental concerns have given a great deal of attention for the production of ultra-low-sulfur fuels. The conventional hydrodesulfurization (HDS) process has high operating cost and also encounters difficulty in removing sulfur compound with steric hindrance. Consequently, various research efforts have been made to overcome the limitation of conventional HDS process and exploring the alternative technologies for deep desulfurization. The alternative processes being explored for the production of ultra-low-sulfur content fuel are adsorptive desulfurization (ADS), biodesulfurization (BDS), oxidative desulfurization (ODS), and extractive desulfurization (EDS). The present article provided the comprehensive information on the basic principle, reaction mechanism, workability, advantages, and disadvantages of conventional and alternative technologies. This review article aims to provide valuable insight into the recent advances made in conventional HDS process and alternative techniques. For deep desulfurization of liquid fuels, integration of conventional HDS with an alternative technique is also proposed.

The quantitative understanding of the dissolution of nuclear fuel materials is essential for the process design and development of an industrial-scale nuclear fuel reprocessing plant. The main objective of this review article is to analyze the published data related to the dissolution of important nuclear materials, namely, urania, plutonia, thoria, and their oxides in the existing literature. The published results on rate-controlling step and reaction mechanism of dissolution processes are reconciled and reviewed in this work. Clear suggestions are made for future research work for the identification of rate-controlling step. Suggestions are also provided to overcome the shortfalls in the published data for the identification of intrinsic kinetics and mass-transfer rates.

Biochar is a solid by-product of thermochemical conversion of biomass to bio-oil and syngas. It has a carbonaceous skeleton, a small amount of heteroatom functional groups, mineral matter, and water. Biochar’s unique physicochemical structures lead to many valuable properties of important technological applications, including its sorption capacity. Indeed, biochar’s wide range of applications include carbon sequestration, reduction in greenhouse gas emissions, waste management, renewable energy generation, soil amendment, and environmental remediation. Aside from these applications, new scientific insights and technological concepts have continued to emerge in the last decade. Consequently, a systematic update of current knowledge regarding the complex nature of biochar, the scientific and technological impacts, and operational costs of different activation strategies are highly desirable for transforming biochar applications into industrial scales. This communication presents a comprehensive review of physical activation/modification strategies and their effects on the physicochemical properties of biochar and its applications in environment-related fields. Physical activation applied to the activation of biochar is discussed under three different categories: I) gaseous modification by steam, carbon dioxide, air, or ozone; II) thermal modification by conventional heating and microwave irradiation; and III) recently developed modification methods using ultrasound waves, plasma, and electrochemical methods. The activation results are discussed in terms of different physicochemical properties of biochar, such as surface area; micropore, mesopore, and total pore volume; surface functionality; burn-off; ash content; organic compound content; polarity; and aromaticity index. Due to the rapid increase in the application of biochar as adsorbents, the synergistic and antagonistic effects of activation processes on the desired application are also covered.