Startseite Kinetic Study of Adsorption of Pigments and Oxidation Products in the Bleaching of Rice Bran Oil
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Kinetic Study of Adsorption of Pigments and Oxidation Products in the Bleaching of Rice Bran Oil

  • Ricardo S. Pohndorf , Cláudio P. Pinheiro und Luiz A. A. Pinto EMAIL logo
Veröffentlicht/Copyright: 26. März 2016
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Abstract

In this study, different concentrations and types of adsorbents (activated earth, chitin and chitosan) were tested for adsorption of carotenoids, chlorophylls and peroxides in the bleaching of rice bran oil (RBO). The bleaching kinetics showed that using 1 % (w/w) of activated earth for 20 min, there was a suitable reduction in peroxide and pigment contents. The bleaching with 2 % (w/w) of biopolymeric adsorbents promoted to a decrease of around 40 % in the peroxide value. The increased concentration of activated earth led to an increase in the adsorption rate constant, indicating more speed in the bleaching process. The pseudo-second-order model showed best fit to the experimental data in the oil bleaching onto activated earth; however, the pseudo-first-order model was more appropriate to describe the kinetic behavior of adsorption onto chitin and chitosan. The biopolymeric adsorbent has shown to be a potential source for adsorption of metal ions in RBO.

Funding statement: Funding: The authors would like to thank CAPES/Brazil (Coordination for the Improvement of Higher Education Personnel) and CNPq/Brazil (National Council for Scientific and Technological Development) for the financial support.

References

1. Lerma-García MJ, Herrero-Martínez JM, Simó-Alfonso EF, Mendonça CR, Ramis-Ramos G. Composition industrial processing and applications of rice bran γ-oryzanol. Food Chem 2009;115:389–404.10.1016/j.foodchem.2009.01.063Suche in Google Scholar

2. Van Hoed V, Depaemelaere G, Vila Ayala J, Santiwattana P, Verhé R, De Greyt W. Influence of chemical refining on the major and minor components of rice bran oil. J Am Oil Chem Soc 2006;83:315–21.10.1007/s11746-006-1206-ySuche in Google Scholar

3. Pestana-Bauer VR, Zambiazi RC, Mendonça CR, Beneito-Cambra M, Ramis-Ramos G. ɣ-oryzanol and tocopherol contents in residues of rice bran oil refining. Food Chem 2012;134:1479–83.10.1016/j.foodchem.2012.03.059Suche in Google Scholar PubMed

4. Monte ML, Monte ML, Pohndorf RS, Crexi VT, Pinto LA. Bleaching with blends of bleaching earth and activated carbon reduces color and oxidation products of carp oil. Eur J Lipid Sci Technol 2015;117:829–836. DOI: 10.1002/ejlt.201400223.Suche in Google Scholar

5. Wan Ngah WS, Teong LC, Hanafiah MA. Adsorption of dyes and heavy metal ions by chitosan composites: a review. Carbohydr Pol 2011;83:1446–56.10.1016/j.carbpol.2010.11.004Suche in Google Scholar

6. Sathivel S, Prinyawiwatkul W. Adsorption of FFA in crude catfish oil onto chitosan, activated carbon, and activated earth: a kinetics study. J Am Oil Chem Soc 2004;81:493–96.10.1007/s11746-004-0929-0Suche in Google Scholar

7. Huang J, Sathivel S. Purifying salmon oil using adsorption, neutralization, and a combined neutralization and adsorption process. J Food Eng 2010;96:51–8.10.1016/j.jfoodeng.2009.06.042Suche in Google Scholar

8. Moura CM, Moura JM, Soares NM, Pinto LA. Evaluation of molar weight and deacetylation degree of chitosan during chitin deacetylation reaction: used to produce biofilm. Chem Eng Process 2011;50:351–55.10.1016/j.cep.2011.03.003Suche in Google Scholar

9. MPOB. Determination of carotene content. Method no. p 2.6. Malaysian Palm Oil Board, 2005.Suche in Google Scholar

10. Sabah E. Decolorization of vegetable oils: Chlorophyll-a adsorption by acid-activated sepiolite. J Colloid Interface Sci 2007;310:1–7.10.1016/j.jcis.2007.01.044Suche in Google Scholar PubMed

11. AOCS. Official methods of analysis. Washington, DC: American Oil Chemists’ Society Press, 2003.Suche in Google Scholar

12. AOCS. Official and tentative methods of the American Oil Chemist’s Society. Chicago, IL: American Oil Chemists’ Society Press, 1998.Suche in Google Scholar

13. Silva SM, Sampaio KA, Ceriani R, Verhé R, Stevens C, De Greyt W, Meirelles AJ. Adsorption of carotenes and phosphorus from palm oil onto acid activated bleaching earth: equilibrium, kinetics and thermodynamics. J Food Eng 2013;118:341–49.10.1016/j.jfoodeng.2013.04.026Suche in Google Scholar

14. Dotto GL, Vieira ML, Gonçalves JA, Pinto LA. Removal of acid blue 9, food yellow 3 and FD&C yellow no. 5 dyes from aqueous solutions using activated carbon, activated earth, diatomaceous earth, chitin and chitosan: equilibrium studies and thermodynamic. Quim Nova 2011;34: 1193–99.10.1590/S0100-40422011000700017Suche in Google Scholar

15. Silva SM, Sampaio KA, Ceriani R, Verhé R, Stevens C, De Greyt W, Meirelles AJ. Effect of type of bleaching earth on the final color of refined palm oil. Lebensm Wiss Technol 2014;59:1258–64.10.1016/j.lwt.2014.05.028Suche in Google Scholar

16. Prokof’ev VY, Razgovorov PB, Gordina NE. The adsorption of undesirable impurities from sunflower oil on the granulated sorbents based on kaolin clay. Int J Food Eng 2014;10:713–20.10.1515/ijfe-2014-0103Suche in Google Scholar

17. Huang J, Sathivel S. Thermal and rheological properties and the effects of temperature on the viscosity and oxidation rate of unpurified salmon oil. J Food Eng 2008;89:105–11.10.1016/j.jfoodeng.2008.03.007Suche in Google Scholar

18. Guillén MD, Cabo N. Some of the most significant changes in the Fourier transform infrared spectra of edible oils under oxidative conditions. J Sci Food Agric 2000;80: 2028–36.10.1002/1097-0010(200011)80:14<2028::AID-JSFA713>3.0.CO;2-4Suche in Google Scholar

Published Online: 2016-3-26
Published in Print: 2016-5-1

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Heruntergeladen am 12.11.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ijfe-2015-0164/html
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